File name: Pandora206s1_BuffaloNY_20241212_L2Fit_fout2c6d20240814p1-8.txt
File generation date: 20241213T051448.6Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: Kang Sun
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 206
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora206_OF_v3d20211008.txt
Instrument calibration file used: Pandora206s1_CF_v6d20240814.txt
Level 1 file used: Pandora206s1_BuffaloNY_20241212_L1_smca1c6d20240814p1-8.txt
Full location name: University at Buffalo
Short location name: BuffaloNY
Country of location: United States
Location latitude [deg]: 43.0015
Location longitude [deg]: -78.7869
Location altitude [m]: 190
Local noon date: 20241212
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0348 305.1758 305.3167 305.4577 305.5987 305.7396 305.8805 306.0215 306.1624 306.3033 306.4442 306.5850 306.7259 306.8668 307.0076 307.1484 307.2893 307.4301 307.5709 307.7117 307.8524 307.9932 308.1340 308.2747 308.4154 308.5561 308.6968 308.8375 308.9782 309.1189 309.2596 309.4002 309.5408 309.6815 309.8221 309.9627 310.1033 310.2438 310.3844 310.5250 310.6655 310.8060 310.9466 311.0871 311.2276 311.3681 311.5085 311.6490 311.7894 311.9299 312.0703 312.2107 312.3511 312.4915 312.6319 312.7723 312.9126 313.0530 313.1933 313.3336 313.4740 313.6143 313.7545 313.8948 314.0351 314.1753 314.3156 314.4558 314.5960 314.7362 314.8764 315.0166 315.1568 315.2970 315.4371 315.5772 315.7174 315.8575 315.9976 316.1377 316.2777 316.4178 316.5579 316.6979 316.8379 316.9780 317.1180 317.2580 317.3980 317.5379 317.6779 317.8178 317.9578 318.0977 318.2376 318.3775 318.5174 318.6573 318.7972 318.9370 319.0769 319.2167 319.3565 319.4963 319.6361 319.7759 319.9157 320.0554 320.1952 320.3349 320.4747 320.6144 320.7541 320.8938 321.0335 321.1731 321.3128 321.4524 321.5921 321.7317 321.8713 322.0109 322.1505 322.2900 322.4296 322.5692 322.7087 322.8482 322.9877 323.1272 323.2667 323.4062 323.5457 323.6851 323.8246 323.9640 324.1034 324.2428 324.3822 324.5216 324.6610 324.8003 324.9397
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Spectrometer control temperature [°C], 999=no temperature signal
Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 96: Temperature in head sensor [°C], 999=no temperature signal
Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20241212T143546.8Z 9112.608181 236 1 27.60 2 74.96 143.79 118.78 1.79 0.00 1 0.00 1 0 17 2.201e-01 9.318e-03 2.084e-01 6.515e-03 5.932222e-01 3.366547e-03 6.959084e-03 -6.000000e+00 1.226053e-01 222.35 -2.00 3.55 -2.00 320.51 0.00e+00 2.215579e-03 1.267555e-03 1.787065e-03 -6.000000e+00 5.863543e-03 274.60 -2.00 20.00 -2.00 320.01 0.00e+00 3.781 0.001 302.00 328.00 3 4.1677e+00 1.0048e-02 4.8929e-02 -6.0000e+00 3.0266e-01 3.5173e-02 1.3038e-02 3.3887e-02 -6.0000e+00 3.3117e-01 -8.2029e-03 1.3523e-02 1.6318e-02 -6.0000e+00 1.9525e-01 -1.0907e-02 6.8512e-03 5.8619e-03 -6.0000e+00 8.4737e-02 1.0139e-04 -7.4311e-04 1.7851e-04 5.3956e-05 -6.0000e+00 5.8294e-03 -9.8803e-04 0.0000e+00 11 8 0 10 0 0 99.70 17.83 0.33 -0.00099 -0.00657 9 9 4 8 0 3066.260 15.00 17.83 -0.09 21.48 21.27 22.2 868.77 -94035 900000 900000 12305 900000 -86408 900000 -129050 900000 -67997 900000 -35449 119351 -14786 -15389 9031 8559 -2909 40793 1005 -22571 113 -34300 25204 -23010 -5652 -26764 17051 -13663 36195 7455 7850 -9080 -4773 4629 -10331 -278 -2059 28315 -11976 4391 -182 