File name: Pandora206s1_BuffaloNY_20231008_L2Fit_fwvt1c4d20220512p1-8.txt File generation date: 20241121T063800.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20231008_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20231008 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1793 Nominal wavelengths inside fitting window [nm]: 492.0227 492.1437 492.2647 492.3857 492.5066 492.6276 492.7485 492.8694 492.9903 493.1112 493.2321 493.3529 493.4738 493.5946 493.7154 493.8362 493.9569 494.0777 494.1984 494.3191 494.4398 494.5605 494.6812 494.8018 494.9224 495.0430 495.1636 495.2842 495.4048 495.5253 495.6459 495.7664 495.8869 496.0073 496.1278 496.2482 496.3687 496.4891 496.6095 496.7298 496.8502 496.9705 497.0909 497.2112 497.3315 497.4517 497.5720 497.6922 497.8125 497.9327 498.0528 498.1730 498.2932 498.4133 498.5334 498.6535 498.7736 498.8937 499.0137 499.1338 499.2538 499.3738 499.4938 499.6137 499.7337 499.8536 499.9735 500.0934 500.2133 500.3332 500.4530 500.5729 500.6927 500.8125 500.9322 501.0520 501.1717 501.2915 501.4112 501.5309 501.6505 501.7702 501.8898 502.0095 502.1291 502.2487 502.3682 502.4878 502.6073 502.7268 502.8464 502.9658 503.0853 503.2048 503.3242 503.4436 503.5630 503.6824 503.8018 503.9211 504.0404 504.1598 504.2790 504.3983 504.5176 504.6368 504.7561 504.8753 504.9945 505.1136 505.2328 505.3519 505.4711 505.5902 505.7093 505.8283 505.9474 506.0664 506.1854 506.3044 506.4234 506.5424 506.6613 506.7803 506.8992 507.0181 507.1370 507.2558 507.3747 507.4935 507.6123 507.7311 507.8499 507.9687 508.0874 508.2061 508.3248 508.4435 508.5622 508.6808 508.7995 508.9181 509.0367 509.1553 509.2739 509.3924 509.5109 509.6295 509.7480 509.8664 509.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231008T114341.9Z 8681.488680 213 1 16.62 2 86.61 101.29 23.67 140.63 0.00 1 0.00 1 0 22 5.374e-03 5.340e-03 1.345e-04 1.344e-04 8.791292e+03 9.218786e+00 5.930225e+02 -6.000000e+00 3.058271e+02 282.57 -2.00 20.00 -2.00 505.33 0.00e+00 1.695466e-03 3.756289e-06 1.010583e-04 -6.000000e+00 1.520740e-04 282.57 -2.00 20.00 -2.00 500.60 0.00e+00 1.278380e+00 2.658167e-03 6.335996e-02 -6.000000e+00 1.070099e-01 226.38 -2.00 3.55 -2.00 502.18 0.00e+00 12.660 0.039 489.00 513.00 1 1.0041e+00 2.0427e-04 1.9456e-02 -6.0000e+00 8.2272e-03 -9.6192e-03 5.0964e-05 1.8077e-03 -6.0000e+00 2.0976e-03 1.0759e-01 1.7695e-03 1.3838e-05 7.0360e-05 -6.0000e+00 5.8854e-04 7.5175e-03 -3.6950e-05 12 8 8 10 0 0 -33.81 17.87 3.04 0.00752 0.01979 519 173 2 2 0 31.230 15.00 17.87 13.31 21.38 21.27 18.9 913.10 -1200 -983 -569 35 411 723 970 967 916 665 272 -45 -210 -384 -567 -593 -403 -129 248 397 346 360 318 304 482 501 285 118 -74 -568 -855 -777 -560 -42 367 406 251 164 -45 -191 -187 -76 132 356 541 687 628 393 48 -286 -722 -1020 -1199 -1111 -662 -157 244 424 512 536 589 662 667 602 501 342 14 -278 -329 -490 -573 -549 -405 -262 -22 -95 -424 -710 -808 -858 -837 -693 -620 -499 -293 -290 -245 -240 -214 -227 -92 107 484 721 554 419 207 -202 -440 -839 -1106 -982 -740 -313 50 -43 -180 -327 -414 -344 -59 254 473 710 911 931 946 971 807 479 339 214 68 272 409 314 377 444 235 292 398 -49 -391 -430 -577 -480 -50 76 110 327 445 349 400 364 288 185 7 -333 -761 -966 -834 -1149 -949 -552 34 412 726 990 979 929 672 272 -46 -210 -380 -559 -587 -403 -129 253 403 354 370 328 315 501 522 297 122 -75 -574 -852 -774 -566 -43 374 420 259 168 -46 -194 -190 -78 136 371 558 710 648 403 49 -289 -727 -1008 -1173 -1091 -662 -158 246 432 524 548 603 680 688 611 514 348 14 -277 -329 -487 -565 -542 -403 -258 -21 -94 -415 -699 -787 -832 -812 -675 -609 -486 -287 -287 -244 -239 -212 -226 -90 106 481 715 544 410 197 -192 -409 -787 -1037 -917 -698 -301 49 -43 -178 -321 -405 -338 -59 254 470 709 915 941 965 979 816 481 341 213 67 269 405 313 376 444 235 292 394 -48 -382 -417 -562 -473 -49 76 110 331 456 354 409 374 296 189 7 -338 -764 -967 -841 SQ 20231008T114358.6Z 8681.488873 213 2 16.62 2 86.56 101.34 23.64 140.76 0.00 1 0.00 1 0 22 5.351e-03 5.314e-03 1.319e-04 1.317e-04 8.700254e+03 9.013206e+00 5.862997e+02 -6.000000e+00 3.045382e+02 282.57 -2.00 20.00 -2.00 505.33 0.00e+00 1.681015e-03 3.680347e-06 1.001538e-04 -6.000000e+00 1.514267e-04 282.57 -2.00 20.00 -2.00 500.60 0.00e+00 1.265191e+00 2.602851e-03 6.308372e-02 -6.000000e+00 1.065354e-01 226.38 -2.00 3.55 -2.00 502.18 0.00e+00 12.554 0.038 489.00 513.00 1 9.8111e-01 1.9990e-04 1.9273e-02 -6.0000e+00 8.1910e-03 -9.1676e-03 4.9955e-05 1.7940e-03 -6.0000e+00 2.0877e-03 1.1187e-01 1.7753e-03 1.3527e-05 7.0719e-05 -6.0000e+00 5.8596e-04 -1.5416e-02 1.1797e-04 12 8 8 10 0 0 -30.29 17.86 3.01 -0.01542 -0.00310 519 173 2 2 0 31.230 15.00 17.86 13.31 21.38 21.27 18.8 913.10 -1207 -999 -606 -9 366 733 948 965 890 658 284 -26 -201 -394 -565 -583 -428 -157 250 385 341 401 337 312 480 512 295 119 -45 -592 -857 -786 -552 -68 383 391 235 194 -23 -200 -173 -98 109 358 527 679 645 398 55 -281 -718 -1014 -1203 -1101 -679 -146 243 434 516 544 616 647 674 580 493 334 18 -284 -335 -485 -589 -561 -398 -251 -46 -92 -430 -694 -793 -852 -846 -678 -585 -462 -285 -247 -237 -248 -213 -212 -73 91 471 706 557 396 180 -214 -444 -824 -1061 -968 -714 -260 52 -51 -207 -345 -441 -324 -47 235 472 735 910 910 938 948 809 484 289 181 79 283 413 300 380 