File name: Pandora206s1_BuffaloNY_20241014_L2Fit_fwvt1c4d20220512p1-8.txt File generation date: 20241121T094227.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v4d20220512.txt Level 1 file used: Pandora206s1_BuffaloNY_20241014_L1_smca1c4d20220512p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: Canada Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20241014 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1793 Nominal wavelengths inside fitting window [nm]: 492.0227 492.1437 492.2647 492.3857 492.5066 492.6276 492.7485 492.8694 492.9903 493.1112 493.2321 493.3529 493.4738 493.5946 493.7154 493.8362 493.9569 494.0777 494.1984 494.3191 494.4398 494.5605 494.6812 494.8018 494.9224 495.0430 495.1636 495.2842 495.4048 495.5253 495.6459 495.7664 495.8869 496.0073 496.1278 496.2482 496.3687 496.4891 496.6095 496.7298 496.8502 496.9705 497.0909 497.2112 497.3315 497.4517 497.5720 497.6922 497.8125 497.9327 498.0528 498.1730 498.2932 498.4133 498.5334 498.6535 498.7736 498.8937 499.0137 499.1338 499.2538 499.3738 499.4938 499.6137 499.7337 499.8536 499.9735 500.0934 500.2133 500.3332 500.4530 500.5729 500.6927 500.8125 500.9322 501.0520 501.1717 501.2915 501.4112 501.5309 501.6505 501.7702 501.8898 502.0095 502.1291 502.2487 502.3682 502.4878 502.6073 502.7268 502.8464 502.9658 503.0853 503.2048 503.3242 503.4436 503.5630 503.6824 503.8018 503.9211 504.0404 504.1598 504.2790 504.3983 504.5176 504.6368 504.7561 504.8753 504.9945 505.1136 505.2328 505.3519 505.4711 505.5902 505.7093 505.8283 505.9474 506.0664 506.1854 506.3044 506.4234 506.5424 506.6613 506.7803 506.8992 507.0181 507.1370 507.2558 507.3747 507.4935 507.6123 507.7311 507.8499 507.9687 508.0874 508.2061 508.3248 508.4435 508.5622 508.6808 508.7995 508.9181 509.0367 509.1553 509.2739 509.3924 509.5109 509.6295 509.7480 509.8664 509.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241014T143312.5Z 9053.606395 207 1 24.00 2 61.48 137.41 146.93 359.10 0.00 1 0.00 1 0 15 3.367e-03 3.347e-03 1.873e-03 1.867e-03 1.639592e+03 1.125498e+02 1.227852e+02 -6.000000e+00 1.909077e+02 281.68 -2.00 20.00 -2.00 505.24 0.00e+00 4.776659e-04 5.163154e-05 2.612016e-05 -6.000000e+00 9.509179e-05 281.68 -2.00 20.00 -2.00 500.26 0.00e+00 1.650864e-01 3.735158e-02 1.193443e-02 -6.000000e+00 6.707690e-02 225.54 -2.00 3.55 -2.00 501.88 0.00e+00 2.084 0.000 489.00 513.00 1 8.1493e+00 2.8730e-03 3.1516e-03 -6.0000e+00 5.1550e-03 1.0442e-02 7.3190e-04 3.2444e-04 -6.0000e+00 1.3161e-03 4.1483e-04 2.5179e-03 1.9868e-04 1.6491e-05 -6.0000e+00 3.6841e-04 -4.0778e-02 1.6496e-04 10 0 0 10 0 0 99.83 18.08 2.34 -0.04078 -0.02331 6 6 2 2 0 4000.000 14.99 18.08 12.91 21.58 21.48 23.2 907.55 -893 -354 -264 -298 276 388 512 435 463 222 122 -176 15 -104 51 -534 -185 -245 -75 139 144 279 351 244 448 541 77 -196 413 -434 -617 -270 -566 240 176 442 139 126 257 -495 -247 -111 11 -197 -13 306 430 207 24 -6 -599 -418 -302 -1049 -429 -286 73 277 122 670 174 367 453 240 -79 97 201 -23 86 -107 -34 -164 -117 -209 -101 -237 -137 -486 -350 -367 -33 -292 -158 108 -138 117 -283 -65 -147 45 150 -16 202 201 359 -18 82 101 26 -443 -272 -736 -558 -476 729 -92 -189 -397 -493 -360 373 -124 487 391 579 201 520 302 287 385 -107 -19 -97 162 220 55 167 -250 423 27 500 -78 -232 -116 -507 -565 172 30 -123 282 321 504 121 337 86 105 -2 -27 -498 -685 -362 -889 -353 -269 -305 290 416 543 467 497 238 129 -183 16 -108 52 -554 -194 -255 -79 150 157 302 