File name: Pandora206s1_BuffaloNY_20240421_L2Fit_fout2c4d20220512p1-8.txt File generation date: 20241121T080123.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20240421_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20240421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0744 305.2154 305.3564 305.4973 305.6383 305.7792 305.9201 306.0611 306.2020 306.3428 306.4837 306.6246 306.7654 306.9063 307.0471 307.1879 307.3287 307.4695 307.6103 307.7511 307.8918 308.0326 308.1733 308.3140 308.4548 308.5955 308.7362 308.8768 309.0175 309.1582 309.2988 309.4394 309.5801 309.7207 309.8613 310.0019 310.1424 310.2830 310.4236 310.5641 310.7046 310.8451 310.9857 311.1261 311.2666 311.4071 311.5476 311.6880 311.8285 311.9689 312.1093 312.2497 312.3901 312.5305 312.6708 312.8112 312.9515 313.0919 313.2322 313.3725 313.5128 313.6531 313.7934 313.9336 314.0739 314.2141 314.3543 314.4946 314.6348 314.7750 314.9151 315.0553 315.1955 315.3356 315.4758 315.6159 315.7560 315.8961 316.0362 316.1763 316.3163 316.4564 316.5964 316.7364 316.8765 317.0165 317.1565 317.2964 317.4364 317.5764 317.7163 317.8563 317.9962 318.1361 318.2760 318.4159 318.5558 318.6956 318.8355 318.9753 319.1152 319.2550 319.3948 319.5346 319.6744 319.8141 319.9539 320.0937 320.2334 320.3731 320.5128 320.6525 320.7922 320.9319 321.0716 321.2112 321.3509 321.4905 321.6301 321.7697 321.9093 322.0489 322.1885 322.3280 322.4676 322.6071 322.7467 322.8862 323.0257 323.1652 323.3046 323.4441 323.5836 323.7230 323.8624 324.0018 324.1413 324.2806 324.4200 324.5594 324.6988 324.8381 324.9774 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240421T130107.9Z 8877.542453 236 1 24.01 2 62.21 99.58 126.61 310.10 0.00 1 0.00 1 0 17 4.133e-01 4.327e-02 2.892e-01 2.593e-02 3.836363e-01 1.328334e-02 4.688477e-03 -6.000000e+00 2.340677e-01 228.86 -2.00 3.55 -2.00 319.22 0.00e+00 4.206487e-03 3.354172e-03 1.603553e-03 -6.000000e+00 1.142775e-02 278.69 -2.00 20.00 -2.00 318.60 0.00e+00 2.134 0.000 302.00 328.00 3 7.9976e+00 3.7085e-02 3.0719e-02 -6.0000e+00 5.8681e-01 1.1032e-01 4.3086e-02 2.4791e-02 -6.0000e+00 6.3913e-01 2.1456e-02 3.3239e-02 9.9868e-03 -6.0000e+00 3.7715e-01 -2.0275e-02 1.7628e-02 5.8080e-03 -6.0000e+00 1.6246e-01 1.1997e-05 4.2075e-04 7.4158e-04 3.9688e-05 -6.0000e+00 1.0982e-02 -1.0578e-02 3.9887e-04 12 8 8 10 0 0 -41.27 18.02 3.49 -0.01058 -0.00742 6 6 2 8 0 4000.000 15.00 18.02 12.61 21.58 21.48 20.9 987.22 -88229 900000 900000 900000 -13569 278983 70510 900000 91481 900000 900000 59687 147038 133927 900000 -8486 154176 -19112 88773 -15062 146307 -15686 70620 