430 276 288 371 -58 -399 -450 -552 -474 -38 81 104 362 445 390 397 372 269 157 -3 -375 -796 -982 -799 -1146 -956 -582 -9 364 730 961 989 915 672 288 -26 -199 -394 -564 -584 -425 -159 253 396 354 409 345 321 495 530 305 122 -46 -594 -847 -776 -554 -68 396 401 241 198 -24 -205 -178 -99 112 370 549 709 673 412 56 -287 -718 -994 -1190 -1094 -674 -145 247 446 524 552 625 660 690 594 503 338 18 -286 -333 -477 -577 -549 -392 -250 -46 -92 -425 -679 -767 -820 -815 -656 -570 -454 -277 -243 -234 -244 -210 -209 -72 91 465 696 553 385 174 -202 -418 -767 -987 -914 -682 -253 51 -51 -203 -343 -436 -321 -46 233 474 742 908 915 951 967 826 491 289 178 78 282 407 297 377 426 274 285 365 -57 -393 -440 -543 -463 -37 80 105 365 452 400 410 379 275 160 -3 -378 -793 -976 -800 SQ 20231008T114415.2Z 8681.489064 213 3 16.31 2 86.51 101.39 23.61 140.90 0.00 1 0.00 1 0 29 5.357e-03 5.323e-03 1.298e-04 1.297e-04 8.589956e+03 8.853058e+00 5.801310e+02 -6.000000e+00 3.048694e+02 282.57 -2.00 20.00 -2.00 505.33 0.00e+00 1.666940e-03 3.625817e-06 9.931165e-05 -6.000000e+00 1.515958e-04 282.57 -2.00 20.00 -2.00 500.60 0.00e+00 1.258442e+00 2.562782e-03 6.211770e-02 -6.000000e+00 1.066665e-01 226.38 -2.00 3.55 -2.00 502.18 0.00e+00 12.451 0.037 489.00 513.00 1 9.6551e-01 1.9691e-04 1.9081e-02 -6.0000e+00 8.2009e-03 -8.9565e-03 4.9175e-05 1.7716e-03 -6.0000e+00 2.0906e-03 1.1538e-01 1.8440e-03 1.3334e-05 7.1089e-05 -6.0000e+00 5.8665e-04 -4.9975e-03 4.4769e-05 12 8 8 10 0 0 -35.81 17.86 2.99 -0.00500 0.00779 519 173 2 2 0 31.230 15.00 17.86 13.31 21.38 21.27 18.8 913.39 -1195 -964 -601 5 394 719 957 968 912 668 254 -38 -246 -382 -595 -604 -409 -166 230 405 343 374 332 315 483 523 324 117 -59 -588 -827 -778 -577 -65 358 388 251 191 -19 -194 -168 -87 111 371 524 683 617 387 47 -287 -728 -1003 -1211 -1123 -676 -134 252 415 527 552 605 663 678 588 513 312 12 -283 -344 -483 -578 -554 -411 -253 -37 -111 -422 -694 -802 -845 -833 -672 -588 -470 -257 -243 -234 -251 -223 -234 -91 103 499 683 544 398 183 -185 -445 -816 -1066 -969 -730 -275 49 -33 -175 -360 -433 -330 -30 216 483 725 903 934 909 984 800 478 290 201 57 264 424 316 371 427 262 289 373 -57 -417 -451 -567 -460 -39 76 121 370 447 376 392 379 285 178 16 -378 -787 -981 -824 -1136 -923 -578 5 392 717 971 994 920 684 258 -38 -244 -383 -594 -594 -407 -169 234 417 350 382 341 325 499 541 336 121 -59 -591 -819 -770 -580 -66 371 400 259 196 -20 -199 -173 -88 114 384 548 715 645 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275 -7 -183 -208 -300 -257 22 62 39 217 281 217 205 192 134 96 66 -161 -424 -570 -502 SQ 20231008T135512.9Z 8681.580011 263 3 5.02 2 