File name: Pandora114s1_BuenosAires_20200316_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T110739.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v6d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20200316_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20200316 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200316T115135.0Z 7380.494155 280 1 50.01 2 66.96 74.95 26.44 289.84 0.00 1 0.00 1 0 17 2.957e-02 6.578e-03 1.654e-02 3.288e-03 2.805203e-01 1.627720e-03 2.994636e-03 -6.000000e+00 1.659015e-02 227.90 -2.00 3.16 -2.00 318.43 0.00e+00 4.363468e-04 3.192528e-04 2.174033e-04 -6.000000e+00 7.512777e-04 288.12 -2.00 20.00 -2.00 317.56 0.00e+00 2.535 0.000 302.00 328.00 3 4.2069e+00 4.4295e-03 2.8364e-02 -6.0000e+00 4.1167e-02 3.3605e-02 5.0665e-03 1.3144e-02 -6.0000e+00 4.4719e-02 3.8324e-03 3.2758e-03 6.4070e-03 -6.0000e+00 2.6716e-02 -1.0215e-02 1.6909e-03 1.8030e-03 -6.0000e+00 1.1435e-02 4.5525e-04 1.1687e-04 9.4504e-05 1.8050e-05 -6.0000e+00 7.7034e-04 1.8258e-02 -1.4103e-04 11 8 0 10 0 0 99.98 22.03 0.40 0.01826 0.01914 32 6 1 5 0 1562.535 26.11 20.00 22.03 -16348 7827 -2291 -11597 11269 -10747 1287 -5956 5813 3657 -9485 -2170 -85 4671 -3127 6832 -3365 -1646 3660 -1508 -190 -167 5398 289 1933 -235 -1997 -2292 -1833 5596 -1586 2192 1452 -2906 -2566 -5761 -167 -1747 -608 -1608 47 -796 260 20 -389 1474 -1364 151 -335 -1332 2317 917 1460 311 1036 390 -537 1436 -1072 704 280 1715 1247 1431 -63 335 485 -1273 1051 -90 1014 108 28 1127 -494 842 -642 -815 -462 -1232 -171 -1443 -1707 -2170 -339 -599 355 -124 -250 878 168 608 -694 497 492 -163 65 622 542 -555 116 -674 -779 401 -102 -736 -1156 -486 -420 575 824 385 556 210 289 -500 291 248 -6 -14 -309 98 -447 221 394 515 6 2 997 -443 444 -745 -273 113 143 78 -518 796 256 -114 -73 -173 -263 -289 -1163 510 -162 -815 571 -679 80 -457 433 283 -827 -189 -8 509 -419 896 -508 -256 561 -253 -32 -28 874 53 368 -47 -398 -429 -323 915 -301 441 320 -673 -552 -1266 -38 -486 -202 -623 19 -348 115 9 -175 652 -610 65 -143 -580 1030 446 752 170 582 226 -320 837 -627 401 165 1068 853 1049 -47 234 310 -800 684 -67 830 94 25 944 -394 600 -416 -495 -286 -863 -135 -1279 -1637 -2194 -358 -618 387 -141 -288 978 195 644 -676 450 459 -167 74 787 681 -722 144 -845 -900 455 -124 -975 -1611 -639 -576 833 1273 623 893 322 408 -722 399 347 -8 -21 -474 151 -678 355 605 754 8 3 1350 -658 704 -1253 -466 178 238 138 -963 1498 493 -221 -137 -316 -460 -498 SS 20200316T121401.1Z 7380.509735 288 1 50.15 2 62.54 71.13 30.75 284.29 0.00 1 0.00 1 0 17 8.794e-03 4.991e-03 1.160e-03 3.687e-04 2.413213e-01 1.823163e-04 2.598498e-03 -6.000000e+00 4.936434e-03 227.90 -2.00 3.16 -2.00 317.51 0.00e+00 3.459458e-04 2.784544e-05 5.192467e-05 -6.000000e+00 2.234251e-04 288.12 -2.00 20.00 -2.00 316.65 0.00e+00 2.157 0.000 302.00 328.00 3 9.0338e-01 4.8378e-04 2.4186e-02 -6.0000e+00 1.2250e-02 1.9209e-02 5.4690e-04 1.1261e-02 -6.0000e+00 1.3304e-02 -3.0583e-04 3.2803e-04 5.4732e-03 -6.0000e+00 7.9480e-03 -7.8338e-03 1.6305e-04 1.5535e-03 -6.0000e+00 3.4039e-03 1.9175e-02 3.1302e-04 1.0396e-05 1.6708e-05 -6.0000e+00 2.2908e-04 1.5861e-02 -8.9671e-05 10 0 0 10 0 0 99.95 22.13 0.45 0.01586 0.01821 885 174 1 5 0 56.521 26.21 20.01 22.13 -824 -617 -2057 -3566 -2941 -2910 -275 494 -233 -2019 -2111 -520 -407 702 494 -217 53 432 