File name: Pandora114s1_BuenosAires_20200615_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T114927.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v7d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20200615_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20200615 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200615T123329.1Z 7471.523253 292 1 50.16 2 75.03 46.99 40.52 337.61 0.00 1 0.00 1 0 17 7.482e-02 4.858e-03 1.327e-02 8.959e-04 4.350372e-01 4.430625e-04 4.529392e-03 -6.000000e+00 4.136547e-02 224.16 -2.00 3.16 -2.00 319.89 0.00e+00 1.589207e-03 1.380182e-04 6.801073e-04 -6.000000e+00 1.860739e-03 283.08 -2.00 20.00 -2.00 319.20 0.00e+00 3.795 0.000 302.00 328.00 3 5.1638e-01 1.2825e-03 4.2610e-02 -6.0000e+00 1.0194e-01 5.3660e-02 1.5468e-03 2.0146e-02 -6.0000e+00 1.1116e-01 -2.6972e-02 1.2852e-03 1.0377e-02 -6.0000e+00 6.6405e-02 -1.7342e-03 6.7027e-04 3.3833e-03 -6.0000e+00 2.8496e-02 4.3999e-03 -8.3891e-05 2.5592e-05 3.5241e-05 -6.0000e+00 1.9478e-03 2.2537e-02 -1.6724e-04 10 0 0 10 0 0 63.55 20.91 0.46 0.02254 0.02191 395 77 1 5 0 126.644 25.17 20.00 20.91 -23262 -18452 -22480 -28298 -34345 -35326 -25444 -20168 -19847 -21314 -17435 -20017 -13839 -5426 -3777 -4537 -2385 106 -771 -238 -269 -1012 -1330 -1816 -2334 -2637 -3493 -5313 -5119 -2537 -689 630 498 -2955 -3101 -3572 -3153 -837 402 207 -579 -323 -729 -657 1061 373 370 582 -145 884 1049 1535 1722 1319 833 1260 359 136 241 130 1124 1702 2039 1666 493 468 -18 -125 1410 1091 666 410 126 138 -267 -588 -509 -1186 -507 -996 -910 -1020 -2125 -1321 -987 -729 -2 154 318 136 452 172 -270 36 113 -33 69 680 -53 -254 -70 -855 -308 489 -446 -1090 -489 -660 -56 585 468 352 222 332 43 334 494 267 350 -111 -430 -65 200 -90 349 343 -311 727 518 -156 -103 -341 -404 -190 107 -193 -236 437 110 -227 96 -83 -277 168 -449 -369 -469 -574 -681 -719 -527 -456 -493 -555 -448 -596 -472 -208 -168 -228 -126 6 -46 -15 -17 -63 -88 -130 -181 -212 -280 -413 -386 -196 -59 61 54 -340 -336 -388 -381 -119 69 41 -128 -76 -178 -162 260 93 93 146 -37 233 299 479 578 474 314 490 144 55 94 50 443 726 966 870 269 243 -9 -61 733 593 403 261 81 85 -168 -334 -262 -592 -266 -604 -579 -732 -1682 -1096 -867 -685 -2 158 328 138 428 151 -220 28 94 -30 73 804 -70 -344 -91 -1015 -331 511 -502 -1331 -622 -884 -79 817 714 572 363 524 64 501 714 395 548 -171 -691 -103 308 -135 546 515 -447 1000 747 -251 -166 -588 -720 -350 207 -400 -512 965 229 -473 208 -171 -548 326 SS 20200615T131643.4Z 7471.553280 311 1 4.75 2 68.97 38.72 44.98 323.37 0.00 1 0.00 1 0 17 1.625e-02 5.408e-03 4.941e-03 1.378e-03 3.221725e-01 6.755587e-04 3.470502e-03 -6.000000e+00 8.986683e-03 224.16 -2.00 3.16 -2.00 317.62 0.00e+00 6.886886e-04 1.067173e-04 8.656848e-05 -6.000000e+00 4.041526e-04 283.08 -2.00 20.00 -2.00 316.88 0.00e+00 2.760 0.000 302.00 328.00 3 8.4090e-01 1.7838e-03 3.1076e-02 -6.0000e+00 2.2148e-02 4.1472e-02 2.0216e-03 1.4729e-02 -6.0000e+00 2.4148e-02 -1.8528e-02 1.2468e-03 7.2598e-03 -6.0000e+00 1.4425e-02 -2.1404e-03 6.3184e-04 2.1337e-03 -6.0000e+00 6.1923e-03 9.9860e-03 -1.3687e-04 3.8110e-05 2.2433e-05 -6.0000e+00 4.2300e-04 2.0487e-02 -1.6299e-04 12 1 1 12 1 1 89.75 21.02 0.48 0.02049 0.01946 37 81 1 5 0 120.398 25.28 20.00 21.02 -4166 -2867 -6715 -6608 -6493 -6335 -4877 -3245 -3918 -4856 -3337 -3468 -677 1629 -423 