64.74 126.59 23.93 219.00 0.00 1 0.00 1 0 15 3.089e-03 3.080e-03 1.013e-04 1.010e-04 1.511190e+03 6.069980e+00 1.124843e+02 -6.000000e+00 1.757729e+02 282.55 -2.00 20.00 -2.00 505.24 0.00e+00 5.493687e-04 2.795518e-06 3.130593e-05 -6.000000e+00 8.741197e-05 282.55 -2.00 20.00 -2.00 500.33 0.00e+00 2.184521e-01 2.012420e-03 1.156891e-02 -6.000000e+00 6.151807e-02 226.37 -2.00 3.55 -2.00 501.93 0.00e+00 2.328 0.000 489.00 513.00 1 7.3434e-01 1.5475e-04 3.4837e-03 -6.0000e+00 4.7295e-03 4.7160e-03 3.9423e-05 3.1922e-04 -6.0000e+00 1.2061e-03 6.6270e-01 1.8997e-03 1.0749e-05 1.7169e-05 -6.0000e+00 3.3825e-04 -1.0068e-02 5.5466e-05 10 0 0 10 0 0 99.97 17.88 2.28 -0.01007 0.00311 1970 1970 2 2 0 2.490 14.99 17.88 17.94 21.38 21.27 19.1 942.51 -761 -621 -417 -17 214 426 557 562 555 433 141 -70 -149 -206 -368 -380 -275 -137 130 248 199 232 203 138 290 301 121 13 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414 511 477 434 464 363 152 114 59 -27 146 192 89 220 265 87 143 253 -1 -212 -222 -322 -263 4 61 44 213 294 207 219 204 135 101 75 -131 -428 -564 -479 SQ 20231008T135518.0Z 8681.580070 263 4 5.02 2 64.73 126.61 23.94 219.04 0.00 1 0.00 1 0 15 3.235e-03 3.229e-03 7.360e-05 7.344e-05 1.508999e+03 4.388142e+00 1.116024e+02 -6.000000e+00 1.840815e+02 282.55 -2.00 20.00 -2.00 505.25 0.00e+00 5.628618e-04 2.034996e-06 3.204362e-05 -6.000000e+00 9.153863e-05 282.55 -2.00 20.00 -2.00 500.37 0.00e+00 2.049832e-01 1.460454e-03 1.176087e-02 -6.000000e+00 6.441408e-02 226.37 -2.00 3.55 -2.00 501.97 0.00e+00 2.327 0.000 489.00 513.00 1 1.4972e-01 1.1232e-04 3.4905e-03 -6.0000e+00 4.9523e-03 2.4830e-03 2.8607e-05 3.2088e-04 -6.0000e+00 1.2626e-03 1.1903e+00 1.6383e-03 7.8351e-06 1.7421e-05 -6.0000e+00 3.5423e-04 -1.1177e-02 7.5742e-05 10 0 0 10 0 0 99.28 17.88 2.27 -0.01118 0.00019 1970 1970 2 2 0 2.490 14.99 17.88 17.94 21.38 21.27 19.1 942.51 -781 -649 -453 -36 197 425 586 576 566 442 156 -56 -137 -227 -376 -418 -302 -154 145 263 224 265 214 162 301 313 129 26 30 -334 -455 -423 -347 14 306 304 184 196 59 -97 -120 -104 9 160 278 402 381 195 -20 -224 -502 -663 -835 -795 -505 -168 108 235 312 349 404 421 424 337 312 199 -16 -209 -174 -224 -308 -283 -205 -116 60 52 -191 -362 -398 -423 -444 -288 -250 -214 -42 -77 -56 -91 -117 -125 -54 13 291 450 343 253 159 -50 -182 -424 -647 -604 -474 -211 14 -101 -157 -207 -297 -229 -13 133 276 447 541 502 470 508 388 183 129 84 -17 151 220 100 214 275 77 158 264 -18 -232 -239 -349 -289 -3 69 52 239 304 230 236 217 136 108 56 -176 -491 -634 -530 -784 -642 -460 -37 203 446 613 609 599 464 162 -59 -142 -231 -381 -424 -310 -162 152 280 240 279 225 