File name: Pandora206s1_BuffaloNY_20230121_L2Fit_fnvs5c4d20220512p1-8.txt File generation date: 20241121T051129.0Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c4p1-8 Local principal investigator: ---- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v2d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20230121_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20230121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 918 1463 Nominal wavelengths inside fitting window [nm]: 400.1150 400.2472 400.3794 400.5115 400.6437 400.7758 400.9080 401.0401 401.1722 401.3043 401.4363 401.5684 401.7004 401.8324 401.9645 402.0965 402.2284 402.3604 402.4924 402.6243 402.7562 402.8882 403.0201 403.1519 403.2838 403.4157 403.5475 403.6793 403.8112 403.9430 404.0747 404.2065 404.3383 404.4700 404.6017 404.7335 404.8652 404.9968 405.1285 405.2602 405.3918 405.5234 405.6551 405.7867 405.9182 406.0498 406.1814 406.3129 406.4445 406.5760 406.7075 406.8390 406.9704 407.1019 407.2333 407.3648 407.4962 407.6276 407.7590 407.8903 408.0217 408.1530 408.2844 408.4157 408.5470 408.6783 408.8095 408.9408 409.0720 409.2033 409.3345 409.4657 409.5969 409.7280 409.8592 409.9903 410.1215 410.2526 410.3837 410.5147 410.6458 410.7769 410.9079 411.0389 411.1700 411.3009 411.4319 411.5629 411.6939 411.8248 411.9557 412.0866 412.2175 412.3484 412.4793 412.6101 412.7410 412.8718 413.0026 413.1334 413.2642 413.3949 413.5257 413.6564 413.7872 413.9179 414.0486 414.1792 414.3099 414.4405 414.5712 414.7018 414.8324 414.9630 415.0936 415.2241 415.3547 415.4852 415.6157 415.7462 415.8767 416.0072 416.1377 416.2681 416.3986 416.5290 416.6594 416.7898 416.9201 417.0505 417.1808 417.3112 417.4415 417.5718 417.7021 417.8323 417.9626 418.0928 418.2231 418.3533 418.4835 418.6136 418.7438 418.8740 419.0041 419.1342 419.2643 419.3944 419.5245 419.6546 419.7846 419.9147 420.0447 420.1747 420.3047 420.4347 420.5646 420.6946 420.8245 420.9544 421.0843 421.2142 421.3441 421.4739 421.6038 421.7336 421.8634 421.9932 422.1230 422.2528 422.3826 422.5123 422.6420 422.7717 422.9014 423.0311 423.1608 423.2904 423.4201 423.5497 423.6793 423.8089 423.9385 424.0680 424.1976 424.3271 424.4566 424.5861 424.7156 424.8451 424.9746 425.1040 425.2334 425.3629 425.4923 425.6216 425.7510 425.8804 426.0097 426.1390 426.2683 426.3976 426.5269 426.6562 426.7854 426.9147 427.0439 427.1731 427.3023 427.4315 427.5606 427.6898 427.8189 427.9480 428.0771 428.2062 428.3353 428.4644 428.5934 428.7224 428.8514 428.9804 429.1094 429.2384 429.3674 429.4963 429.6252 429.7541 429.8830 430.0119 430.1408 430.2696 430.3984 430.5273 430.6561 430.7849 430.9136 431.0424 431.1711 431.2999 431.4286 431.5573 431.6860 431.8146 431.9433 432.0719 432.2005 432.3291 432.4577 432.5863 432.7149 432.8434 432.9720 433.1005 433.2290 433.3575 433.4859 433.6144 433.7428 433.8713 433.9997 434.1281 434.2565 434.3848 434.5132 434.6415 434.7699 434.8982 435.0265 435.1547 435.2830 435.4112 435.5395 435.6677 435.7959 435.9241 436.0522 