364 819 984 1520 2104 580 1456 1126 334 1025 -305 -1036 -1144 -886 187 1154 1782 727 -1774 -1422 -1115 -1130 305 614 -521 -220 135 -343 -425 493 -666 -551 -345 -691 232 715 481 1426 316 537 819 237 185 -212 460 1015 1109 1467 1186 -37 265 -254 -448 1108 940 -39 390 104 387 -161 -335 -168 -491 -138 -671 -857 -887 -2124 -1702 -975 -1037 -250 -137 64 248 529 463 3 283 571 -125 384 531 -77 -470 -224 -492 -350 663 -245 -915 -210 -711 -339 418 436 298 245 290 66 303 612 263 532 -6 -586 -293 -10 -59 389 591 -49 931 661 -173 135 -328 -176 -93 292 -179 -162 473 -93 -314 124 -199 -445 -86 -394 -285 -684 -609 -543 -531 -448 -336 -446 -569 -384 -435 -96 243 -74 69 162 204 327 467 132 326 262 84 272 -85 -284 -295 -216 46 306 523 216 -545 -407 -343 -353 112 252 -250 -115 68 -179 -224 258 -354 -288 -191 -381 129 392 287 897 198 347 543 161 125 -141 301 678 798 1155 948 -31 204 -193 -332 863 783 -34 357 96 343 -143 -269 -128 -356 -103 -533 -779 -847 -2099 -1759 -1062 -1149 -292 -166 79 297 593 502 3 282 588 -136 438 641 -102 -613 -292 -620 -404 790 -298 -1150 -274 -978 -464 608 651 467 383 433 95 425 822 362 735 -8 -881 -442 -15 -88 554 842 -66 1203 882 -242 204 -499 -273 -148 466 -305 -278 824 -166 -562 215 -346 -742 -141 SS 20200615T133105.0Z 7471.563252 314 1 49.99 2 67.18 35.74 46.84 319.20 0.00 1 0.00 1 0 17 1.421e-02 4.882e-03 5.419e-03 1.050e-03 3.011268e-01 5.113494e-04 3.225109e-03 -6.000000e+00 7.860489e-03 224.17 -2.00 3.16 -2.00 318.43 0.00e+00 6.683319e-04 1.005557e-04 1.304179e-04 -6.000000e+00 3.533867e-04 283.08 -2.00 20.00 -2.00 317.67 0.00e+00 2.558 0.000 302.00 328.00 3 2.1866e+00 1.3763e-03 2.8879e-02 -6.0000e+00 1.9372e-02 4.5388e-02 1.5749e-03 1.3818e-02 -6.0000e+00 2.1120e-02 -9.5590e-03 1.0400e-03 6.8504e-03 -6.0000e+00 1.2616e-02 -6.6936e-03 5.4466e-04 2.0521e-03 -6.0000e+00 5.4175e-03 3.2408e-03 3.1498e-04 3.0033e-05 2.0644e-05 -6.0000e+00 3.6982e-04 1.9758e-02 -8.8958e-05 10 0 0 10 0 0 99.99 21.03 0.41 0.01976 0.02213 228 45 1 5 0 219.220 25.28 20.00 21.03 -2714 -2294 -5007 -4500 -7378 -3880 -3731 1199 -1557 -2760 -4212 -4989 -430 -2247 1427 -834 884 74 -101 1439 319 1358 503 2077 -133 -1068 -876 -1434 -13 677 1194 1127 784 -1586 -2469 -1819 -2191 290 170 -395 -740 -756 -556 -898 276 -478 -87 -638 -1039 590 696 923 1321 1124 382 708 539 -36 213 514 1248 1447 1635 1219 -401 52 -258 -151 1268 805 309 355 93 223 184 -4 -184 -596 -450 -599 -1123 -1031 -2097 -1246 -1013 -786 -87 -220 227 102 440 196 -192 229 192 110 270 851 -93 -222 -5 -686 -160 571 -107 -986 -175 -638 -171 308 467 342 285 295 26 358 502 136 265 -132 -535 -275 55 -182 169 550 -192 948 685 -3 41 -354 -390 -189 237 -110 -200 399 105 -96 22 -152 -373 51 -174 -156 -344 -278 -425 -216 -230 81 -117 -214 -330 -425 -41 -254 177 -115 125 11 -16 230 52 217 84 364 -25 -211 -169 -261 -2 115 220 230 175 -365 -534 -387 -517 80 56 -152 -312 -333 -251 -411 125 -218 -39 -282 -455 258 322 461 700 629 223 383 298 -22 127 301 745 928 1043 841 -285 34 -173 -98 863 569 243 292 77 178 138 -3 -123 -377 -293 -439 -856 -875 -1941 -1200 -1032 -858 -101 -265 274 120 487 199 -178 200 173 109 300 1046 -126 -308 -6 -835 -179 625 -126 -1265 -233 -893 -249 478 711 545 453 446 40 502 675 187 385 -208 -812 -420 89 -286 254 784 -262 1224 912 -5 64 -586 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