171 318 331 136 27 31 -339 -463 -430 -351 15 319 320 194 205 61 -102 -125 -107 10 167 292 424 401 203 -21 -230 -501 -660 -822 -784 -497 -169 109 240 319 358 414 432 437 341 319 202 -16 -206 -173 -220 -301 -276 -202 -115 59 50 -188 -352 -383 -405 -427 -278 -244 -206 -40 -75 -55 -89 -116 -124 -53 13 291 452 343 250 157 -48 -172 -402 -613 -578 -455 -205 14 -99 -153 -203 -290 -223 -13 130 274 447 536 500 469 508 385 180 127 81 -16 146 213 97 209 268 75 153 254 -17 -222 -225 -329 -275 -3 67 50 232 297 227 230 212 133 104 55 -168 -470 -603 -498 SQ 20231008T135523.1Z 8681.580129 263 5 5.02 2 64.71 126.63 23.95 219.08 0.00 1 0.00 1 0 15 3.222e-03 3.212e-03 8.270e-05 8.249e-05 1.511223e+03 4.946698e+00 1.112886e+02 -6.000000e+00 1.833385e+02 282.55 -2.00 20.00 -2.00 505.25 0.00e+00 5.605989e-04 2.286839e-06 3.191906e-05 -6.000000e+00 9.117334e-05 282.55 -2.00 20.00 -2.00 500.34 0.00e+00 2.042413e-01 1.643481e-03 1.187274e-02 -6.000000e+00 6.416401e-02 226.37 -2.00 3.55 -2.00 501.95 0.00e+00 2.326 0.000 489.00 513.00 1 3.6785e-01 1.2643e-04 3.4907e-03 -6.0000e+00 4.9330e-03 3.1813e-03 3.2176e-05 3.2240e-04 -6.0000e+00 1.2579e-03 9.5719e-01 1.8682e-03 8.7835e-06 1.6988e-05 -6.0000e+00 3.5281e-04 -1.0119e-02 5.7933e-05 10 0 0 10 0 0 99.94 17.88 2.27 -0.01012 0.00284 1970 1970 2 2 0 2.490 14.99 17.88 17.94 21.38 21.27 19.1 942.51 -780 -645 -444 -36 199 418 576 570 552 435 128 -62 -153 -220 -385 -420 -301 -144 154 256 222 272 220 163 309 314 120 29 29 -323 -472 -420 -334 8 309 287 190 199 48 -96 -101 -85 5 155 264 409 388 197 -24 -224 -505 -658 -828 -807 -521 -154 115 256 321 353 410 427 437 326 304 209 -1 -203 -168 -232 -312 -286 -217 -106 51 63 -191 -346 -379 -412 -441 -289 -253 -202 -43 -77 -58 -97 -115 -130 -66 2 283 440 325 252 176 -50 -180 -432 -623 -583 -489 -198 26 -84 -146 -208 -294 -220 -36 116 267 431 532 487 462 497 397 178 136 97 -12 155 232 86 217 274 75 147 252 -19 -242 -250 -370 -302 -3 70 45 234 304 228 232 226 146 106 62 -172 -479 -654 -544 -784 -638 -450 -37 208 437 612 600 580 464 135 -64 -157 -228 -397 -435 -308 -151 160 271 236 289 234 174 331 337 128 31 30 -333 -478 -425 -342 8 325 300 198 210 50 -99 -105 -89 5 161 276 428 404 203 -25 -228 -511 -651 -810 -793 -520 -154 118 260 326 358 416 435 446 334 308 210 -1 -203 -166 -227 -302 -277 -212 -105 50 62 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10 0 0 10 0 0 99.90 17.88 2.33 -0.01053 0.00228 1970 1970 2 2 0 2.490 14.99 17.88 17.94 21.38 21.27 19.1 942.51 -753 -595 -432 -10 192 433 541 569 532 409 143 -77 -135 -188 -359 -368 -276 -153 100 201 185 220 180 127 285 290 114 35 37 -274 -391 -363 -290 43 