436.1804 436.3085 436.4367 436.5648 436.6929 436.8210 436.9490 437.0771 437.2051 437.3331 437.4611 437.5891 437.7171 437.8451 437.9730 438.1009 438.2288 438.3567 438.4846 438.6125 438.7403 438.8682 438.9960 439.1238 439.2516 439.3794 439.5071 439.6349 439.7626 439.8903 440.0180 440.1457 440.2734 440.4010 440.5287 440.6563 440.7839 440.9115 441.0391 441.1667 441.2942 441.4217 441.5493 441.6768 441.8042 441.9317 442.0592 442.1866 442.3140 442.4415 442.5689 442.6962 442.8236 442.9509 443.0783 443.2056 443.3329 443.4602 443.5875 443.7147 443.8420 443.9692 444.0964 444.2236 444.3508 444.4779 444.6051 444.7322 444.8594 444.9865 445.1135 445.2406 445.3677 445.4947 445.6218 445.7488 445.8758 446.0027 446.1297 446.2567 446.3836 446.5105 446.6374 446.7643 446.8912 447.0180 447.1449 447.2717 447.3985 447.5253 447.6521 447.7789 447.9056 448.0324 448.1591 448.2858 448.4125 448.5391 448.6658 448.7924 448.9191 449.0457 449.1723 449.2989 449.4254 449.5520 449.6785 449.8050 449.9315 450.0580 450.1845 450.3109 450.4374 450.5638 450.6902 450.8166 450.9430 451.0694 451.1957 451.3220 451.4484 451.5747 451.7009 451.8272 451.9535 452.0797 452.2059 452.3321 452.4583 452.5845 452.7107 452.8368 452.9630 453.0891 453.2152 453.3413 453.4673 453.5934 453.7194 453.8454 453.9714 454.0974 454.2234 454.3494 454.4753 454.6012 454.7272 454.8531 454.9789 455.1048 455.2307 455.3565 455.4823 455.6081 455.7339 455.8597 455.9854 456.1112 456.2369 456.3626 456.4883 456.6140 456.7396 456.8653 456.9909 457.1165 457.2421 457.3677 457.4933 457.6188 457.7444 457.8699 457.9954 458.1209 458.2464 458.3718 458.4973 458.6227 458.7481 458.8735 458.9989 459.1243 459.2496 459.3749 459.5003 459.6256 459.7508 459.8761 460.0014 460.1266 460.2518 460.3770 460.5022 460.6274 460.7526 460.8777 461.0028 461.1280 461.2531 461.3781 461.5032 461.6283 461.7533 461.8783 462.0033 462.1283 462.2533 462.3782 462.5032 462.6281 462.7530 462.8779 463.0028 463.1276 463.2525 463.3773 463.5021 463.6269 463.7517 463.8765 464.0012 464.1259 464.2507 464.3754 464.5000 464.6247 464.7494 464.8740 464.9986 465.1232 465.2478 465.3724 465.4970 465.6215 465.7460 465.8705 465.9950 466.1195 466.2440 466.3684 466.4929 466.6173 466.7417 466.8661 466.9904 467.1148 467.2391 467.3634 467.4877 467.6120 467.7363 467.8606 467.9848 468.1090 468.2332 468.3574 468.4816 468.6058 468.7299 468.8540 468.9781 469.1022 469.2263 469.3504 469.4744 469.5985 469.7225 469.8465 469.9705 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Spectrometer control temperature [°C], 999=no temperature signal Column 159: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 160: Temperature in head sensor [°C], 999=no temperature signal Column 161: Temperature at electronics board 1 [°C], 999=no temperature signal Column 162: Temperature at electronics board 2 [°C], 999=no temperature signal Column 163: Humidity in head sensor [%], -9=no humidity signal Column 164: Pressure in head sensor [hPa], -9=no pressure signal Columns 