File name: Pandora114s1_BuenosAires_20200423_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T112523.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v7d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20200423_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20200423 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200423T114128.2Z 7418.487132 450 1 50.41 2 75.95 63.30 79.39 68.70 0.00 1 0.00 1 0 17 2.617e-01 1.256e-02 1.890e-01 7.109e-03 4.618340e-01 3.609362e-03 4.872059e-03 -6.000000e+00 1.466135e-01 225.79 -2.00 3.16 -2.00 320.57 0.00e+00 2.878898e-03 1.398217e-03 6.605991e-04 -6.000000e+00 6.650660e-03 286.10 -2.00 20.00 -2.00 319.87 0.00e+00 4.026 0.001 302.00 328.00 3 3.7090e+00 1.1302e-02 4.5379e-02 -6.0000e+00 3.6206e-01 3.0745e-02 1.4194e-02 2.1829e-02 -6.0000e+00 3.9417e-01 -9.7155e-02 1.2207e-02 1.1444e-02 -6.0000e+00 2.3487e-01 3.4479e-02 6.1250e-03 4.2760e-03 -6.0000e+00 1.0049e-01 1.4592e-04 -7.1217e-04 2.0831e-04 4.7244e-05 -6.0000e+00 6.8392e-03 1.7100e-02 -1.9841e-04 12 9 8 11 8 0 99.74 21.92 0.87 0.01710 0.01175 23 5 1 5 0 2191.274 26.00 20.00 21.92 -98107 13841 -97385 115948 -98480 900000 -58374 -60944 30067 -91014 76143 -103304 55737 1634 8867 68109 -52261 33614 -2127 23769 -18344 -9390 9966 -11331 20882 -23295 20361 -13635 10401 1224 -5444 29220 -9072 20187 -12849 7271 -17858 3107 1825 -12129 13471 -33 16193 -3222 10178 5501 -1283 11837 2657 10143 -806 8977 5317 1354 4054 -853 5483 -1965 5594 1748 1284 786 -1615 7614 -1594 3419 -593 1506 3396 803 -593 -1358 2176 756 -1689 -1684 -3705 1024 -4433 798 -2461 159 -2014 -1088 -1788 -2364 1277 -231 2148 -401 745 1419 -1676 479 -2075 1616 -1558 134 -348 -428 -250 -2634 521 118 405 -1068 -1111 -110 -1004 369 209 604 999 1076 -559 -142 326 -486 763 -969 263 37 371 329 -322 1178 -944 1472 873 -188 425 -266 -33 146 534 -531 68 591 -573 140 -121 223 -647 -322 -2597 131 -2823 804 -2421 900000 -1067 -1306 284 -2983 528 -4427 597 37 224 1073 -2964 869 -83 749 -890 -414 415 -628 898 -1615 903 -813 476 64 -351 1539 -786 1343 -1122 514 -1795 304 220 -1968 1868 -6 2413 -594 1658 953 -239 1953 488 1800 -173 1929 1283 363 1107 -253 1566 -603 1555 498 378 253 -597 2835 -678 1330 -227 559 1332 371 -309 -752 1167 396 -843 -757 -1544 392 -1896 373 -1382 99 -1399 -793 -1394 -1989 1103 -212 1938 -364 631 1102 -1243 336 -1582 1336 -1517 145 -421 -538 -302 -2971 517 114 416 -1203 -1317 -136 -1330 525 327 1006 1686 1758 -872 -206 454 -698 1144 -1582 442 62 602 518 -491 1702 -1330 1954 1219 -295 731 -492 -64 290 1117 -1199 146 1289 -1286 313 -262 505 -1401 -680 SS 20200423T121855.0Z 7418.513137 463 1 50.08 2 69.27 56.77 72.61 62.62 0.00 1 0.00 1 0 17 3.512e-02 5.521e-03 2.181e-02 2.769e-03 3.281172e-01 1.366635e-03 3.467290e-03 -6.000000e+00 1.956270e-02 225.79 -2.00 3.16 -2.00 319.17 0.00e+00 5.075096e-04 3.345679e-04 4.529467e-04 -6.000000e+00 8.846729e-04 286.10 -2.00 20.00 -2.00 318.37 0.00e+00 2.797 0.000 302.00 328.00 3 3.5237e+00 3.8217e-03 3.1612e-02 -6.0000e+00 4.8341e-02 -1.6850e-02 4.4497e-03 1.5276e-02 -6.0000e+00 5.2599e-02 6.0228e-03 3.1624e-03 7.5454e-03 -6.0000e+00 3.1437e-02 -1.3027e-02 1.6558e-03 2.1580e-03 -6.0000e+00 1.3502e-02 6.7101e-04 3.1431e-04 8.0172e-05 2.2159e-05 -6.0000e+00 9.1434e-04 1.4290e-02 -9.9466e-05 10 0 0 10 0 0 99.99 22.05 0.80 0.01429 0.01665 72 