File name: Pandora206s1_BuffaloNY_20231203_L2Fit_fout2c4d20220512p1-8.txt
File generation date: 20241121T065439.9Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Kang Sun
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 206
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora206_OF_v3d20211008.txt
Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt
Level 1 file used: Pandora206s1_BuffaloNY_20231203_L1_smca1c4d20220512p1-8.txt
Full location name: University at Buffalo
Short location name: BuffaloNY
Country of location: Canada
Location latitude [deg]: 43.0015
Location longitude [deg]: -78.7869
Location altitude [m]: 190
Local noon date: 20231203
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0744 305.2154 305.3564 305.4973 305.6383 305.7792 305.9201 306.0611 306.2020 306.3428 306.4837 306.6246 306.7654 306.9063 307.0471 307.1879 307.3287 307.4695 307.6103 307.7511 307.8918 308.0326 308.1733 308.3140 308.4548 308.5955 308.7362 308.8768 309.0175 309.1582 309.2988 309.4394 309.5801 309.7207 309.8613 310.0019 310.1424 310.2830 310.4236 310.5641 310.7046 310.8451 310.9857 311.1261 311.2666 311.4071 311.5476 311.6880 311.8285 311.9689 312.1093 312.2497 312.3901 312.5305 312.6708 312.8112 312.9515 313.0919 313.2322 313.3725 313.5128 313.6531 313.7934 313.9336 314.0739 314.2141 314.3543 314.4946 314.6348 314.7750 314.9151 315.0553 315.1955 315.3356 315.4758 315.6159 315.7560 315.8961 316.0362 316.1763 316.3163 316.4564 316.5964 316.7364 316.8765 317.0165 317.1565 317.2964 317.4364 317.5764 317.7163 317.8563 317.9962 318.1361 318.2760 318.4159 318.5558 318.6956 318.8355 318.9753 319.1152 319.2550 319.3948 319.5346 319.6744 319.8141 319.9539 320.0937 320.2334 320.3731 320.5128 320.6525 320.7922 320.9319 321.0716 321.2112 321.3509 321.4905 321.6301 321.7697 321.9093 322.0489 322.1885 322.3280 322.4676 322.6071 322.7467 322.8862 323.0257 323.1652 323.3046 323.4441 323.5836 323.7230 323.8624 324.0018 324.1413 324.2806 324.4200 324.5594 324.6988 324.8381 324.9774
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Spectrometer control temperature [°C], 999=no temperature signal
Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 96: Temperature in head sensor [°C], 999=no temperature signal
Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20231203T160912.7Z 8737.673064 346 1 24.00 2 66.38 165.91 77.31 281.53 0.00 1 0.00 1 0 25 3.064e-01 2.313e-02 2.373e-01 2.043e-02 3.216888e-01 1.003997e-02 3.772470e-03 -6.000000e+00 1.695970e-01 222.48 -2.00 3.55 -2.00 318.62 0.00e+00 1.053236e-03 2.096342e-03 1.393484e-04 -6.000000e+00 7.661662e-03 275.71 -2.00 20.00 -2.00 318.02 0.00e+00 2.477 0.000 302.00 328.00 3 7.5368e+00 2.7115e-02 2.9031e-02 -6.0000e+00 4.1724e-01 1.0420e-01 3.1116e-02 1.6314e-02 -6.0000e+00 4.5621e-01 7.5702e-02 2.2536e-02 8.1942e-03 -6.0000e+00 2.7058e-01 -4.8553e-02 1.2101e-02 2.6418e-03 -6.0000e+00 1.1600e-01 1.5781e-05 -2.7933e-04 5.7793e-04 2.5103e-05 -6.0000e+00 7.9683e-03 -1.1626e-02 2.8474e-04 12 8 8 10 0 0 -152.77 17.93 1.71 -0.01163 -0.01372 6 6 2 8 0 4000.000 15.00 17.93 13.21 21.48 21.38 19.3 955.78 33962 92006 900000 99992 900000 103481 900000 52825 21702 87480 103987 259142 37039 -25858 -4260 12659 1555 13897 -14528 -248 4854 5991 27703 16363 -415 -3621 11431 -10523 5857 3305 18273 -1568 14173 3727 -2724 -2166 1934 922 2792 -5691 -1077 -9852 4199 3886 3341 2278 -8893 -12852 94 3486 -2649 -1400 -3686 809 -432 3421 2495 -1181 2164 -7338 1111 4418 1326 2092 -2412 -1547 -17 -287 -77 -2200 3962 315 5831 1049 4584 -892 -14063 -2896 -1342 -1498 155 217 -1183 -979 -897 3061 9598 303 771 446 929 -951 -99 -3917 -1423 -2019 -326 -2212 3129 1699 2027 -585 -1506 -2722 381 -1686 205 622 248 1192 585 -506 -562 -1569 -1858 58 -1445 -830 -742 697 1014 -935 3029 -676 1427 -1225 18 -686 752 -1474 1129 504 -1282 -1396 -588 214 1488 1404 815 1856 -307 -2026 -984 972 1832 900000 1991 900000 2060 900000 1493 948 2206 2208 5160 1784 -2590 -416 1189 173 1444 -2051 -33 625 753 2879 2046 -65 -613 1693 -1833 805 467 2433 -279 2390 737 -532 -407 385 215 775 -1985 -396 -4137 1594 1547 1335 927 -4001 -5918 38 1364 -1180 -667 -1906 426 -239 1854 1397 -683 1178 -4342 622 2587 879 1492 -1758 -1060 -11 -178 -51 -1697 3158 263 4731 854 3334 -611 -9949 -1804 -870 -1078 123 193 -1140 -980 -933 3280 10421 360 916 509 1000 -954 -91 -3610 -1369 -2177 -386 -2897 4134 2223 2546 -689 -1659 -3128 464 -2201 274 871 356 1823 959 -851 -913 -2398 -2690 77 -1950 -1161 -1112 1094 1605 -1475 4479 -990 1935 -1630 23 -897 1052 -2195 1735 805 -2121 -2403 -1071 393 2754 2663 1562 3497 -566 -3654 -1709
SS 20231203T171842.5Z 8737.721325 382 1 27.16 2 65.21 183.51 89.27 292.43 0.00 1 0.00 1 0 17 4.514e-01 4.377e-02 2.882e-01 3.489e-02 3.379910e-01 1.728626e-02 4.765195e-03 -6.000000e+00 2.507308e-01 222.48 -2.00 3.55 -2.00 318.75 0.00e+00 3.417366e-03 3.751804e-03 2.623361e-03 -6.000000e+00 1.238738e-02 275.71 -2.00 20.00 -2.00 318.16 0.00e+00 2.369 0.000 302.00 328.00 3 7.8331e+00 4.6856e-02 3.1213e-02 -6.0000e+00 6.1998e-01 1.4618e-01 5.3981e-02 2.5065e-02 -6.0000e+00 6.7858e-01 8.2373e-02 4.0373e-02 9.1314e-03 -6.0000e+00 4.0002e-01 -5.7991e-02 2.1742e-02 4.0296e-03 -6.0000e+00 1.7174e-01 1.2125e-05 -9.9751e-04 9.9121e-04 3.5209e-05 -6.0000e+00 1.1774e-02 -1.2157e-02 4.0939e-04 12 8 8 10 0 0 -123.56 17.93 0.70 -0.01216 -0.01965 17 17 1 8 0 1597.590 15.00 17.93 14.54 21.48 21.38 19.4 964.89 344622 127994 900000 223243 141344 -5896 900000 102817 900000 121842 900000 900000 38664 1200 12494 104131 46879 63522 11007 56690 -13547 24830 6824 35947 17499 -4327 -2119 14024 -11614 47875 30383 -7034 19070 -7777 19501 -57598 32311 -5584 5214 -14737 -12822 -2635 11136 3531 -17416 16385 228 -22262 6337 4142 3876 5992 1632 7151 4432 2038 1436 4690 -2706 2749 4739 7560 1970 -1328 -1676 -1751 730 -4310 2976 -1046 9169 -16547 1907 5245 6339 3326 -4740 5260 -4077 5977 -14772 4047 -2534 2385 -4444 3396 2372 570 1032 2809 3148 2950 5238 2594 2145 4871 3060 -101 1245 272 5191 309 -1735 1095 -1863 -1985 -1495 3504 -4208 231 1187 268 -5879 -2734 -213 2185 -2964 -1837 125 -1546 1235 -2387 -400 260 5072 -4167 -764 668 4014 -6126 3807 3888 -1590 677 -297 517 1637 2062 802 2016 -2076 -1039 -2031 11717 4352 900000 7590 4805 -228 900000 3496 900000 4142 900000 900000 1690 86 949 3920 3243 3947 1185 4187 -1946 2476 828 3463 2122 -660 -323 1796 -1803 4266 3443 -1242 2982 -1646 3028 -17877 4614 -1298 1309 -5382 -4931 -991 3811 1332 -7864 5517 90 -10841 2307 1553 1556 2557 771 3404 2250 1075 778 2448 -1481 1408 2448 4104 1244 -946 -1219 -1179 449 -2718 1838 -770 6717 -16351 1562 3975 4401 2123 -3062 2927 -2620 3976 -13252 3351 -2406 2239 -4771 3612 2674 675 1222 3139 3221 2855 4547 2234 1979 4880 3492 -129 1682 364 6383 364 -1919 1200 -2299 -2576 -2012 4721 -6244 353 1917 445 -10058 -4374 -305 2847 -4048 -2582 184 -2462 1938 -3790 -606 374 6570 -5658 -980 849 5365 -9448 5644 5962 -2623 1131 -534 970 3094 3968 1573 3766 -3865 -1835 -3514