10817 -6219 5298 -4990 -6436 -8521 4878 10377 1757 5635 -1218 9498 1283 2181 -1027 -33 -1206 -4327 2427 1225 948 1153 594 -2208 -263 -2863 2441 -2057 5436 -1145 1203 1332 1849 690 -882 1784 -3172 180 -2049 -2759 -3201 283 -1261 1410 794 -114 -102 756 -24 544 1569 -874 513 -379 350 315 953 -463 762 -640 128 340 -361 -730 -1289 196 -866 390 96 740 -1195 176 -129 1001 -384 -6 -285 -92 -324 -1085 689 31 -926 1191 1004 772 1156 -897 719 392 84 -233 -23 -585 170 261 -60 269 -230 -341 -146 -776 900000 900000 78 900000 -768 900000 -2087 900000 -791 900000 -337 757 -185 -244 138 148 -63 621 24 -716 3 -1262 565 -905 -200 -1217 487 -509 887 279 347 -555 -311 263 -656 -18 -155 1929 -1447 515 -24 1355 -954 730 -780 -1041 -1443 752 1593 326 1128 -285 2182 341 597 -291 -9 -344 -1243 665 371 316 435 240 -887 -101 -1146 997 -1020 2712 -641 656 709 899 302 -360 724 -1434 93 -1228 -1907 -2378 214 -1031 1203 695 -104 -93 683 -20 423 1179 -676 419 -360 369 370 1189 -586 920 -709 129 341 -398 -828 -1539 246 -1159 557 149 1206 -1983 277 -196 1455 -565 -9 -452 -149 -523 -1742 1053 47 -1354 1645 1365 1074 1752 -1512 1272 722 161 -462 -48 -1283 377 575 -132 584 -485 -679 -286
SS 20241212T144603.8Z 9112.615322 238 1 28.44 2 73.88 145.98 118.64 4.43 0.00 1 0.00 1 0 25 1.949e-01 5.600e-03 1.160e-01 2.903e-03 5.608854e-01 1.457715e-03 6.575403e-03 -6.000000e+00 1.071592e-01 222.35 -2.00 3.55 -2.00 320.31 0.00e+00 1.852173e-03 5.160093e-04 6.039725e-04 -6.000000e+00 4.662076e-03 274.60 -2.00 20.00 -2.00 319.80 0.00e+00 3.542 0.001 302.00 328.00 3 2.8477e+00 4.2798e-03 4.5188e-02 -6.0000e+00 2.6390e-01 2.6996e-02 5.3697e-03 2.9646e-02 -6.0000e+00 2.8815e-01 -4.1502e-02 5.2558e-03 1.5174e-02 -6.0000e+00 1.7153e-01 8.1291e-03 2.6987e-03 5.0873e-03 -6.0000e+00 7.3553e-02 4.9931e-04 -8.3744e-04 7.8345e-05 5.0091e-05 -6.0000e+00 4.9575e-03 -8.3176e-04 0.0000e+00 12 1 1 12 1 1 99.11 17.83 0.37 -0.00083 -0.00712 41 27 2 8 0 677.110 15.00 17.83 -0.16 21.48 21.27 22.1 868.34 -56391 -53148 112010 -23819 -116250 -67121 -52238 -52324 -47708 -37307 -38224 -26827 -33438 426 -9316 35 -7646 -28910 -6956 -3693 -5596 -7107 -3236 -4543 -4118 -6967 -4341 -5228 -4124 -5412 23522 -1134 -6062 -256 -3688 -7003 -2843 -2159 1707 -2459 96 -1236 1091 2862 -172 -3164 -705 -1728 2187 -137 1742 2051 1304 2219 1218 1701 675 528 258 -381 2130 1057 -523 3100 1375 636 409 -577 151 439 963 1123 1058 474 -172 -762 -678 -1006 -1352 -952 -1005 -783 -1824 -1492 -1501 -244 -250 100 1425 717 214 859 -33 137 82 293 417 788 221 -371 64 -47 -452 -846 -919 -931 -905 -306 -530 96 36 462 106 -14 134 254 -95 188 131 54 -604 -98 154 183 100 373 369 1131 547 333 345 44 -24 -155 -374 41 -228 41 -30 -146 -62 -127 -7 -527 -572 317 -209 -2095 -779 -562 -637 -635 -496 -530 -357 -587 7 -203 1 -223 -1146 -240 -131 -209 -268 -121 -189 -184 -341 -215 -253 -188 -259 986 -71 -463 -20 -291 -547 -233 -205 191 -319 14 -193 176 467 -29 -563 -124 -313 394 -26 363 476 332 609 359 517 214 168 80 -116 646 353 -200 1291 618 277 172 -249 69 233 568 695 653 280 -94 -374 -304 -445 -652 -539 -663 -588 -1397 -1196 -1286 -222 -238 98 1387 680 189 697 -26 106 69 284 464 922 286 -483 78 -57 -488 -914 -1082 -1157 -1088 -391 -730 146 57 756 174 -23 212 378 -142 291 216 86 -979 -164 249 285 148 532 503 1557 848 578 605 82 -47 -316 -765 89 -500 91 -68 -316 -126 -263 -14
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