File name: Pandora114s1_BuenosAires_20200624_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T114929.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v7d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20200624_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20200624 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200624T120914.8Z 7480.506422 64 1 49.67 2 79.15 51.47 110.32 78.16 0.00 1 0.00 1 0 17 3.927e-01 9.609e-03 2.541e-01 5.268e-03 6.167283e-01 2.732797e-03 6.202187e-03 -6.000000e+00 2.187032e-01 224.44 -2.00 3.16 -2.00 321.17 0.00e+00 1.548050e-03 1.315662e-03 5.767393e-04 -6.000000e+00 9.835992e-03 282.84 -2.00 20.00 -2.00 320.61 0.00e+00 5.117 0.001 302.00 328.00 3 1.9049e+00 9.2613e-03 5.8416e-02 -6.0000e+00 5.3908e-01 1.0273e-01 1.2857e-02 2.9552e-02 -6.0000e+00 5.8803e-01 -9.4933e-02 1.3089e-02 1.5537e-02 -6.0000e+00 3.4999e-01 2.5744e-02 6.2486e-03 5.1436e-03 -6.0000e+00 1.4953e-01 2.5361e-04 -5.9345e-04 1.4597e-04 5.5741e-05 -6.0000e+00 1.0272e-02 2.4029e-02 -2.2798e-04 12 8 8 10 0 0 99.95 20.92 0.60 0.02403 0.01957 47 9 1 5 0 1056.516 25.17 19.99 20.92 -20766 -114041 171382 -30595 -156299 900000 -178930 188950 -125936 -2372 -65289 -151362 -23301 -106530 10318 -54432 11417 -36915 -19727 13144 -37306 26646 -59110 7145 -30254 -32386 -4525 -34593 34652 -39414 3254 -1970 8753 2920 -7007 13909 -21859 21216 -9381 7555 1118 3393 10759 -3412 8369 -5273 4607 -1832 7705 9794 -2338 8049 -2476 5276 5221 4256 2639 -1900 2479 -6419 4377 1214 2869 1949 3334 1768 -889 2715 -1048 4998 1903 1593 205 -553 -826 -457 10 -2741 998 -800 -2742 737 -3398 -342 -2214 386 1481 6 2241 -424 2043 -1996 1630 -418 882 -196 -143 982 -897 318 -1086 87 -293 -1039 -601 -2869 -478 -1289 -379 170 804 382 -2 761 -558 63 -190 -171 950 -570 -507 -652 865 439 711 795 -57 1169 467 47 98 29 -342 133 52 -516 233 316 200 -324 227 181 -711 -362 -107 -905 880 -157 -1679 900000 -2841 971 -1529 -12 -488 -3181 -174 -2338 87 -1017 123 -707 -341 172 -819 342 -1739 132 -886 -1015 -107 -1066 534 -1397 90 -69 315 116 -292 472 -1190 916 -679 547 96 307 945 -352 778 -574 464 -203 811 1082 -324 1129 -424 905 950 818 531 -399 484 -1342 845 266 705 544 971 511 -256 768 -340 1764 770 679 88 -228 -315 -155 3 -867 333 -320 -1317 392 -2082 -216 -1517 275 1108 5 1736 -329 1453 -1375 1020 -266 603 -155 -131 1019 -1058 385 -1280 91 -278 -960 -586 -3079 -527 -1512 -474 235 1232 580 -3 1159 -898 96 -280 -258 1498 -968 -803 -1114 1395 687 1074 1157 -80 1582 680 78 182 52 -661 269 112 -1194 560 772 496 -803 537 403 -1501 -747 SS 20200624T122735.6Z 7480.519162 73 1 5.25 2 76.26 48.34 106.77 75.94 0.00 1 0.00 1 0 17 1.904e-01 1.232e-02 1.700e-01 9.192e-03 5.144652e-01 4.602832e-03 5.432566e-03 -6.000000e+00 1.059951e-01 224.44 -2.00 3.16 -2.00 319.99 0.00e+00 1.143397e-03 1.513925e-03 8.320685e-04 -6.000000e+00 4.766745e-03 282.84 -2.00 20.00 -2.00 319.32 0.00e+00 4.113 0.001 302.00 328.00 3 2.6042e+00 1.3455e-02 4.7366e-02 -6.0000e+00 2.6127e-01 7.3929e-02 