165-710: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 711-1256: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230121T164911.4Z 8421.700826 136 1 28.01 2 63.43 170.20 69.53 172.30 0.00 1 0.00 1 0 33 1.855e-03 1.843e-03 1.763e-03 1.751e-03 -1.806554e+02 3.320029e+02 1.996022e+01 2.964050e+02 3.599199e+02 272.41 -2.00 20.00 -2.00 444.26 0.00e+00 4.537134e-04 1.887398e-04 7.985584e-07 1.183022e-05 2.028993e-04 272.41 -2.00 20.00 -2.00 453.58 0.00e+00 1.547271e-04 1.580518e-05 1.065132e-06 7.788444e-06 1.690350e-05 227.61 -2.00 2.19 -2.00 433.11 0.00e+00 7.397176e+05 2.466210e+05 4.980368e+03 1.882849e+05 2.654727e+05 255.10 -2.00 11.28 -2.00 456.71 0.00e+00 2.319665e-01 5.228941e-02 4.217482e-04 7.393638e-03 5.782552e-02 223.71 -2.00 3.55 -2.00 453.00 0.00e+00 3.715776e-06 6.530582e-06 1.918614e-07 9.398948e-07 7.097188e-06 272.41 -2.00 20.00 -2.00 454.56 0.00e+00 2.224 0.000 397.00 473.00 4 8.3424e+00 1.8481e-03 5.5143e-03 3.1957e-04 1.8942e-03 8.0090e-02 2.1584e-03 1.1514e-03 1.8323e-04 2.3220e-03 -1.1993e-02 1.2655e-03 1.5155e-04 7.3499e-05 1.3519e-03 -2.2929e-03 4.1753e-04 1.9231e-05 1.9582e-05 4.4987e-04 2.5189e-04 2.1270e-04 8.9970e-06 1.0963e-05 2.2604e-04 2.8062e-04 5.3593e-03 1.2245e-03 1.0215e-05 2.4348e-05 1.1653e-03 1.9885e-04 2.0324e-05 1.8294e-07 2.9336e-07 2.0715e-05 6.8122e-05 2.6772e-05 1.4493e-07 3.4393e-07 2.7759e-05 5.0603e-03 -7.1637e-05 8.9884e-01 1.6251e-01 6.8268e-04 1.0286e-03 1.6581e-01 12 8 8 10 0 0 96.66 17.62 2.16 0.00506 0.00364 7 7 2 2 0 4000.000 14.99 17.62 6.72 21.17 20.96 13.8 943.17 373 14 95 -216 227 34 -159 181 -142 90 -114 -136 -262 -11 -3 -66 -69 -139 -5 -98 -179 54 -187 -153 -319 -177 243 -374 -131 217 204 -18 -385 -73 -66 -280 104 -228 289 189 53 125 -170 308 -129 -55 272 -170 135 -33 33 51 91 47 -148 -27 99 367 229 -26 -6 -11 -18 383 195 124 31 477 2 62 92 -32 -272 -70 -212 65 -290 215 331 -34 243 191 220 -261 214 41 253 83 36 -197 238 120 325 -119 15 120 -77 -14 57 396 -284 105 -281 130 16 -18 190 -243 49 -444 -104 -501 181 -132 187 -272 108 -4 -9 5 91 -89 306 -94 -101 208 -190 70 -302 -249 -252 279 -199 80 -117 36 78 -564 215 -460 210 71 265 109 95 -244 31 -180 -244 -67 85 -200 21 291 148 -4 -446 -87 88 123 211 -326 -236 -204 -127 177 37 -22 127 -122 100 -350 -430 -38 -207 -94 259 -34 112 -125 2 53 -118 -117 -126 287 -299 -53 -517 71 145 103 -142 185 235 128 62 -290 90 -178 10 2 -124 159 143 128 265 678 -144 264 -324 -240 -91 -120 -242 385 25 44 -18 -225 65 -116 -416 230 99 139 217 86 409 44 162 -231 83 115 -456 -120 -111 1 -135 301 59 8 27 250 105 290 24 304 299 40 -211 -242 214 113 386 69 73 125 130 -363 -311 -185 -41 -48 14 -109 -134 -59 -219 -119 -25 102 -304 73 -157 214 -82 -4 -144 -114 13 235 17 -36 134 -28 423 -161 -63 43 -35 -41 -88 24 44 162 -199 201 -107 290 113 272 56 -25 -94 244 1 80 30 24 29 6 -21 -209 -264 64 223 -44 -123 -41 174 -123 -256 -108 -80 73 103 64 -69 -49 131 30 -150 85 -67 151 -216 -61 265 -105 -47 114 47 185 -15 -227 226 -266 64 42 200 81 -38 -78 -163 53 -95 261 -28 -18 247 -125 -26 98 -145 -23 322 -307 -93 -346 94 -37 350 -153 43 -327 -23 -22 -137 -25 81 227 -51 -128 10 -123 -75 -161 -179 15 -9 117 -50 -51 239 -102 -35 35 286 -1 205 -236 211 91 210 -250 52 -106 35 395 -167 -85 227 146 21 69 -228 49 -52 62 -400 -101 177 -157 -139 30 97 -93 432 -154 -251 160 262 164 176 -130 -202 103 -116 -71 -21 70 26 103 -413 329 -184 -17 -93 249 -83 -50 -288 -64 200 127 -89 41 -170 134 179 -197 223 -65 42 -106 131 77 70 129 52 93 -289 358 -96 -136 213 -41 -153 -63 -140 -39 62 189 -154 54 131 -78 163 222 -341 -130 -4 53 -43 -118 -51 -150 -93 -171 -118 112 -48 -88 94 143 152 -306 -287 -30 -158 -19 -115 38 25 -128 173 -245 -222 113 642 145 -42 -78 -155 263 -3 92 67 201 -125 255 -193 340 20 88 -120 77 125 243 -6 -34 -201 -309 7 -29 362 14 88 -197 205 31 -153 179 -136 87 -110 -136 -252 -10 -3 -64 -67 -136 -4 -97 -176 54 -178 -145 -298 -164 236 -368 -132 220 205 -18 -355 -67 -60 -263 101 -235 296 191 52 119 -160 291 -123 -52 259 -160 124 -31 32 50 88 45 -144 -26 94 357 222 -25 -6 -11 -19 393 202 127 33 505 2 64 93 -32 -272 -67 -199 57 -262 195 303 -33 243 195 228 -263 218 43 270 90 39 -208 247 124 338 -125 16 124 -80 -14 59 398 -285 106 -284 137 18 -19 201 -248 51 -457 -105 -519 188 -137 192 -276 108 -4 -9 5 95 -95 320 -100 -107 217 -204 74 -313 -251 -248 280 -199 81 -116 36 78 -572 217 -465 208 70 261 108 96 -257 31 -189 -250 -66 85 -195 20 280 147 -4 -459 -91 92 130 224 -344 -244 -208 -128 178 38 -23 132 -121 95 -321 -387 -35 -199 -93 264 -35 113 -124 2 52 -119 -116 -128 295 -308 -53 -507 69 142 101 -142 180 232 126 62 -285 87 -175 9 2 -130 164 141 123 240 615 -130 239 -314 -233 -89 -118 -237 371 24 42 -17 -211 59 -106 -387 216 94 130 192 74 340 35 125 -181 66 90 -349 -90 -83 1 -109 261 55 8 28 262 109 299 24 277 270 37 -197 -234 218 114 392 69 74 120 119 -319 -263 -159 -38 -46 14 -110 -133 -60 -217 -116 -24 98 -303 72 -155 215 -83 -4 -152 -120 14 242 17 -36 132 -27 416 -158 -63 42 -35 -40 -83 22 38 142 -182 185 -102 282 107 259 54 -25 -94 244 1 79 28 23 27 6 -19 -202 -258 64 227 -44 -122 -40 171 -124 -265 -108 -83 74 104 65 -71 -48 130 30 -150 84 -66 151 -213 -61 265 -104 -46 112 47 187 -15 -232 229 -267 62 39 190 75 -35 -73 -154 50 -90 252 -28 -17 242 -123 -25 96 -146 -23 331 -317 -94 -343 90 -37 338 -153 43 -333 -23 -22 -136 -25 80 225 -51 -128 10 -126 -76 -164 -184 16 -9 122 -53 -53 247 -105 -35 35 285 -1 206 -238 212 91 212 -248 50 -103 34 377 -161 -83 222 140 21 69 -234 49 -52 64 -411 -102 177 -155 -136 29 95 -91 426 -154 -255 165 274 169 181 -133 -210 106 -120 -74 -22 73 28 109 -438 349 -190 -18 -96 252 -83 -52 -296 -64 203 131 -93 43 -176 137 182 -200 226 -66 44 -108 133 79 71 133 55 98 -309 381 -102 -144 224 -44 -162 -66 -148 -42 66 202 -165 58 140 -84 175 238 -366 -139 -4 56 -46 -127 -55 -161 -100 -184 -126 117 -50 -91 97 150 161 -329 -309 -32 -170 -20 -122 41 27 -139 182 -252 -230 116 659 147 -43 -83 -167 283 -3 98 71 211 -132 269 -207 365 21 95 -130 83 134 261 -7 -37 -218 -331 8 -30 SQ 20230121T180139.4Z 8421.751150 167 1 28.00 