File name: Pandora206s1_BuffaloNY_20240327_L2Fit_fout2c4d20220512p1-8.txt File generation date: 20241121T074925.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20240327_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20240327 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2154 305.3564 305.4973 305.6383 305.7792 305.9201 306.0611 306.2020 306.3428 306.4837 306.6246 306.7654 306.9063 307.0471 307.1879 307.3287 307.4695 307.6103 307.7511 307.8918 308.0326 308.1733 308.3140 308.4548 308.5955 308.7362 308.8768 309.0175 309.1582 309.2988 309.4394 309.5801 309.7207 309.8613 310.0019 310.1424 310.2830 310.4236 310.5641 310.7046 310.8451 310.9857 311.1261 311.2666 311.4071 311.5476 311.6880 311.8285 311.9689 312.1093 312.2497 312.3901 312.5305 312.6708 312.8112 312.9515 313.0919 313.2322 313.3725 313.5128 313.6531 313.7934 313.9336 314.0739 314.2141 314.3543 314.4946 314.6348 314.7750 314.9151 315.0553 315.1955 315.3356 315.4758 315.6159 315.7560 315.8961 316.0362 316.1763 316.3163 316.4564 316.5964 316.7364 316.8765 317.0165 317.1565 317.2964 317.4364 317.5764 317.7163 317.8563 317.9962 318.1361 318.2760 318.4159 318.5558 318.6956 318.8355 318.9753 319.1152 319.2550 319.3948 319.5346 319.6744 319.8141 319.9539 320.0937 320.2334 320.3731 320.5128 320.6525 320.7922 320.9319 321.0716 321.2112 321.3509 321.4905 321.6301 321.7697 321.9093 322.0489 322.1885 322.3280 322.4676 322.6071 322.7467 322.8862 323.0257 323.1652 323.3046 323.4441 323.5836 323.7230 323.8624 324.0018 324.1413 324.2806 324.4200 324.5594 324.6988 324.8381 324.9774 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240327T155623.5Z 8852.664161 340 1 24.01 2 44.18 149.12 132.78 293.01 0.00 1 0.00 1 0 17 8.150e-02 2.497e-02 6.672e-02 1.785e-02 2.500878e-01 8.797287e-03 3.061058e-03 -6.000000e+00 4.542469e-02 226.85 -2.00 3.55 -2.00 317.53 0.00e+00 -1.263963e-03 1.297463e-03 1.302073e-04 -6.000000e+00 1.959795e-03 275.89 -2.00 20.00 -2.00 316.90 0.00e+00 1.392 0.000 302.00 328.00 3 8.4656e+00 2.3326e-02 1.8941e-02 -6.0000e+00 1.1293e-01 7.1958e-02 2.6314e-02 1.2993e-02 -6.0000e+00 1.2305e-01 2.4851e-02 1.6157e-02 6.4740e-03 -6.0000e+00 7.3049e-02 -2.1637e-02 8.1009e-03 2.0533e-03 -6.0000e+00 3.0925e-02 2.0126e-05 -6.4890e-04 4.9692e-04 2.1212e-05 -6.0000e+00 2.0768e-03 -5.4381e-03 2.5886e-04 12 8 8 10 0 0 -317.95 17.72 1.34 -0.00544 -0.01031 6 6 2 8 0 4000.000 15.00 17.72 13.33 21.27 21.17 20.6 1001.72 -14903 10695 -16364 35443 4767 25341 9800 7343 20229 3482 49730 5051 7425 2940 14546 -16012 22265 1369 3315 -5298 18887 -705 12584 5078 -9139 654 -2041 16331 -15493 7491 -7434 2068 -7218 1493 -5590 -6630 -2189 -3038 4799 -4093 -488 -4300 7154 -2656 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2628 897 684 -263 4909 -1837 481 -3983 1537 -5225 2227 1121 1252 393 3089 1408 -3484 1171 -4592 3117 -2966 -491 -6106 2997 -631 -1739 -487 773 1201 -2557 -430 924 1739 -1554 4812 -406 2335 -2002 753 -1748 922 1181 2141 2383 -1135 -1669 -2141 SS 20240327T165816.4Z 8852.707134 376 1 24.01 2 40.32 171.48 142.25 309.15 0.00 1 0.00 1 0 17 2.338e-02 1.308e-02 2.067e-02 8.001e-03 2.247509e-01 3.941887e-03 2.710534e-03 -6.000000e+00 1.303143e-02 226.85 -2.00 3.55 -2.00 316.91 0.00e+00 1.323802e-03 5.017257e-04 7.912886e-05 -6.000000e+00 5.623287e-04 275.89 -2.00 20.00 -2.00 316.30 0.00e+00 1.310 0.000 302.00 328.00 3 7.6278e+00 1.0334e-02 1.7359e-02 -6.0000e+00 