1.6399e-02 2.4284e-02 -6.0000e+00 2.8502e-01 -6.5278e-02 1.4099e-02 1.2168e-02 -6.0000e+00 1.6963e-01 2.0068e-02 7.2919e-03 3.5195e-03 -6.0000e+00 7.2456e-02 3.6285e-04 -1.1450e-03 2.5236e-04 3.9763e-05 -6.0000e+00 4.9807e-03 2.4068e-02 -2.7936e-04 12 9 9 12 9 1 99.45 20.97 0.30 0.02407 0.01546 3 8 1 5 0 1267.988 25.17 20.01 20.97 -57088 -103747 -111021 4653 -46667 900000 -32226 -11461 -33087 -88485 -29183 -1216 -49154 4657 30203 -16527 -17754 -4116 -23892 14648 -8607 42714 -21081 -6204 -14625 7230 4775 7880 17689 -20175 619 -11533 3323 13065 -4912 25206 -6772 -1054 -7797 4219 2996 3458 8219 1531 1581 313 3058 4228 -4015 4965 1135 6475 2271 5979 -1236 3348 2925 -6158 532 1238 555 753 2844 483 -407 2668 1821 1719 3387 2326 -1156 -507 3097 -762 3066 -488 -402 -6499 -2852 -2441 -3448 -584 -2652 -1095 -2121 -303 41 -2036 261 313 1253 -61 -424 -345 1217 865 1571 1517 -709 -601 394 -2006 1323 -224 -45 -1659 -397 -1547 -79 220 1141 1014 172 610 -1398 620 -395 1110 689 -68 -424 127 -1035 513 1223 920 135 293 266 570 -611 -859 696 -395 832 -741 -495 53 -335 22 435 77 -157 -257 -1024 -2959 -3782 46 -711 900000 -491 -164 -653 -3173 -602 -22 -1763 121 731 -726 -859 -188 -1414 617 -463 1378 -1361 -378 -1049 434 291 445 888 -1573 45 -1117 313 1148 -489 1853 -765 -136 -1321 745 594 659 1709 314 327 67 702 974 -936 1113 290 1736 690 1881 -439 1181 1065 -2449 193 437 203 299 1245 240 -213 1307 856 811 1711 1366 -715 -328 1930 -472 1844 -273 -205 -3422 -1550 -1534 -2336 -437 -2223 -957 -1837 -276 39 -2081 262 307 1144 -57 -367 -292 1083 807 1665 1826 -898 -788 490 -2498 1440 -241 -52 -2068 -514 -1977 -105 323 1705 1627 282 971 -2135 931 -580 1638 1078 -106 -690 203 -1617 818 1866 1352 191 400 383 916 -1026 -1549 1286 -719 1586 -1530 -1066 109 -703 45 927 156 -300 -482 SS 20200624T130705.9Z 7480.546596 89 1 3.74 2 70.54 41.01 99.24 71.09 0.00 1 0.00 1 0 25 3.741e-02 6.912e-03 1.551e-02 2.796e-03 3.795749e-01 1.374806e-03 4.056341e-03 -6.000000e+00 2.071119e-02 224.44 -2.00 3.16 -2.00 318.32 0.00e+00 1.373116e-03 2.689214e-04 1.673743e-04 -6.000000e+00 9.293470e-04 282.84 -2.00 20.00 -2.00 317.59 0.00e+00 2.967 0.000 302.00 328.00 3 1.6316e+00 3.6929e-03 3.4214e-02 -6.0000e+00 5.1079e-02 4.4084e-02 4.2211e-03 1.7404e-02 -6.0000e+00 5.5681e-02 -2.0618e-02 2.8064e-03 8.6396e-03 -6.0000e+00 3.3249e-02 -1.9976e-04 1.4709e-03 2.7423e-03 -6.0000e+00 1.4263e-02 3.3816e-03 4.0069e-05 7.6950e-05 2.7040e-05 -6.0000e+00 9.7363e-04 2.1018e-02 -8.8712e-05 12 9 1 12 1 1 99.83 21.09 0.48 0.02102 0.02132 11 33 1 5 0 297.282 25.28 20.00 21.09 -13576 -12500 -14167 -9880 -11683 -14289 -13466 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-559 -464 -952 -1009 -1429 -2092 -1798 -1503 -1061 -547 -178 752 557 770 432 -568 119 1067 -60 551 1395 212 -718 -527 -682 -330 434 -1424 -1020 -1126 -1117 -842 541 894 385 406 -180 514 581 459 218 286 185 -484 -334 28 598 510 1249 509 1207 1786 177 571 123 -1022 22 -125 -363 -357 748 178 -237 -180 -709 -1103 -318