File name: Pandora114s1_BuenosAires_20200313_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T110706.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v6d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20200313_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20200313 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200313T105136.4Z 7377.452505 243 1 20.82 2 78.58 85.30 52.22 281.81 0.00 1 0.00 1 0 17 2.433e-01 8.979e-03 2.149e-01 6.618e-03 5.057180e-01 3.401654e-03 5.340690e-03 -6.000000e+00 1.366414e-01 228.07 -2.00 3.16 -2.00 320.68 0.00e+00 2.800198e-03 1.389512e-03 1.574427e-03 -6.000000e+00 6.185545e-03 288.23 -2.00 20.00 -2.00 319.97 0.00e+00 4.880 0.001 302.00 328.00 3 2.4115e+00 1.0937e-02 5.4270e-02 -6.0000e+00 3.3919e-01 3.9988e-02 1.3990e-02 2.5258e-02 -6.0000e+00 3.6837e-01 -5.8167e-02 1.2564e-02 1.3073e-02 -6.0000e+00 2.2005e-01 1.8273e-02 6.2461e-03 4.1261e-03 -6.0000e+00 9.4197e-02 2.2300e-04 -4.4313e-04 1.9008e-04 5.7235e-05 -6.0000e+00 6.3396e-03 1.5685e-02 -1.7289e-04 12 9 1 12 9 1 99.26 22.36 0.73 0.01569 0.01236 13 7 1 5 0 1474.412 26.32 20.00 22.36 -50568 -62628 -70198 162008 -116824 -93183 -12603 -75683 -28817 34295 -36233 18174 -340 -29003 -41426 59705 -12393 -12547 -22915 -14336 -16193 -14361 -5941 16111 4711 -24414 -19712 -20847 -22356 -27405 -6164 13526 -443 10526 -1015 -12131 -10293 -1848 1219 -1513 8516 -3526 4468 2330 -3352 1060 214 4381 -283 -2723 1094 1300 5644 3666 278 3666 1580 26 2660 -3151 -1737 -711 2508 4899 4457 3520 -297 -840 2598 -403 3093 49 1424 242 586 -1787 -883 -223 -3178 -971 -792 -1427 -2857 -1705 -1071 -1026 866 701 1394 2153 -745 712 -318 529 431 -1418 -162 -27 240 -296 -488 -1481 -924 241 -941 -1879 -1243 -959 -612 615 898 425 1109 31 -652 208 499 310 463 -535 250 -1062 573 369 1258 610 -864 582 111 293 403 -150 -375 -136 407 -391 -406 341 461 -502 386 106 -542 -296 -475 -735 -906 1046 -2262 -1444 -98 -1270 -335 221 -491 164 -5 -655 -1284 771 -360 -397 -858 -518 -606 -528 -211 499 176 -1276 -980 -1009 -1082 -1486 -314 664 -28 625 -64 -853 -791 -157 124 -186 1050 -523 640 349 -539 166 34 684 -48 -492 208 274 1242 885 73 968 439 7 714 -885 -495 -219 843 1790 1718 1325 -110 -314 1018 -188 1549 27 769 127 285 -803 -358 -87 -1364 -473 -450 -928 -2076 -1184 -785 -808 712 603 1202 1805 -608 583 -244 393 341 -1178 -152 -29 285 -368 -584 -1635 -919 230 -965 -2099 -1452 -1178 -799 868 1394 712 1884 51 -1034 307 710 452 713 -890 429 -1833 941 588 1921 901 -1238 795 160 472 719 -265 -692 -260 822 -849 -927 792 1087 -1196 883 230 -1122 -598 SS 20200313T105852.1Z 7377.457547 246 1 50.12 2 77.10 84.24 53.63 280.57 0.00 1 0.00 1 0 25 1.452e-01 6.009e-03 5.212e-02 2.291e-03 4.615652e-01 1.174144e-03 4.838626e-03 -6.000000e+00 8.155201e-02 228.07 -2.00 3.16 -2.00 320.42 0.00e+00 2.190400e-03 