321 240 181 142 -7 -144 -153 -118 -14 121 235 366 339 222 -33 -196 -454 -556 -778 -741 -488 -145 107 200 264 272 351 389 356 285 287 183 14 -223 -144 -189 -280 -243 -199 -113 76 75 -174 -348 -412 -388 -448 -282 -280 -213 -47 -58 -33 -65 -85 -91 -59 19 251 430 334 239 149 -37 -171 -443 -603 -575 -431 -223 39 -129 -131 -202 -284 -190 4 151 297 427 509 454 427 442 306 113 93 53 -41 126 195 90 205 268 86 167 285 19 -180 -247 -306 -281 18 40 21 220 299 174 206 207 126 72 69 -157 -424 -567 -488 -747 -594 -441 -11 200 460 583 620 580 443 153 -82 -140 -194 -368 -377 -287 -161 108 220 203 242 192 136 304 310 121 37 40 -286 -401 -371 -301 45 337 255 192 149 -8 -149 -157 -122 -14 127 249 389 359 232 -34 -198 -464 -554 -768 -734 -491 -144 109 206 272 280 361 401 369 295 295 186 14 -221 -140 -183 -269 -234 -192 -111 75 74 -169 -333 -390 -366 -424 -267 -269 -205 -46 -57 -32 -64 -84 -90 -57 18 247 425 329 232 142 -36 -162 -413 -559 -539 -414 -213 37 -127 -128 -194 -272 -182 4 147 294 427 513 444 420 434 299 110 92 51 -39 122 189 88 199 260 83 161 272 18 -169 -228 -283 -261 17 37 20 209 287 168 200 202 123 70 66 -147 -391 -518 -448 SQ 20231008T135533.8Z 8681.580252 263 7 5.02 2 64.69 126.67 23.98 219.16 0.00 1 0.00 1 0 22 3.010e-03 2.996e-03 1.664e-04 1.657e-04 1.503399e+03 1.005059e+01 1.120497e+02 -6.000000e+00 1.713021e+02 282.55 -2.00 20.00 -2.00 505.24 0.00e+00 5.409181e-04 4.599435e-06 3.063902e-05 -6.000000e+00 8.518372e-05 282.55 -2.00 20.00 -2.00 500.25 0.00e+00 2.304042e-01 3.325296e-03 1.134684e-02 -6.000000e+00 5.994215e-02 226.37 -2.00 3.55 -2.00 501.87 0.00e+00 2.324 0.000 489.00 513.00 1 1.5596e+00 2.5606e-04 3.4698e-03 -6.0000e+00 4.6085e-03 8.0708e-03 6.5039e-05 3.1528e-04 -6.0000e+00 1.1749e-03 2.9032e-01 1.7187e-03 1.7657e-05 1.6788e-05 -6.0000e+00 3.2964e-04 -1.1164e-02 7.5805e-05 10 0 0 10 0 0 99.54 17.88 2.31 -0.01116 0.00076 1970 1970 2 2 0 2.490 14.99 17.88 17.94 21.38 21.27 19.1 942.51 -739 -615 -411 -4 207 417 535 556 528 421 131 -56 -129 -226 -364 -373 -279 -145 120 237 185 248 182 142 284 281 102 33 57 -297 -431 -358 -304 37 292 244 135 161 12 -107 -116 -114 -20 141 237 374 365 205 -28 -197 -480 -635 -782 -771 -482 -149 82 209 278 315 371 408 385 292 307 223 -11 -177 -128 -193 -271 -254 -172 -98 36 52 -203 -361 -403 -394 -426 -268 -238 -192 -25 -76 -11 -60 -87 -117 -31 17 260 435 321 243 153 -65 -175 -443 -611 -599 -441 -206 -3 -90 -114 -196 -282 -213 7 127 237 406 474 458 383 432 334 121 79 49 -41 161 199 104 198 278 86 170 311 -11 -186 -232 -316 -271 0 55 36 176 276 212 216 222 133 87 85 -173 -423 -580 -500 -739 -620 -423 -4 218 447 565 594 564 446 137 -60 -136 -235 -377 -388 -293 -150 127 254 199 268 197 154 308 306 111 35 60 -304 -433 -359 -309 39 312 264 146 173 13 -113 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4.5111e-03 9.7562e-03 7.9159e-05 3.1782e-04 -6.0000e+00 1.1502e-03 2.1517e-01 1.6304e-03 2.1399e-05 1.6806e-05 -6.0000e+00 3.2266e-04 -1.1245e-02 7.3083e-05 10 0 0 10 0 0 99.78 17.88 2.26 -0.01124 0.00006 1970 1970 2 2 0 2.490 14.99 17.88 17.94 21.38 21.27 19.1 942.51 -697 -563 -421 -22 163 382 490 513 507 375 92 -80 -111 -165 -334 -356 -284 -120 147 265 235 258 193 148 240 255 90 -14 13 -287 -450 -390 -308 19 280 308 203 203 78 -74 -112 -94 -9 58 228 338 335 170 -58 -218 -492 -631 -795 -779 -477 -164 84 218 315 335 402 405 410 284 275 162 -7 -221 -199 -240 -304 -258 -189 -86 88 97 -116 -304 -277 -350 -377 -206 -195 -176 -38 -82 -40 -110 -113 -144 -117 -13 256 393 292 247 190 -10 -113 -401 -571 -553 -449 -260 31 -121 -142 -160 -251 -248 -33 115 246 383 479 412 423 471 344 165 128 78 -11 130 163 42 164 228 41 96 224 -9 -202 -241 -308 -255 31 86 81 258 301 247 249 182 102 88 67 -158 -433 -614 -508 -690 -561 -429 -24 169 405 529 559 553 406 99 -85 -116 -170 -342 -365 -294 -127 158 290 249 275 205 159 256 273 95 -15 14 -300 -461 -399 -320 20 295 328 216 214 82 -76 -116 -97 -10 62 242 360 355 179 -60 -221 -503 -630 -784 -771 -480 -163 86 225 325 346 414 419 425 295 283 165 -7 -219 -195 -232 -292 -248 -183 -84 86 96 -113 -291 -262 -330 -357 -195 -187 -170 -37 -81 -40 -109 -112 -138 -113 -13 253 389 288 240 182 -10 -107 -374 -530 -519 -417 -249 30 -119 -139 -155 -241 -239 -32 113 245 384 469 405 417 465 338 161 122 76 -10 126 158 40 160 222 40 93 215 -9 -189 -224 -285 -238 30 80 77 247 290 239 242 178 100 85 64 -148 -400 -564 -469 SQ 20231008T135544.0Z 8681.580371 263 9 5.03 2 64.66 126.71 23.99 219.25 0.00 1 0.00 1 0 15 2.993e-03 2.977e-03 1.562e-04 1.556e-04 1.551716e+03 9.434170e+00 1.149360e+02 -6.000000e+00 1.703027e+02 282.55 -2.00 20.00 -2.00 505.24 0.00e+00 5.180243e-04 4.316508e-06 2.980490e-05 -6.000000e+00 8.468648e-05 282.55 -2.00 20.00 -2.00 500.26 0.00e+00 2.181357e-01 3.119643e-03 1.176453e-02 -6.000000e+00 5.959163e-02 226.37 -2.00 3.55 -2.00 501.88 0.00e+00 2.322 0.000 489.00 513.00 1 1.4611e+00 2.4016e-04 3.4727e-03 -6.0000e+00 4.5816e-03 7.9205e-03 6.1066e-05 3.2362e-04 -6.0000e+00 1.1680e-03 3.2082e-01 1.5934e-03 1.6552e-05 1.6807e-05 -6.0000e+00 3.2771e-04 -1.1444e-02 7.8546e-05 10 0 0 10 0 0 99.51 17.88 2.27 -0.01144 -0.00039 1970 1970 2 2 0 2.490 14.99 17.88 17.94 21.38 21.27 19.1 942.51 -716 -594 -445 -9 178 390 517 515 514 402 117 -55 -147 -202 -320 -376 -274 -120 145 252 208 