3311 34985 -5357 -2350 36003 -10786 28007 4807 56746 -16767 55429 -22825 20980 -12483 17735 26303 -6006 31551 -10478 18465 -8115 4751 3505 1504 -21005 36909 5349 15928 -9123 2909 4265 1622 1139 6678 12064 -4280 11845 -36634 12663 -4862 8212 -2182 3388 -4126 3592 2591 -6223 7831 847 10543 3157 5629 -2493 5496 -19870 -7995 -6457 2625 2209 -1577 -190 -2974 3088 1515 186 -2979 9278 -1666 3574 -2432 1868 -2253 1985 2236 1196 3942 2133 2064 -3072 518 -4047 6104 -4772 74 2794 391 295 1627 -863 -3385 -1660 -4822 746 -2441 2149 -3589 1036 -1144 2229 640 2158 641 -338 -1649 2184 -178 -1645 4101 -1089 296 -3130 2582 -616 676 -966 1902 1101 1081 -1658 -1502 -5403 900000 900000 900000 -418 7047 1781 900000 2311 900000 900000 1508 3714 3383 900000 -697 3894 -2006 3472 -1688 3696 -1783 3568 337 2794 -647 -280 2875 -1301 2350 572 4485 -3004 5284 -4270 2530 -2246 2818 4629 -1678 6890 -3540 4883 -2857 1478 1120 489 -8506 8661 1697 5061 -3925 1180 1821 737 529 2994 5085 -2068 4980 -25071 5943 -2913 4719 -1410 1920 -2384 1955 1522 -4445 5335 643 7207 2213 3660 -1566 2902 -13049 -4996 -4587 1934 1825 -1405 -174 -2998 3134 1637 210 -3473 9161 -1684 3244 -2166 1563 -2124 2015 2467 1502 5134 2763 2496 -3672 550 -4633 6893 -6095 97 3651 554 452 2640 -1466 -5705 -2573 -7095 1008 -3413 2998 -5496 1601 -1818 3438 976 3089 881 -449 -2105 2731 -250 -2533 6343 -1838 504 -5564 4627 -1194 1317 -1955 3742 2097 2028 -3056 -2685 SS 20240421T140414.6Z 8877.586280 277 1 24.01 2 51.12 112.47 134.17 327.49 0.00 1 0.00 1 0 17 1.349e-01 2.292e-02 7.570e-02 1.350e-02 3.006148e-01 6.689154e-03 3.586490e-03 -6.000000e+00 7.582643e-02 228.86 -2.00 3.55 -2.00 318.17 0.00e+00 2.662475e-03 1.201998e-03 1.215474e-04 -6.000000e+00 3.282976e-03 278.69 -2.00 20.00 -2.00 317.50 0.00e+00 1.590 0.000 302.00 328.00 3 7.8677e+00 1.8011e-02 2.2357e-02 -6.0000e+00 1.8924e-01 8.0849e-02 2.0447e-02 1.6013e-02 -6.0000e+00 2.0575e-01 -2.3171e-02 1.3171e-02 7.8329e-03 -6.0000e+00 1.2214e-01 8.7281e-03 6.7581e-03 3.1813e-03 -6.0000e+00 5.1651e-02 2.7260e-05 6.6312e-05 3.7583e-04 2.8261e-05 -6.0000e+00 3.4401e-03 -1.1204e-02 1.8944e-04 12 8 8 10 0 0 93.33 18.02 1.52 -0.01120 -0.01071 6 6 2 8 0 4000.000 15.00 18.02 14.75 21.58 21.48 21.2 1002.39 -41051 30550 4173 40158 32600 -4728 46359 6672 53865 18443 77618 -12588 7497 -59853 13883 122 33716 7442 7726 2231 23768 10890 3375 5531 -6437 11928 -5006 4472 -15131 2197 17323 14938 -4206 6781 -2517 -4914 -1631 -3280 11762 -5154 4103 -2394 8964 -5900 8070 -4635 -753 -12258 3668 1255 2736 67 -2752 5535 1040 5645 -1905 2645 -2949 1528 -689 2453 -54 