3.2398e-02 5.6770e-02 1.1616e-02 1.1637e-02 -6.0000e+00 3.5303e-02 -6.6441e-03 6.8526e-03 5.7083e-03 -6.0000e+00 2.0957e-02 1.0975e-03 3.3089e-03 1.9073e-03 -6.0000e+00 8.8722e-03 5.3228e-05 3.4530e-04 2.2088e-04 1.8467e-05 -6.0000e+00 5.9602e-04 -7.5698e-03 1.3320e-04 12 8 8 10 0 0 99.46 17.71 1.16 -0.00757 -0.00498 6 6 2 8 0 4000.000 15.00 17.71 13.48 21.27 21.17 21.0 1005.63 -8390 2378 2933 8536 -6163 2244 -3735 2489 -4553 1029 2235 6134 -2633 648 1933 -1420 5035 196 -3082 -2107 5387 1458 3592 -3836 1133 -2665 2002 1916 -8160 -1713 -1036 2568 -414 292 -3347 -460 -2687 -132 1374 -726 -1102 -682 -17 -692 2037 -1265 -1337 -3585 -1189 -1674 1408 367 830 2024 7297 -760 1392 854 -1162 -30 -123 3246 527 -790 -37 2618 -1993 -1023 -736 -649 512 3597 1996 1544 589 -806 -2169 -2789 -2802 -2590 -725 -600 -3123 -1476 268 998 104 539 712 943 -463 480 -1149 -2225 -1453 -71 1283 1065 139 586 1036 -675 -1411 -1212 517 -1292 -1126 50 781 344 1136 377 -384 -450 -1243 412 -3057 745 -456 1202 -126 -105 814 109 1489 -293 -682 887 1441 1238 596 158 419 -2423 -196 22 206 852 846 179 -565 -1106 -694 -1318 364 456 1201 -867 277 -518 359 -782 175 362 965 -510 138 463 -386 1317 55 -933 -652 1568 431 1058 -1281 373 -942 674 600 -2593 -503 -321 816 -147 106 -1141 -154 -978 -54 665 -405 -667 -424 -11 -446 1269 -814 -840 -2228 -726 -1021 881 239 563 1429 5003 -570 1040 635 -861 -22 -93 2548 460 -720 -32 2115 -1560 -794 -586 -590 485 3427 1921 1481 528 -653 -1660 -2029 -2140 -2233 -663 -603 -3296 -1593 305 1212 129 689 910 1149 -541 522 -1153 -2175 -1499 -80 1523 1363 188 766 1301 -793 -1624 -1414 650 -1730 -1523 70 1132 516 1775 595 -580 -647 -1694 519 -3996 981 -635 1760 -191 -155 1169 155 1967 -388 -856 1106 1918 1694 860 234 624 -3735 -315 37 342 1440 1434 304 -935 -1776 -1085 SS 20240327T170804.4Z 8852.713940 382 1 7.62 2 40.11 175.25 143.59 312.22 0.00 1 0.00 1 0 17 9.739e-03 6.365e-03 5.474e-03 2.655e-03 2.061922e-01 1.315124e-03 2.533824e-03 -6.000000e+00 5.427205e-03 226.85 -2.00 3.55 -2.00 316.26 0.00e+00 6.171487e-04 1.439672e-04 4.797400e-05 -6.000000e+00 2.342012e-04 275.90 -2.00 20.00 -2.00 315.68 0.00e+00 1.306 0.000 302.00 328.00 3 4.7295e+00 3.4175e-03 1.6698e-02 -6.0000e+00 1.3493e-02 1.9352e-02 3.8294e-03 1.0662e-02 -6.0000e+00 1.4703e-02 -4.6190e-03 2.2198e-03 5.2624e-03 -6.0000e+00 8.7283e-03 -1.1931e-03 1.0356e-03 1.5555e-03 -6.0000e+00 3.6948e-03 1.0277e-03 1.9592e-04 7.2598e-05 1.7066e-05 -6.0000e+00 2.4824e-04 -7.0841e-03 1.3859e-04 12 1 1 12 1 1 99.99 17.71 0.24 -0.00708 -0.00561 14 28 1 8 0 507.380 15.00 17.71 14.23 21.27 21.17 21.1 1010.53 -656 -992 411 -2553 -1974 -3966 1222 -1229 1876 -2726 -623 -1669 -727 -575 -416 -401 -242 1116 747 1824 -53 1699 1 1797 -811 1052 138 236 -773 -150 1282 91 3010 -1986 -769 -2264 -857 -1546 421 -545 -649 -995 -253 -1348 -487 -268 -734 53 -858 717 497 1094 548 1013 490 997 1031 1073 455 675 892 1023 1387 1376 23 43 -484 -1322 290 493 308 23 500 645 -95 -42 -559 -215 -1037 -350 -1061 -911 -2334 -1188 -1332 -696 -285 103 447 -260 447 161 483 150 616 133 858 764 -345 -438 253 -572 -855 403 -583 -689 -714 -612 -315 398 586 435 -68 208 -267 241 116 285 65 -289 -280 9 295 -68 1264 273 704 917 307 429 328 237 -91 -151 -24 -28 -105 208 -63 -144 -464 -229 -747 -129 -212 88 -521 -345 -676 218 -240 395 -631 -136 -369 -178 -159 -125 -131 -81 378 262 654 -20 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