File name: Pandora206s1_BuffaloNY_20230809_L2Fit_fout2c4d20220512p1-8.txt File generation date: 20241121T061049.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20230809_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20230809 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2154 305.3564 305.4973 305.6383 305.7792 305.9201 306.0611 306.2020 306.3428 306.4837 306.6246 306.7654 306.9063 307.0471 307.1879 307.3287 307.4695 307.6103 307.7511 307.8918 308.0326 308.1733 308.3140 308.4548 308.5955 308.7362 308.8768 309.0175 309.1582 309.2988 309.4394 309.5801 309.7207 309.8613 310.0019 310.1424 310.2830 310.4236 310.5641 310.7046 310.8451 310.9857 311.1261 311.2666 311.4071 311.5476 311.6880 311.8285 311.9689 312.1093 312.2497 312.3901 312.5305 312.6708 312.8112 312.9515 313.0919 313.2322 313.3725 313.5128 313.6531 313.7934 313.9336 314.0739 314.2141 314.3543 314.4946 314.6348 314.7750 314.9151 315.0553 315.1955 315.3356 315.4758 315.6159 315.7560 315.8961 316.0362 316.1763 316.3163 316.4564 316.5964 316.7364 316.8765 317.0165 317.1565 317.2964 317.4364 317.5764 317.7163 317.8563 317.9962 318.1361 318.2760 318.4159 318.5558 318.6956 318.8355 318.9753 319.1152 319.2550 319.3948 319.5346 319.6744 319.8141 319.9539 320.0937 320.2334 320.3731 320.5128 320.6525 320.7922 320.9319 321.0716 321.2112 321.3509 321.4905 321.6301 321.7697 321.9093 322.0489 322.1885 322.3280 322.4676 322.6071 322.7467 322.8862 323.0257 323.1652 323.3046 323.4441 323.5836 323.7230 323.8624 324.0018 324.1413 324.2806 324.4200 324.5594 324.6988 324.8381 324.9774 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230809T103841.9Z 8621.443541 141 1 32.01 2 86.68 71.34 25.50 139.60 0.00 1 0.00 1 0 151 1.028e+00 4.180e-01 6.531e-01 2.998e-01 3.869106e-01 2.386019e-01 2.295666e-02 -6.000000e+00 7.975875e-01 232.07 -2.00 3.55 -2.00 320.01 0.00e+00 2.228796e-01 6.147371e-02 3.995509e-02 -6.000000e+00 1.098625e-01 287.81 -2.00 20.00 -2.00 319.22 0.00e+00 12.768 0.040 302.00 328.00 3 -4.7815e-01 7.3371e-01 4.4120e-01 -6.0000e+00 2.1143e+00 3.7110e+00 8.4659e-01 7.0034e-01 -6.0000e+00 2.4235e+00 -3.2074e+00 6.9401e-01 2.4112e-02 -6.0000e+00 1.6950e+00 1.3229e+00 3.8511e-01 2.2850e-01 -6.0000e+00 9.0779e-01 2.0262e-07 -9.0904e-03 1.0396e-02 2.6523e-03 -6.0000e+00 4.4417e-02 -2.2385e-02 1.6733e-03 12 8 8 10 0 0 10.18 18.35 22.96 -0.02238 -0.09069 8 8 4 8 0 4000.000 15.00 18.35 24.29 21.79 21.79 18.5 983.04 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 100868 900000 900000 900000 900000 900000 900000 900000 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900000 8569 39783 -57098 900000 84857 900000 900000 44576 900000 900000 900000 900000 900000 900000 -2311 -7062 900000 -30037 900000 22320 900000 32913 900000 900000 93033 900000 900000 900000 900000 900000 37001 900000 900000 900000 5772 900000 900000 39595 18694 900000 58012 40982 19034 -56818 900000 7302 900000 900000 900000 900000 1738 900000 27937 22641 35843 900000 102106 900000 16280 900000 -24486 900000 30814 24693 476 36646 25514 -142847 8673 28419 58993 18162 -16479 -53318 49452 -5362 32001 668 24115 42749 36845 37553 27511 24271 24149 55665 -10273 28512 -8629 11654 -5350 -841 8613 5844 14796 31351 -22753 -50821 SS 20230809T114529.6Z 8621.489926 159 1 7.43 2 74.81 82.32 20.76 176.90 0.00 1 0.00 1 0 17 1.345e-01 6.233e-03 1.281e-01 4.563e-03 5.257175e-01 2.357553e-03 6.017431e-03 -6.000000e+00 7.662572e-02 232.07 -2.00 3.55 -2.00 320.22 0.00e+00 -4.443333e-04 8.324893e-04 2.754863e-04 -6.000000e+00 3.449688e-03 287.82 -2.00 20.00 -2.00 319.49 0.00e+00 3.743 0.001 302.00 328.00 3 2.7668e+00 7.1416e-03 4.6339e-02 -6.0000e+00 1.9216e-01 2.2190e-02 8.8880e-03 2.8210e-02 -6.0000e+00 2.0797e-01 -3.1785e-02 7.7756e-03 1.3893e-02 -6.0000e+00 1.2390e-01 3.9093e-03 3.9531e-03 3.8895e-03 -6.0000e+00 5.2708e-02 4.6427e-04 