249 194 142 279 270 82 11 31 -296 -430 -413 -309 17 272 281 197 203 68 -90 -93 -97 -22 114 238 349 326 175 -48 -239 -486 -607 -762 -744 -481 -138 125 219 293 335 368 399 398 302 291 205 -24 -217 -157 -220 -295 -249 -178 -97 70 74 -142 -316 -333 -355 -401 -256 -231 -195 -47 -58 -51 -90 -129 -133 -62 10 257 438 308 239 174 -51 -162 -402 -603 -568 -433 -258 18 -98 -139 -190 -267 -224 -30 85 263 384 517 482 421 463 352 176 131 86 -33 118 194 53 171 240 47 107 257 -15 -224 -230 -325 -245 12 86 63 243 296 218 231 229 119 92 63 -136 -468 -633 -529 -715 -598 -458 -9 188 419 547 551 549 426 123 -57 -155 -210 -331 -391 -288 -124 153 271 225 270 210 154 303 294 88 12 32 -303 -433 -415 -315 18 291 295 206 217 72 -95 -97 -102 -23 118 249 366 341 181 -50 -245 -488 -596 -739 -723 -476 -140 129 223 298 341 374 407 408 309 296 207 -24 -213 -156 -217 -289 -243 -175 -97 68 72 -140 -308 -321 -341 -386 -248 -219 -186 -45 -56 -50 -88 -126 -131 -62 10 252 431 301 238 170 -49 -151 -371 -553 -527 -412 -253 17 -95 -135 -182 -254 -214 -29 83 260 383 518 486 414 455 355 175 128 84 -32 114 187 51 166 232 46 103 245 -14 -209 -212 -299 -227 11 83 60 232 285 211 224 223 116 89 60 -127 -445 -597 -487 SQ 20231008T135549.1Z 8681.580430 263 10 5.02 2 64.65 126.73 24.00 219.29 0.00 1 0.00 1 0 15 2.960e-03 2.952e-03 1.774e-04 1.766e-04 1.527722e+03 1.071178e+01 1.140541e+02 -6.000000e+00 1.684469e+02 282.55 -2.00 20.00 -2.00 505.24 0.00e+00 5.301085e-04 4.902568e-06 3.058067e-05 -6.000000e+00 8.376387e-05 282.55 -2.00 20.00 -2.00 500.24 0.00e+00 2.241956e-01 3.546174e-03 1.148020e-02 -6.000000e+00 5.894296e-02 226.37 -2.00 3.55 -2.00 501.87 0.00e+00 2.321 0.000 489.00 513.00 1 1.6595e+00 2.7299e-04 3.4683e-03 -6.0000e+00 4.5317e-03 8.6000e-03 6.9457e-05 3.1822e-04 -6.0000e+00 1.1553e-03 2.6297e-01 1.6410e-03 1.8809e-05 1.6971e-05 -6.0000e+00 3.2414e-04 -1.1211e-02 7.6216e-05 10 0 0 10 0 0 99.70 17.88 2.31 -0.01121 0.00017 1970 1970 2 2 0 2.490 14.99 17.88 17.94 21.38 21.27 19.1 942.51 -725 -596 -413 -6 194 417 556 574 551 426 163 -39 -149 -204 -347 -368 -277 -147 132 213 179 257 162 146 263 278 107 28 63 -274 -384 -374 -294 5 280 259 149 158 16 -111 -160 -112 5 105 258 333 328 174 -28 -190 -461 -621 -770 -743 -489 -147 84 212 269 284 367 394 380 285 285 156 -23 -215 -142 -210 -263 -254 -167 -85 53 78 -178 -373 -348 -368 -432 -256 -252 -182 -37 -60 -60 -101 -93 -92 -36 -8 251 420 295 260 146 -49 -184 -415 -629 -571 -462 -219 -22 -105 -162 -193 -262 -216 9 139 274 419 482 433 426 428 324 127 109 68 -40 145 189 64 202 286 72 147 322 6 -158 -227 -292 -247 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