380 258 474 573 81 -212 433 -447 -624 -271 -579 250 184 466 146 131 273 -524 -260 -115 11 -207 -14 323 452 215 25 -6 -604 -410 -300 -1023 -424 -290 73 283 125 682 178 376 465 247 -81 99 200 -23 86 -105 -33 -160 -115 -208 -99 -232 -136 -476 -338 -353 -32 -282 -154 103 -133 114 -277 -63 -144 44 148 -16 199 199 353 -18 81 97 24 -420 -256 -684 -530 -455 705 -90 -185 -385 -474 -345 359 -122 481 391 568 199 515 300 283 375 -103 -18 -94 156 213 53 162 -244 409 26 478 -74 -217 -107 -469 -527 162 29 -117 271 310 489 118 330 84 102 -2 -25 -463 -632 -334 SQ 20241014T144136.0Z 9053.612223 211 1 27.08 2 60.46 139.48 146.86 2.71 0.00 1 0.00 1 0 15 2.881e-03 2.882e-03 6.453e-04 6.437e-04 1.052054e+03 3.771079e+01 7.731361e+01 -6.000000e+00 1.633428e+02 281.68 -2.00 20.00 -2.00 505.24 0.00e+00 4.995611e-04 1.778063e-05 2.804898e-05 -6.000000e+00 8.135771e-05 281.68 -2.00 20.00 -2.00 500.33 0.00e+00 2.008594e-01 1.280073e-02 8.897128e-03 -6.000000e+00 5.737077e-02 225.54 -2.00 3.55 -2.00 501.94 0.00e+00 2.019 0.000 489.00 513.00 1 6.2149e+00 9.8435e-04 2.9984e-03 -6.0000e+00 4.4094e-03 2.7700e-03 2.5128e-04 2.4761e-04 -6.0000e+00 1.1251e-03 2.8916e-03 1.7432e-03 6.8730e-05 1.3610e-05 -6.0000e+00 3.1528e-04 -4.2592e-02 2.0994e-04 10 0 0 10 0 0 97.17 18.08 2.30 -0.04259 -0.03050 31 31 1 2 0 873.440 15.00 18.08 13.26 21.58 21.48 23.3 909.71 -678 -613 -441 -137 136 404 550 479 579 422 113 4 -168 -143 -313 -454 -103 -163 51 150 233 216 299 185 304 289 160 -117 -2 -221 -410 -315 -376 -68 292 274 98 145 69 -143 -110 -105 25 145 196 396 279 254 55 -236 -485 -598 -607 -724 -460 -212 17 215 228 236 444 475 468 279 315 208 121 -136 -168 -149 -234 -244 -178 -171 -7 -31 -98 -362 -346 -343 -392 -342 -228 -283 -52 -4 -55 -64 -124 -107 -44 -98 196 383 298 198 211 -41 -126 -261 -589 -512 -405 -239 79 -92 -87 -254 -158 -146 123 100 243 379 465 431 427 333 263 198 136 69 -104 66 149 170 123 273 176 49 235 22 -322 -164 -323 -217 71 13 -15 82 310 191 278 220 70 48 67 -129 -387 -536 -441 -675 -614 -440 -141 140 426 576 508 615 445 118 4 -175 -147 -319 -464 -106 -171 54 160 250 232 322 195 320 305 168 -125 -2 -225 -419 -321 -380 -70 303 289 103 151 71 -149 -115 -108 26 151 206 417 293 264 56 -242 -486 -598 -598 -715 -452 -214 17 219 233 241 452 486 480 287 322 210 120 -136 -167 -146 -228 -238 -175 -170 -7 -30 -97 -352 -333 -329 -377 -330 -222 -271 -50 -4 -54 -63 -122 -105 -44 -97 195 383 297 195 208 -40 -120 -249 -558 -490 -388 -230 77 -92 -86 -249 -153 -142 120 99 239 376 465 433 431 336 264 196 133 66 -100 63 144 164 119 262 169 47 224 21 -306 -154 -302 -205 68 12 -15 80 299 185 271 215 68 47 65 -124 -366 -504 -416 SQ 20241014T145956.3Z 9053.624957 218 1 13.24 2 58.39 144.17 146.41 10.50 0.00 1 0.00 1 0 15 2.941e-03 2.934e-03 3.410e-04 3.402e-04 9.029962e+02 1.982910e+01 6.645567e+01 -6.000000e+00 1.667422e+02 281.68 -2.00 20.00 -2.00 505.25 0.00e+00 5.244238e-04 9.408352e-06 2.926147e-05 -6.000000e+00 8.305517e-05 281.68 -2.00 20.00 -2.00 500.34 0.00e+00 1.574295e-01 6.770181e-03 7.950294e-03 -6.000000e+00 5.858085e-02 225.54 -2.00 3.55 -2.00 501.95 0.00e+00 1.901 0.000 489.00 513.00 1 4.2426e+00 5.2072e-04 2.8288e-03 -6.0000e+00 4.5021e-03 2.3892e-03 1.3288e-04 2.2105e-04 -6.0000e+00 1.1492e-03 2.1194e-02 2.1500e-03 3.6292e-05 1.3306e-05 -6.0000e+00 3.2180e-04 -4.1636e-02 1.8026e-04 12 1 1 12 1 1 99.81 18.08 2.33 -0.04164 -0.02672 98 107 1 2 0 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