1.2883e-04 1.2531e-04 3.8827e-05 -6.0000e+00 3.4853e-03 -2.1574e-02 2.0543e-04 12 1 1 12 1 1 78.98 18.43 0.33 -0.02157 -0.02061 16 35 4 8 0 427.470 15.00 18.43 26.41 21.88 21.79 18.3 996.36 -28282 -49068 -18176 900000 -36705 16735 -57755 -29125 -67727 -10065 -54131 105 -70629 -2325 -32806 -2255 -1235 522 2540 3031 2055 -11254 -4092 -17138 1648 -17977 206 -15132 -5542 -8359 1606 -5788 -979 2897 -662 1432 -2820 -2192 -2723 -732 -4094 1077 -2102 3783 -791 2446 -1969 -2426 -4315 -514 1858 1328 884 751 3316 -126 4085 536 469 521 6403 1041 4117 2724 1215 816 -1120 402 -506 -104 -333 557 -60 1229 -131 -712 -869 -432 -841 -1948 -508 -233 -1341 -1053 -373 -851 461 -326 554 648 1097 -70 -75 187 578 307 -586 360 37 292 -124 -443 -1265 -141 -1060 -235 -550 -203 -321 125 123 -287 461 -65 -55 -227 166 -602 144 87 -185 95 630 -200 598 86 547 713 397 166 -166 260 -146 252 -104 -79 148 534 -138 -46 -65 -519 -540 -247 -613 -180 900000 -383 100 -800 -349 -1379 -127 -1093 1 -2130 -45 -1022 -64 -38 17 89 112 79 -493 -175 -892 80 -1093 11 -914 -287 -462 93 -415 -77 237 -53 110 -251 -220 -340 -109 -712 189 -401 694 -152 464 -393 -492 -915 -110 427 341 247 229 1008 -41 1326 180 159 173 2065 373 1603 1201 565 361 -490 175 -242 -56 -198 343 -37 713 -74 -358 -403 -196 -419 -1152 -330 -172 -1054 -867 -328 -781 439 -322 546 614 987 -59 -62 154 505 298 -653 440 48 371 -153 -513 -1349 -152 -1218 -282 -695 -264 -450 187 196 -478 752 -105 -82 -333 244 -904 229 142 -303 154 989 -304 885 123 768 1028 621 279 -294 471 -276 497 -216 -168 321 1177 -308 -98 -135 -1028 -1065 SS 20230809T120341.5Z 8621.502564 167 1 45.41 2 71.51 85.32 20.87 188.51 0.00 1 0.00 1 0 25 5.562e-02 4.886e-03 1.229e-02 8.761e-04 4.364347e-01 4.442078e-04 5.088501e-03 -6.000000e+00 3.168115e-02 232.07 -2.00 3.55 -2.00 319.58 0.00e+00 1.206453e-03 1.273956e-04 1.951954e-04 -6.000000e+00 1.405840e-03 287.82 -2.00 20.00 -2.00 318.79 0.00e+00 3.112 0.001 302.00 328.00 3 2.1265e+00 1.2827e-03 3.8522e-02 -6.0000e+00 7.9442e-02 -5.1183e-03 1.5215e-03 2.3375e-02 -6.0000e+00 8.5985e-02 -1.3098e-02 1.1796e-03 1.1446e-02 -6.0000e+00 5.1190e-02 -2.2674e-03 6.1504e-04 3.4865e-03 -6.0000e+00 2.1720e-02 1.7791e-03 4.1822e-05 2.4394e-05 3.3303e-05 -6.0000e+00 1.4187e-03 -2.1905e-02 1.8007e-04 10 0 0 10 0 0 84.32 18.43 0.28 -0.02191 -0.02159 330 102 2 8 0 137.160 15.00 18.43 27.34 21.88 21.88 18.5 1002.51 -23982 -10127 -17175 -18394 -26579 -19244 -21935 -16773 -13859 -12271 -13541 -12484 -10321 -8764 -3211 -4470 -1527 -3637 -493 -1727 -752 -3736 -1864 -427 -2267 -456 -865 -3289 -4797 -1562 -132 261 580 1082 -2881 -3410 -3039 -1875 -830 -916 -833 -1004 -286 -577 394 -407 269 -431 -433 -596 1161 823 967 1117 998 1071 882 534 217 343 580 1345 1831 2201 843 483 71 -355 418 513 788 469 634 559 354 -261 -487 -1338 -662 -1049 -1149 -761 -1869 -1480 -973 -473 -181 103 593 665 620 573 264 277 333 43 375 619 214 -183 -205 -830 -865 -169 -737 -949 -740 -580 -331 114 353 191 257 94 -159 192 -6 186 -75 -12 -435 -32 228 196 515 385 394 861 566 309 246 -5 -144 25 -43 -112 -6 219 -55 -196 -18 -317 -352 -482 -203 -396 -416 -579 -377 -476 -391 -358 -340 -383 -369 -357 -362 -151 -249 -90 -234 -33 -123 -55 -278 -141 -35 -200 -42 -81 -302 -420 -136 -13 28 71 142 -369 -425 -419 -299 -160 -213 -196 -251 -74 -153 104 -110 72 -117 -119 -168 351 275 346 430 405 446 380 231 92 143 248 621 936 1238 494 266 38 -188 236 335 567 325 477 403 236 -157 -267 -720 -381 -705 -885 -604 -1624 -1342 -944 -491 -197 115 666 718 618 528 227 236 308 45 444 766 286 -243 -254 -947 -984 -195 -867 -1178 -962 -799 -485 169 563 316 416 144 -243 276 -8 281 -113 -20 -703 -51 348 308 768 553 538 1194 868 483 413 -8 -261 47 -82 -224 -13 457 -116 -398 -35 -629 -678 SS 20230809T121805.7Z 8621.512566 169 1 9.72 2 68.88 87.72 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