4.340518e-04 8.627272e-04 -6.000000e+00 3.690842e-03 288.23 -2.00 20.00 -2.00 319.66 0.00e+00 4.358 0.001 302.00 328.00 3 1.5870e+00 3.6537e-03 4.8451e-02 -6.0000e+00 2.0244e-01 2.9848e-02 4.5379e-03 2.2160e-02 -6.0000e+00 2.1984e-01 -3.1457e-02 3.8561e-03 1.1369e-02 -6.0000e+00 1.3132e-01 3.4014e-03 1.9510e-03 3.7419e-03 -6.0000e+00 5.6232e-02 8.7328e-04 -3.6109e-04 6.7067e-05 4.3224e-05 -6.0000e+00 3.7826e-03 1.3833e-02 -1.7236e-04 10 0 0 10 0 0 99.83 22.37 0.59 0.01383 0.01112 114 22 1 5 0 439.587 26.32 20.00 22.37 -65252 24251 -58914 -10791 -76241 -52843 -48730 -51923 -22857 -48598 580 -41344 -15974 -14768 -8287 -16644 -16466 -818 -17338 2876 -10689 -2319 -8880 -6883 2740 -12969 -4080 -6332 152 -7799 -978 3690 -27 4423 -6031 -1453 -6145 -4056 2186 -151 2037 -1259 1149 -717 2581 614 1371 818 -905 1941 -184 2431 2391 1260 -296 881 1919 -1080 1321 -576 -182 2187 2042 3545 93 1960 -662 1115 2086 1871 650 679 940 50 -85 -339 -1252 -1294 -1470 -501 -911 -672 -1981 -1461 -748 -1076 266 -167 954 685 716 765 -188 179 -42 -65 -360 463 -325 -120 -282 -1164 -443 -223 -88 -1222 -678 -1055 -792 365 349 686 18 335 -227 250 305 -44 390 55 52 -154 270 169 157 800 -451 964 483 153 134 -289 -335 -64 286 -265 -20 204 132 -103 20 98 -606 -70 -1061 177 -1005 -116 -1448 -803 -795 -1009 -368 -1053 8 -970 -357 -403 -254 -629 -673 -31 -821 117 -506 -101 -433 -357 139 -803 -230 -349 8 -448 -60 251 -2 347 -497 -114 -559 -435 270 -22 328 -223 207 -134 473 117 260 158 -180 392 -41 587 627 358 -89 273 606 -352 411 -180 -58 745 780 1473 42 831 -272 446 892 921 361 398 553 29 -45 -163 -553 -550 -661 -257 -545 -455 -1490 -1159 -626 -971 229 -151 861 607 660 651 -150 137 -34 -59 -341 492 -387 -148 -335 -1275 -481 -236 -99 -1358 -789 -1296 -1030 511 535 1122 30 541 -346 354 418 -62 575 88 86 -255 431 261 234 1139 -620 1387 662 233 226 -523 -629 -125 586 -583 -46 480 290 -229 48 219 -1288 -144 SS 20200313T110455.0Z 7377.461748 249 1 50.06 2 75.86 83.35 54.81 279.57 0.00 1 0.00 1 0 17 8.180e-02 5.429e-03 2.504e-02 1.509e-03 4.294961e-01 7.648152e-04 4.536251e-03 -6.000000e+00 4.595303e-02 228.07 -2.00 3.16 -2.00 320.06 0.00e+00 1.595491e-03 2.516063e-04 7.932939e-04 -6.000000e+00 2.079426e-03 288.23 -2.00 20.00 -2.00 319.29 0.00e+00 4.002 0.001 302.00 328.00 3 1.3051e+00 2.2815e-03 4.4626e-02 -6.0000e+00 1.1407e-01 2.2211e-02 2.7745e-03 2.0619e-02 -6.0000e+00 1.2387e-01 -2.0396e-02 2.2696e-03 1.0351e-02 -6.0000e+00 7.3996e-02 -7.8683e-04 1.1680e-03 3.1618e-03 -6.0000e+00 3.1687e-02 1.6868e-03 -5.1204e-05 4.3723e-05 3.7960e-05 -6.0000e+00 2.1311e-03 1.4002e-02 -1.3679e-04 10 0 0 10 0 0 72.67 22.40 0.54 0.01400 0.01362 181 36 1 5 0 276.532 26.32 20.00 22.40 -22542 -21902 -37083 -10695 -42281 -23785 -27678 -22940 -26134 -27218 -13794 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