14 1 5 0 695.410 26.11 20.00 22.05 1392 -10450 -1328 -19122 -3974 -24991 1056 4 -7474 -6960 -14522 -2314 -6800 -2506 389 -953 -1845 -3987 -1864 -1121 2882 -2419 840 -1299 -2378 2331 -3634 1394 -2056 3310 1677 -280 1434 -1188 663 -6682 916 -452 1751 -637 -320 -454 -1227 200 563 48 -412 -911 -1654 -62 1889 492 1151 1612 322 1016 488 -10 -1552 560 1724 1292 2169 1390 625 -186 222 35 1848 1562 -279 836 -60 904 356 -44 46 -1400 129 -738 -523 -1494 -1657 -1407 -692 -836 -273 47 -153 548 363 499 -328 -396 756 -364 346 415 157 -271 -391 -860 -474 -74 -691 -1100 -403 -721 -327 566 534 373 511 252 -112 382 400 247 -26 -83 -322 -245 414 -137 379 476 136 595 797 -87 103 -159 -393 -161 258 88 -271 352 171 -414 127 -177 -395 -100 51 -460 -53 -831 -135 -1053 38 0 -373 -355 -800 -122 -441 -184 32 -87 -179 -418 -200 -125 312 -275 96 -163 -323 313 -509 175 -254 392 222 -42 233 -201 103 -1108 156 -93 428 -186 -102 -152 -427 69 195 17 -143 -315 -572 -21 685 197 489 722 151 489 241 -5 -767 268 837 679 1244 870 403 -114 125 19 1059 1024 -207 644 -47 679 252 -28 27 -773 72 -471 -381 -1228 -1480 -1320 -684 -890 -280 50 -165 575 395 499 -301 -346 675 -363 385 468 194 -348 -481 -1070 -538 -83 -829 -1431 -547 -935 -443 814 828 609 833 393 -163 562 565 356 -40 -124 -507 -389 638 -205 599 717 195 815 1123 -135 173 -256 -650 -274 459 166 -540 715 355 -867 257 -346 -740 -184 SS 20200423T122558.3Z 7418.518035 466 1 6.53 2 68.07 55.45 71.38 61.41 0.00 1 0.00 1 0 17 2.036e-02 6.908e-03 1.959e-02 4.309e-03 3.129570e-01 2.119041e-03 3.365322e-03 -6.000000e+00 1.133990e-02 225.79 -2.00 3.16 -2.00 318.08 0.00e+00 4.190282e-04 3.858031e-04 2.572929e-04 -6.000000e+00 5.129451e-04 286.10 -2.00 20.00 -2.00 317.27 0.00e+00 2.653 0.000 302.00 328.00 3 3.3047e+00 5.6763e-03 3.0021e-02 -6.0000e+00 2.8021e-02 -1.0352e-02 6.4650e-03 1.4492e-02 -6.0000e+00 3.0491e-02 -2.6293e-03 4.1228e-03 7.1075e-03 -6.0000e+00 1.8224e-02 -8.0522e-03 2.1258e-03 2.0044e-03 -6.0000e+00 7.8260e-03 9.7836e-04 8.4498e-05 1.2084e-04 2.0949e-05 -6.0000e+00 5.3019e-04 1.4123e-02 -1.5797e-04 12 9 1 12 1 1 99.62 22.08 0.61 0.01412 0.01476 5 9 1 5 0 1057.827 26.11 20.01 22.08 4464 -5198 -1748 -9755 -8567 845 -4510 -1215 -8514 -2516 -1452 -6653 2853 -3051 -3869 -1467 2706 -4500 361 179 -1872 3384 21 3239 -1347 1795 -1461 1550 1820 -513 3082 -851 2260 -2078 -1345 -2418 -1477 1466 124 286 -2815 778 -223 -39 705 -904 908 -806 741 -1141 973 490 340 1185 1349 641 -576 140 -802 -1586 1377 332 1862 1464 57 795 -828 -908 1647 1501 579 886 774 1028 568 173 98 -1028 132 -1154 -934 -1222 -2766 -710 -878 -963 -243 -758 258 211 331 553 -328 -520 749 -686 86 903 -133 -72 -26 -1148 -835 452 -209 -1094 -227 -1008 201 99 611 1041 489 425 133 429 -352 225 57 184 -215 -333 534 -372 146 356 192 929 560 129 440 -186 -979 -102 54 -7 -371 428 854 -223 46 -321 -602 -215 298 -408 -131 -721 -569 51 -320 -96 -794 -226 -129 -671 305 -407 -597 -241 447 -763 61 31 -340 580 4 619 -288 384 -317 307 375 -109 625 -200 562 -547 -329 -590 -394 454 47 115 -1283 359 -107 -19 339 -444 432 -384 344 -548 487 267 199 724 853 387 -360 87 -491 -968 838 220 1333 1137 46 595 -581 -617 1159 1205 483 776 683 876 491 135 69 -690 90 -898 -827 -1126 -2804 -742 -910 -1074 -287 -879 300 256 378 578 -338 -507 745 -711 100 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