File name: Pandora206s1_BuffaloNY_20241221_L2Fit_fwvt1c6d20240814p1-8.txt File generation date: 20241222T051931.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v6d20240814.txt Level 1 file used: Pandora206s1_BuffaloNY_20241221_L1_smca1c6d20240814p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: United States Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20241221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1643 1793 Nominal wavelengths inside fitting window [nm]: 492.0089 492.1299 492.2509 492.3719 492.4929 492.6139 492.7349 492.8558 492.9767 493.0976 493.2185 493.3394 493.4602 493.5810 493.7019 493.8227 493.9434 494.0642 494.1850 494.3057 494.4264 494.5471 494.6678 494.7885 494.9091 495.0297 495.1504 495.2709 495.3915 495.5121 495.6326 495.7532 495.8737 495.9942 496.1147 496.2351 496.3556 496.4760 496.5964 496.7168 496.8372 496.9575 497.0779 497.1982 497.3185 497.4388 497.5591 497.6793 497.7996 497.9198 498.0400 498.1602 498.2804 498.4005 498.5207 498.6408 498.7609 498.8810 499.0011 499.1211 499.2411 499.3612 499.4812 499.6012 499.7211 499.8411 499.9610 500.0809 500.2008 500.3207 500.4406 500.5604 500.6803 500.8001 500.9199 501.0396 501.1594 501.2792 501.3989 501.5186 501.6383 501.7580 501.8776 501.9973 502.1169 502.2365 502.3561 502.4757 502.5952 502.7148 502.8343 502.9538 503.0733 503.1927 503.3122 503.4316 503.5511 503.6705 503.7898 503.9092 504.0286 504.1479 504.2672 504.3865 504.5058 504.6250 504.7443 504.8635 504.9827 505.1019 505.2211 505.3403 505.4594 505.5785 505.6976 505.8167 505.9358 506.0549 506.1739 506.2929 506.4119 506.5309 506.6499 506.7688 506.8878 507.0067 507.1256 507.2445 507.3633 507.4822 507.6010 507.7198 507.8386 507.9574 508.0761 508.1949 508.3136 508.4323 508.5510 508.6697 508.7883 508.9070 509.0256 509.1442 509.2628 509.3814 509.4999 509.6184 509.7370 509.8555 509.9739 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241221T141123.3Z 9121.591242 273 1 26.85 2 78.54 138.08 62.53 251.73 0.00 1 0.00 1 0 15 3.447e-03 3.437e-03 3.817e-04 3.810e-04 5.367568e+02 2.111426e+01 4.015592e+01 -6.000000e+00 1.895662e+02 273.92 -2.00 20.00 -2.00 505.26 0.00e+00 7.014961e-04 1.034295e-05 3.925834e-05 -6.000000e+00 9.553056e-05 273.92 -2.00 20.00 -2.00 500.42 0.00e+00 5.329509e-01 7.542983e-03 8.032081e-03 -6.000000e+00 6.868426e-02 222.57 -2.00 3.55 -2.00 502.02 0.00e+00 4.868 0.002 489.00 513.00 1 4.3744e+00 5.7875e-04 6.9022e-03 -6.0000e+00 5.2662e-03 6.6098e-04 1.4778e-04 3.9617e-04 -6.0000e+00 1.3448e-03 1.1950e-02 1.6503e-03 4.0840e-05 1.6118e-05 -6.0000e+00 3.7714e-04 7.5615e-04 7.4218e-05 10 0 0 10 0 0 99.53 17.77 2.32 0.00076 0.01220 79 79 1 2 0 339.760 15.01 17.77 -0.67 21.38 21.17 22.2 874.89 -839 -651 -481 -36 227 458 600 605 714 577 222 -18 -96 -177 -311 -384 -288 -118 93 275 216 296 201 229 339 353 89 2 13 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-206 -266 -184 26 180 278 507 625 637 557 610 413 197 163 140 50 133 304 171 267 284 142 136 331 -100 -215 -269 -348 -267 -68 63 24 302 316 272 224 329 113 89 16 -192 -469 -671 -461 SQ 20241221T142513.5Z 9121.600850 281 1 35.95 2 76.89 140.85 64.93 254.35 0.00 1 0.00 1 0 15 3.263e-03 3.250e-03 3.350e-04 3.343e-04 3.792939e+02 1.843053e+01 2.876299e+01 -6.000000e+00 1.794337e+02 273.92 -2.00 20.00 -2.00 505.26 0.00e+00 6.272654e-04 9.068601e-06 3.471799e-05 -6.000000e+00 9.042489e-05 273.92 -2.00 20.00 -2.00 500.40 0.00e+00 4.891821e-01 6.617502e-03 6.651574e-03 -6.000000e+00 6.501449e-02 222.57 -2.00 3.55 -2.00 502.01 0.00e+00 4.300 0.001 489.00 513.00 1 4.4789e+00 5.0777e-04 6.0905e-03 -6.0000e+00 4.9848e-03 -1.8376e-04 1.2966e-04 3.4509e-04 -6.0000e+00 1.2730e-03 1.1703e-02 1.7274e-03 3.5817e-05 1.3855e-05 -6.0000e+00 3.5698e-04 1.6061e-03 6.7610e-05 10 0 0 10 0 0 99.48 17.77 2.32 0.00161 0.01359 116 58 1 2 0 309.810 15.00 17.77 -0.19 21.38 21.17 22.2 877.20 -766 -630 -424 -53 148 408 606 544 595 494 193 12 -119 -184 -311 -391 -306 -175 128 192 212 228 228 192 342 340 124 -13 33 -289 -431 -454 -329 -42 228 219 161 225 -9 -67 -84 -18 57 137 237 366 340 197 -37 -279 -531 -646 -763 -739 -494 -195 83 201 343 330 467 466 419 376 329 210 -2 -218 -165 -206 -349 -334 -250 -136 34 37 -191 -427 -427 -453 -425 -346 -302 -215 -58 -142 -63 -105 -102 -134 -67 20 216 475 363 240 120 -64 -200 -431 -699 -578 -503 -243 14 -144 -145 -218 -252 -219 -3 170 329 457 601 561 495 498 406 152 182 133 54 172 181 111 206 273 115 116 279 -49 -269 -232 -328 -252 -29 94 86 212 333 276 219 277 130 87 35 -158 -511 -676 -531 -761 -615 -424 -53 153 420 636 577 631 520 201 12 -120 -188 -318 -401 -310 -181 134 201 224 241 241 204 363 361 132 -13 34 -296 -434 -457 -336 -43 239 228 168 236 -10 -69 -87 -19 59 142 247 382 353 203 -38 -283 -526 -639 -746 -726 -493 -195 85 204 348 335 474 474 428 384 334 211 -2 -218 -163 -201 -339 -325 -245 -134 34 37 -188 -415 -410 -433 -408 -334 -293 -211 -56 -139 -62 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86 1 2 0 163.820 15.00 17.77 -0.11 21.38 21.17 22.2 877.77 -842 -847 -574 -70 250 433 570 668 525 327 129 -70 -61 -158 -342 -396 -323 -107 104 236 241 387 90 53 401 336 61 -37 -37 -268 -321 -527 -422 30 326 260 88 305 160 -131 -148 14 -38 178 373 409 419 196 -100 -170 -367 -611 -744 -845 -502 -166 10 273 401 417 354 504 314 335 346 229 -125 -262 -134 -262 -392 -156 -296 -44 22 -41 -156 -352 -346 -417 -470 -367 -208 -96 -5 -95 40 -134 -105 -66 161 -19 234 562 515 198 100 -140 -134 -302 -669 -572 -527 -188 -56 -268 -225 -202 -380 -127 77 69 356 547 541 580 485 462 388 26 173 35 11 81 210 -3 265 349 31 152 211 -68 -273 -324 -457 -317 -5 137 23 281 103 318 290 212 213 149 118 -198 -488 -639 -616 -831 -842 -572 -72 258 446 598 707 557 345 134 -72 -63 -161 -348 -405 -333 -110 110 247 254 409 96 56 426 357 65 -38 -38 -274 -322 -529 -430 31 341 271 91 320 166 -135 -152 15 -40 184 388 427 436 202 -103 -172 -369 -602 -725 -826 -499 -165 11 277 407 423 359 513 321 342 351 230 -126 -262 -132 -255 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