946 798 272 761 1191 597 768 142 -614 -732 11 696 768 1679 1021 -1668 -2196 -1971 -1914 -216 -81 -746 -860 -489 -637 -574 -41 -391 -627 -663 -903 138 592 559 1088 735 456 931 515 119 172 307 849 1090 1367 1345 146 -80 -374 -503 1125 725 310 286 -28 337 122 -43 -384 -881 -302 -752 -1032 -1003 -1928 -1478 -885 -717 -87 129 303 365 603 443 -106 337 574 150 304 664 111 -187 -9 -643 -503 323 -282 -990 -529 -669 -431 294 376 344 197 240 -51 92 308 54 137 38 -474 -290 6 -66 358 715 32 697 771 187 281 -72 -296 -73 245 31 -170 285 82 -152 44 -179 -513 -212 -96 -76 -250 -396 -293 -287 -29 59 -31 -275 -282 -72 -64 126 100 -47 12 100 227 199 69 189 303 162 220 42 -179 -200 3 173 204 481 318 -535 -658 -580 -620 -82 -34 -358 -448 -264 -353 -320 -23 -217 -341 -351 -468 71 319 324 663 472 302 627 355 82 116 205 579 795 1082 1138 126 -64 -274 -354 819 601 285 253 -25 319 109 -35 -279 -597 -207 -575 -897 -966 -1848 -1478 -933 -812 -104 161 381 450 698 469 -111 329 572 150 337 813 149 -258 -12 -780 -562 355 -334 -1279 -714 -942 -632 419 568 541 308 355 -75 125 399 72 190 57 -701 -434 8 -102 525 995 43 878 988 259 418 -112 -470 -109 381 51 -295 507 149 -279 79 -310 -853 -345 SS 20200316T121943.4Z 7380.513697 291 1 2.79 2 61.44 70.11 31.86 283.06 0.00 1 0.00 1 0 17 9.041e-03 6.697e-03 7.444e-03 3.723e-03 2.325054e-01 1.858646e-03 2.533647e-03 -6.000000e+00 5.071684e-03 227.90 -2.00 3.16 -2.00 316.20 0.00e+00 4.987353e-04 2.087940e-04 4.920284e-05 -6.000000e+00 2.297361e-04 288.12 -2.00 20.00 -2.00 315.41 0.00e+00 2.081 0.000 302.00 328.00 3 2.8846e+00 4.8264e-03 2.3317e-02 -6.0000e+00 1.2585e-02 2.9426e-02 5.4047e-03 1.0825e-02 -6.0000e+00 1.3672e-02 -7.0166e-04 3.1243e-03 5.2610e-03 -6.0000e+00 8.1677e-03 -6.2566e-03 1.4651e-03 1.4817e-03 -6.0000e+00 3.4960e-03 2.8713e-03 -8.0859e-04 1.0247e-04 1.6808e-05 -6.0000e+00 2.3561e-04 1.4022e-02 -3.6952e-04 12 9 1 12 9 1 41.81 22.18 0.41 0.01402 0.00795 3 15 1 5 0 652.906 26.21 20.00 22.18 -26 -208 924 -704 -2168 -2378 1084 335 -942 -713 -1689 -139 -703 -1663 1007 269 1815 -164 1319 -1807 107 1749 203 -334 1366 1091 -1599 -1651 25 206 -396 1463 1068 -1768 -2564 -1450 -1537 -307 1143 -796 -361 -50 -305 -1130 859 -1120 172 -468 -1319 101 693 1005 999 522 368 1562 385 -69 804 1142 568 902 2077 1417 39 -45 -272 -556 870 1056 -20 617 18 -498 -178 -1006 -193 -645 -489 -891 -1234 -390 -2209 -1715 -777 -1108 -121 225 385 443 492 -51 470 -326 1073 115 213 367 663 144 -477 -390 -481 174 9 -1257 -691 -1412 -107 369 51 197 102 861 0 415 -40 61 297 295 -454 -111 163 -52 891 482 776 675 835 195 301 -17 -852 -217 200 20 -358 -40 281 -133 208 -9 -643 -463 -5 -42 198 -138 -387 -422 205 73 -206 -157 -401 -32 -182 -499 330 88 599 -57 469 -687 40 639 77 -136 576 473 -694 -668 9 76 -156 614 485 -826 -1121 -617 -721 -157 645 -493 -242 -35 -218 -816 608 -806 119 -318 -879 66 476 739 731 402 291 1249 317 -57 644 903 464 743 1838 1275 36 -41 -223 -462 750 973 -19 628 18 -502 -169 -917 -165 -514 -394 -800 -1188 -390 -2303 -1863 -844 -1298 -143 276 476 537 588 -59 486 -334 1106 124 242 439 862 185 -614 -482 -550 206 11 -1586 -909 -1868 -145 506 74 287 147 1217 0 542 -51 78 398 409 -643 -159 229 -74 1201 650 988 858 1078 260 410 -24 -1245 -321 295 31 -568 -65 446 -212 337 -14 -977 -719 SS 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