920 -235 -1193 291 -3345 1540 -4086 5881 -2103 3043 1078 3235 -1722 -312 -1968 -4029 -2116 -479 2415 -3916 958 -1201 392 -969 1045 -1106 2403 -265 -753 657 -2565 -1020 -303 2750 -237 1124 -1571 2064 -3158 208 -1782 785 -1547 -347 558 537 1258 786 1780 -1855 738 -1300 1009 -2382 470 -801 500 -534 -799 282 -646 2972 113 1736 -722 1339 -1589 2320 -718 290 -1184 404 -270 678 293 611 243 -351 -126 -1683 -4292 1785 330 2150 1634 -327 2029 479 2677 1379 3237 -1283 723 -12445 1657 19 4011 1167 1262 399 3605 1837 604 1055 -1391 2296 -1149 876 -3349 410 3025 2900 -1088 1639 -612 -1184 -419 -987 3658 -2163 1712 -1108 3841 -2967 3634 -2310 -355 -6356 1650 581 1330 36 -1553 3043 616 3336 -1198 1626 -1868 918 -437 1631 -39 709 -183 -858 198 -2311 1077 -3356 4785 -1926 2630 909 2548 -1270 -205 -1255 -2774 -1633 -409 2154 -3965 961 -1322 454 -1159 1263 -1370 2836 -295 -767 624 -2442 -1024 -326 3197 -308 1527 -2132 2602 -3839 235 -2066 971 -2051 -475 795 781 1946 1295 2938 -3049 1098 -1862 1327 -3245 650 -1206 767 -837 -1230 432 -951 3987 153 2198 -947 1863 -2363 3501 -1149 467 -2008 698 -491 1246 554 1155 444 -619 -220 -2899 SS 20240421T150729.5Z 8877.630203 315 1 24.01 2 41.16 128.97 138.58 348.69 0.00 1 0.00 1 0 17 7.837e-02 1.886e-02 8.654e-02 1.891e-02 2.749025e-01 9.387419e-03 3.497156e-03 -6.000000e+00 4.401309e-02 228.87 -2.00 3.55 -2.00 317.91 0.00e+00 2.897447e-03 1.548996e-03 7.752646e-04 -6.000000e+00 1.906582e-03 278.70 -2.00 20.00 -2.00 317.25 0.00e+00 1.327 0.000 302.00 328.00 3 8.5198e+00 2.5133e-02 2.0118e-02 -6.0000e+00 1.0984e-01 8.1180e-02 2.8367e-02 1.6021e-02 -6.0000e+00 1.1945e-01 1.2120e-02 1.7905e-02 7.1539e-03 -6.0000e+00 7.0909e-02 -1.5596e-02 9.1578e-03 3.2263e-03 -6.0000e+00 2.9971e-02 1.8818e-05 -2.3732e-03 5.2702e-04 2.9667e-05 -6.0000e+00 1.9983e-03 -9.6077e-03 1.1051e-04 12 8 8 10 0 0 46.63 18.02 2.35 -0.00961 -0.02744 6 6 2 8 0 4000.000 15.00 18.02 13.39 21.58 21.48 21.0 993.22 -35138 27362 27480 17751 23726 16478 18082 9786 -560 32009 25731 2385 -2270 16942 19724 6000 13019 -6169 2214 524 197 -11091 22345 2375 1043 -3135 -2673 6054 -4684 3121 -1211 1957 -6905 1062 -3946 5621 -4270 344 -1629 -1067 3192 -3773 2448 -853 2590 -2217 -5146 -10908 4972 -1355 1535 1508 -2500 2914 5679 -2416 -3146 3754 -489 -4609 -2293 2554 -1235 1658 -503 -1735 541 -3359 474 -4028 3145 336 4217 1473 4123 -2285 2972 -3268 -2718 -151 470 -1453 -3065 168 64 1444 1619 855 493 2196 418 317 1958 -5241 -1706 -103 2734 1873 2108 1890 1040 -122 -878 -2802 1397 -2699 -478 208 202 583 320 481 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