2 63.36 189.26 69.54 189.16 0.00 1 0.00 1 0 17 3.208e-03 3.179e-03 2.874e-03 2.852e-03 -6.793326e+02 5.429962e+02 9.644263e+01 2.964015e+02 6.225205e+02 272.41 -2.00 20.00 -2.00 444.05 0.00e+00 5.603906e-04 3.052067e-04 2.519617e-06 1.170365e-05 3.515746e-04 272.41 -2.00 20.00 -2.00 453.44 0.00e+00 2.657881e-04 2.587136e-05 1.786220e-06 7.792302e-06 2.926928e-05 227.77 -2.00 2.19 -2.00 432.69 0.00e+00 9.991392e+05 4.037484e+05 2.701737e+04 1.882933e+05 4.589977e+05 255.10 -2.00 11.28 -2.00 456.69 0.00e+00 1.750952e-01 8.577557e-02 1.867775e-03 7.396525e-03 1.000646e-01 223.72 -2.00 3.55 -2.00 452.87 0.00e+00 3.337051e-07 1.070451e-05 2.524320e-07 9.392897e-07 1.227533e-05 272.41 -2.00 20.00 -2.00 454.50 0.00e+00 2.218 0.000 397.00 473.00 4 9.1261e+00 3.0112e-03 5.5009e-03 3.1789e-04 3.2793e-03 9.9351e-02 3.4770e-03 1.1488e-03 1.8094e-04 4.0051e-03 -1.6110e-02 2.0577e-03 1.5126e-04 7.2531e-05 2.3502e-03 -2.1662e-03 6.7418e-04 2.8286e-05 1.9471e-05 7.7822e-04 3.2078e-04 3.4485e-04 1.6850e-05 1.0858e-05 3.9110e-04 1.2832e-04 2.1275e-03 2.0183e-03 2.1820e-05 2.5192e-05 2.0438e-03 7.7282e-05 3.3302e-05 1.8953e-07 2.9460e-07 3.5879e-05 -3.1348e-06 4.3217e-05 1.7758e-07 3.4417e-07 4.8078e-05 3.7338e-03 -2.3253e-05 1.0723e+00 2.6401e-01 1.6045e-03 1.0003e-03 2.8658e-01 12 8 8 10 0 0 67.75 17.62 2.12 0.00373 0.00570 7 7 2 2 0 4000.000 15.00 17.62 7.79 21.17 20.96 14.0 951.63 78 -98 -358 -365 -58 -215 321 345 211 -267 504 64 517 -489 41 -147 -127 81 -15 117 -323 -193 -116 -239 -638 -65 -85 -57 99 -184 497 -756 114 0 143 -697 -78 -730 1026 -403 492 -395 -483 -24 48 204 276 261 -44 -338 50 225 -340 1014 1 432 -524 155 220 164 -125 -214 720 259 410 -90 -47 132 25 306 263 218 576 471 302 235 -195 -32 -39 413 -80 270 256 283 469 -232 286 -391 137 -265 486 53 390 -657 476 -397 405 -401 14 74 49 451 -632 179 -262 -230 -25 -386 -583 51 -536 277 -92 -628 238 -605 -532 148 373 -729 81 -324 189 -292 423 -22 -69 170 -418 -3 -257 290 -11 276 -831 -132 -60 -213 -86 -147 72 615 246 144 135 -196 386 -135 12 -351 422 182 108 -364 323 136 -22 556 71 255 -183 42 -211 32 -296 423 -412 -212 24 -266 -92 -254 86 486 -363 195 -159 -45 -248 -45 -33 -557 -324 -173 -119 -129 -389 93 -151 74 -151 -132 -214 284 394 103 -252 267 -335 -244 -73 120 280 -181 57 -125 401 -351 122 73 -168 -117 302 -95 135 612 63 47 -336 163 163 248 -124 419 -35 101 -29 151 -270 -32 -138 -200 102 -578 709 -812 247 -609 36 458 460 165 76 138 173 139 36 70 -86 -405 -294 409 207 551 105 150 49 99 -209 -496 167 -475 -386 -120 101 -535 -79 -139 -198 -338 64 -125 240 256 40 662 202 110 -561 54 -154 37 195 -481 -109 -55 466 67 -306 171 -16 -19 -167 -30 1163 -158 -203 -487 -671 616 492 43 125 232 63 441 192 104 -313 -295 -330 1122 -134 76 -761 -186 282 -71 -88 187 156 -6 -195 -355 372 -105 287 -169 -141 -280 332 159 370 165 -76 -58 -136 -4 516 -133 -261 754 -474 359 -604 171 -148 -155 216 71 -276 -289 279 -238 -156 296 -105 234 -72 -15 -556 3 -611 242 94 -123 462 32 -297 82 -177 -127 79 -932 271 19 35 -322 -6 -51 -162 -349 241 93 -296 9 360 -96 420 260 74 91 -192 138 -98 53 108 81 9 -552 -284 157 150 528 275 -245 378 401 149 309 -313 -141 356 -109 42 126 145 122 183 -300 -341 398 630 -279 179 -58 -193 -9 135 -385 -719 393 17 93 269 80 188 338 160 -624 121 -86 277 -391 13 -144 29 145 193 -78 417 213 -197 -357 20 289 -191 133 -219 625 -412 -103 61 -536 519 23 -63 -59 -939 28 -140 60 -152 160 101 -431 535 183 232 128 109 55 -184 297 58 89 156 31 66 568 -310 293 -31 -206 -265 -470 -110 -427 133 -553 -20 -327 -482 -329 125 -72 176 -17 -424 -60 -252 -207 -192 39 -194 -236 -173 -105 -483 394 826 651 -1 169 -238 -20 -23 -108 627 194 71 74 -20 873 -358 -352 -222 -104 249 481 -301 -443 24 30 245 392 74 -98 -344 -345 -54 -204 317 334 207 -264 494 62 505 -483 41 -147 -127 80 -15 118 -324 -197 -113 -224 -588 -61 -86 -57 102 -190 506 -777 108 0 135 -648 -78 -773 1072 -419 493 -388 -468 -24 47 196 259 241 -42 -314 49 224 -337 999 1 419 -509 149 209 160 -128 -224 753 272 433 -93 -50 142 27 320 282 228 583 458 292 214 -174 -29 -37 398 -82 282 269 300 506 -245 307 -425 147 -282 506 55 408 -697 496 -415 417 -431 15 76 49 463 -645 190 -288 -253 -26 -396 -614 53 -570 285 -97 -661 244 -617 -536 154 388 -744 84 -347 206 -324 465 -24 -74 180 -433 -3 -267 294 -12 282 -834 -134 -60 -215 -87 -147 71 602 243 142 137 -207 407 -141 12 -344 419 179 106 -351 319 139 -23 597 77 278 -201 46 -226 34 -308 438 -440 -231 26 -275 -87 -234 77 451 -347 199 -168 -47 -251 -45 -32 -548 -325 -177 -125 -131 -393 96 -152 72 -146 -129 -211 284 401 104 -251 259 -324 -238 -73 120 286 -184 59 -120 360 -321 110 65 -161 -116 304 -92 136 605 62 46 -323 150 147 225 -114 388 -33 93 -26 129 -217 -24 -102 -150 77 -434 540 -616 185 -455 29 390 439 165 77 145 180 146 35 66 -77 -367 -267 398 214 555 107 151 50 95 -186 -429 138 -403 -347 -110 99 -522 -78 -136 -198 -332 62 -122 229 249 40 660 204 113 -591 57 -161 39 197 -482 -107 -53 440 63 -291 165 -16 -18 -158 -26 977 -134 -179 -455 -621 572 462 41 120 227 63 437 190 102 -299 -273 -303 1012 -124 73 -737 -185 282 -70 -86 180 151 -6 -199 -365 377 -106 286 -170 -143 -284 335 159 363 159 -73 -57 -137 -4 524 -135 -261 747 -480 351 -603 170 -146 -151 213 68 -259 -266 254 -219 -145 278 -101 219 -69 -15 -535 3 -597 238 94 -126 475 33 -302 81 -171 -122 76 -937 274 19 35 -322 -6 -51 -160 -348 240 93 -290 9 357 -97 427 268 77 95 -200 142 -101 54 108 80 9 -551 -284 157 150 521 268 -243 362 375 138 285 -292 -132 335 -105 41 127 142 121 182 -297 -349 402 626 -276 175 -57 -190 -8 133 -386 -732 403 17 94 273 80 194 347 165 -651 126 -90 289 -411 14 -153 31 151 198 -79 414 209 -195 -357 20 295 -197 137 -226 633 -418 -104 62 -543 520 23 -64 -60 -969 29 -146 63 -162 169 107 -455 558 192 243 135 115 59 -195 315 62 95 166 33 70 601 -330 309 -33 -215 -275 -486 -114 -443 137 -575 -22 -345 -502 -341 130 -76 187 -18 -457 -65 -273 -217 -204 41 -206 -246 -184 -107 -486 390 819 659 -2 179 -257 -21 -25 -116 661 204 74 79 -21 933 -372 -366 -240 -112 266 515 -313 -462 26 33 257 403