File name: Pandora206s1_BuffaloNY_20240208_L2Fit_fwvt1c4d20220512p1-8.txt File generation date: 20241121T073346.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20240208_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20240208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1793 Nominal wavelengths inside fitting window [nm]: 492.0227 492.1437 492.2647 492.3857 492.5066 492.6276 492.7485 492.8694 492.9903 493.1112 493.2321 493.3529 493.4738 493.5946 493.7154 493.8362 493.9569 494.0777 494.1984 494.3191 494.4398 494.5605 494.6812 494.8018 494.9224 495.0430 495.1636 495.2842 495.4048 495.5253 495.6459 495.7664 495.8869 496.0073 496.1278 496.2482 496.3687 496.4891 496.6095 496.7298 496.8502 496.9705 497.0909 497.2112 497.3315 497.4517 497.5720 497.6922 497.8125 497.9327 498.0528 498.1730 498.2932 498.4133 498.5334 498.6535 498.7736 498.8937 499.0137 499.1338 499.2538 499.3738 499.4938 499.6137 499.7337 499.8536 499.9735 500.0934 500.2133 500.3332 500.4530 500.5729 500.6927 500.8125 500.9322 501.0520 501.1717 501.2915 501.4112 501.5309 501.6505 501.7702 501.8898 502.0095 502.1291 502.2487 502.3682 502.4878 502.6073 502.7268 502.8464 502.9658 503.0853 503.2048 503.3242 503.4436 503.5630 503.6824 503.8018 503.9211 504.0404 504.1598 504.2790 504.3983 504.5176 504.6368 504.7561 504.8753 504.9945 505.1136 505.2328 505.3519 505.4711 505.5902 505.7093 505.8283 505.9474 506.0664 506.1854 506.3044 506.4234 506.5424 506.6613 506.7803 506.8992 507.0181 507.1370 507.2558 507.3747 507.4935 507.6123 507.7311 507.8499 507.9687 508.0874 508.2061 508.3248 508.4435 508.5622 508.6808 508.7995 508.9181 509.0367 509.1553 509.2739 509.3924 509.5109 509.6295 509.7480 509.8664 509.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240208T123509.0Z 8804.524410 34 1 3.26 2 88.68 112.13 85.50 132.41 0.00 1 0.00 1 0 29 8.173e-03 8.101e-03 2.261e-03 2.258e-03 7.806806e+03 1.464477e+02 5.464591e+02 -6.000000e+00 4.469362e+02 272.39 -2.00 20.00 -2.00 505.37 0.00e+00 3.555935e-03 6.172875e-05 1.949829e-04 -6.000000e+00 2.255702e-04 272.39 -2.00 20.00 -2.00 500.84 0.00e+00 1.351244e+00 4.439382e-02 6.884191e-02 -6.000000e+00 1.632980e-01 224.41 -2.00 3.55 -2.00 502.38 0.00e+00 18.041 0.113 489.00 513.00 1 3.8700e+00 3.3980e-03 3.0602e-02 -6.0000e+00 1.2511e-02 -1.2973e-02 8.4635e-04 2.2322e-03 -6.0000e+00 3.1963e-03 2.8427e-03 2.8334e-03 2.3452e-04 1.0221e-04 -6.0000e+00 8.9421e-04 -1.2806e-03 6.5170e-05 12 9 9 12 1 1 999.00 17.61 4.40 -0.00128 0.01837 2 25 4 2 0 1084.980 15.00 17.61 6.92 21.17 21.06 20.2 960.44 -2228 -1168 -1058 -229 476 1119 1449 1478 1334 1006 192 -43 -193 -280 -250 -659 -142 127 344 3 861 661 614 299 473 967 431 -74 -497 -1167 -1473 -1029 -1395 8 566 689 570 82 101 -78 -318 248 575 717 633 746 1105 541 220 -489 -930 -1629 -1807 -1409 -1054 -191 165 503 620 955 867 861 928 848 816 509 -51 -675 -561 -885 -564 -1051 -448 -264 192 -146 -682 -915 -1099 -1219 -1071 -1400 -712 -584 -834 -389 -271 7 -639 -235 -472 692 614 960 492 673 140 -345 -617 -1417 -1833 -1319 -737 -484 65 -398 261 -310 -550 -666 -289 408 650 1324 1208 1303 1306 1362 1045 931 -108 189 174 428 784 474 477 917 478 685 840 -123 -619 -763 -565 -528 -305 109 -13 962 806 551 563 614 251 336 -276 -663 -1316 -1371 -1328 -2051 -1079 -1006 -219 455 1089 1432 1444 1305 979 190 -42 -187 -268 -239 -635 -138 123 341 3 849 655 612 301 478 976 436 -74 -492 -1135 -1445 -1008 -1370 8 566 697 576 83 101 -78 -319 250 585 724 648 767 1130 551 221 -495 -922 -1594 -1757 -1376 -1051 -191 168 507 627 966 880 879 952 870 833 515 -51 -673 -564 -883 -557 -1046 -448 -261 190 -145 -671 -908 -1080 -1196 -1051 -1359 -692 -572 -828 -387 -270 7 -639 -235 -466 684 615 959 489 667 136 -335 -588 -1339 -1734 -1261 -709 -473 65 -397 258 -307 -544 -664 -292 416 657 1344 1238 1345 1336 1401 1077 952 -110 193 177 435 800 479 484 928 486 695 846 -123 -619 -773 -563 -533 -314 111 -14 989 840 580 596 653 263 355 -290 -687 -1355 -1409 -1380 SQ 20240208T124127.3Z 8804.528788 41 1 22.00 2 87.62 113.22 84.68 133.51 0.00 1 0.00 1 0 22 5.785e-03 5.742e-03 1.279e-04 1.277e-04 6.979179e+03 8.212145e+00 4.985136e+02 -6.000000e+00 3.163366e+02 272.39 -2.00 20.00 -2.00 505.35 0.00e+00 2.941328e-03 3.481459e-06 1.618178e-04 -6.000000e+00 1.596547e-04 272.39 -2.00 20.00 -2.00 500.74 0.00e+00 1.267164e+00 2.519205e-03 5.884504e-02 -6.000000e+00 1.155684e-01 224.41 -2.00 3.55 -2.00 502.29 0.00e+00 15.151 0.067 489.00 513.00 1 6.8294e-01 1.9272e-04 2.3939e-02 -6.0000e+00 8.8545e-03 -1.1376e-02 4.8232e-05 1.8422e-03 -6.0000e+00 2.2618e-03 1.0441e-01 2.3226e-03 1.3320e-05 8.8780e-05 -6.0000e+00 6.3287e-04 -9.4354e-03 1.2317e-04 12 8 8 10 0 0 5.82 17.61 3.44 -0.00944 0.00668 634 196 2 2 0 28.600 15.00 17.61 7.45 21.17 21.06 20.1 962.32 -1218 -999 -572 29 468 812 1068 1065 971 709 299 -26 -230 -404 -571 -605 -404 -95 265 408 381 427 365 373 504 552 296 146 -120 -636 -909 -837 -584 -39 347 389 250 179 -34 -192 -150 -51 190 397 594 721 641 388 12 -363 -846 -1113 -1312 -1190 -708 -175 219 432 522 562 622 670 671 619 503 321 -6 -316 -366 -539 -655 -596 -469 -268 -76 -147 -486 -741 -865 -905 -868 -714 -621 -500 -288 -294 -259 -270 -233 -223 -83 143 556 757 651 482 177 -230 -530 -969 -1231 -1108 -831 -342 -63 -136 -262 -392 -451 -341 9 299 565 820 1005 1030 1036 1063 825 503 331 189 70 317 434 333 454 499 278 347 365 -84 -373 -450 -570 -406 -51 90 158 414 483 408 433 412 294 176 -33 -447 -866 -1005 -839 -1150 -932 -548 28 463 803 1073 1059 967 702 300 -26 -226 -393 -553 -590 -399 -93 266 415 382 430 369 379 515 565 303 148 -120 -633 -893 -823 -585 -39 350 398 255 181 -34 -193 -151 -52 195 403 609 742 659 396 12 -366 -836 -1101 -1289 -1177 -700 -177 222 442 537 579 629 680 685 632 511 323 -6 -317 -363 -530 -641 -584 -463 -267 -77 -147 -481 -725 -839 -875 -840 -694 -608 -493 -281 -289 -255 -266 -229 -220 -83 143 551 751 652 474 174 -220 -499 -919 -1168 -1045 -806 -337 -62 -136 -262 -390 -448 -340 9 300 573 823 1015 1049 1064 1097 852 516 336 190 70 316 435 335 459 505 281 351 368 -84 -369 -443 -564 -406 -51 91 160 425 500 426 447 427 305 182 -35 -457 -877 -1017 -856 SQ 20240208T124147.7Z 8804.529025 41 2 18.68 2 87.56 113.27 84.63 133.57 0.00 1 0.00 1 0 22 5.757e-03 5.716e-03 1.254e-04 1.253e-04 6.899165e+03 8.054962e+00 4.944866e+02 -6.000000e+00 3.148479e+02 272.39 -2.00 20.00 -2.00 505.35 0.00e+00 2.882091e-03 3.415980e-06 1.586022e-04 -6.000000e+00 1.589040e-04 272.39 -2.00 20.00 -2.00 500.74 0.00e+00 1.260333e+00 2.472098e-03 5.789953e-02 -6.000000e+00 1.150302e-01 224.41 -2.00 3.55 -2.00 502.29 0.00e+00 15.001 0.065 489.00 513.00 1 6.6950e-01 1.8917e-04 2.3621e-02 -6.0000e+00 8.8132e-03 -1.0997e-02 4.7320e-05 1.8186e-03 -6.0000e+00 2.2514e-03 1.0821e-01 2.2801e-03 1.3088e-05 8.7079e-05 -6.0000e+00 6.2992e-04 -2.1098e-03 7.4766e-05 12 8 8 10 0 0 -7.42 17.61 3.40 -0.00211 0.01371 634 196 2 2 0 28.600 15.00 17.61 7.45 21.17 21.06 20.0 962.91 -1237 -993 -576 77 445 823 1050 1075 986 704 266 -37 -239 -401 -601 -585 -415 -126 270 387 378 414 391 357 533 530 317 115 -104 -654 -922 -829 -581 -23 339 405 260 183 -26 -174 -153 -58 168 409 595 716 641 377 30 -376 -800 -1101 -1314 -1179 -679 -190 241 431 512 542 628 682 679 599 506 303 -24 -315 -363 -516 -669 -603 -432 -268 -73 -152 -466 -733 -838 -917 -882 -707 -614 -485 -276 -274 -219 -244 -239 -219 -101 155 559 775 623 503 179 -204 -539 -967 -1211 -1094 -843 -388 -54 -133 -238 -394 -446 -332 13 276 560 826 1003 1018 1017 1016 818 504 317 216 72 311 413 346 450 504 278 359 398 -61 -388 -461 -570 -439 -27 70 155 396 467 403 437 414 304 182 -36 -433 -855 -984 -860 -1169 -928 -552 75 432 815 1057 1072 985 699 262 -36 -235 -390 -583 -571 -410 -124 272 387 380 418 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