File name: Pandora206s1_BuffaloNY_20250408_L2Fit_fout2c6d20240814p1-8.txt
File generation date: 20250409T052215.1Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: Kang Sun
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 206
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora206_OF_v3d20211008.txt
Instrument calibration file used: Pandora206s1_CF_v6d20240814.txt
Level 1 file used: Pandora206s1_BuffaloNY_20250408_L1_smca1c6d20240814p1-8.txt
Full location name: University at Buffalo
Short location name: BuffaloNY
Country of location: United States
Location latitude [deg]: 43.0015
Location longitude [deg]: -78.7869
Location altitude [m]: 190
Local noon date: 20250408
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0348 305.1758 305.3167 305.4577 305.5987 305.7396 305.8805 306.0215 306.1624 306.3033 306.4442 306.5850 306.7259 306.8668 307.0076 307.1484 307.2893 307.4301 307.5709 307.7117 307.8524 307.9932 308.1340 308.2747 308.4154 308.5561 308.6968 308.8375 308.9782 309.1189 309.2596 309.4002 309.5408 309.6815 309.8221 309.9627 310.1033 310.2438 310.3844 310.5250 310.6655 310.8060 310.9466 311.0871 311.2276 311.3681 311.5085 311.6490 311.7894 311.9299 312.0703 312.2107 312.3511 312.4915 312.6319 312.7723 312.9126 313.0530 313.1933 313.3336 313.4740 313.6143 313.7545 313.8948 314.0351 314.1753 314.3156 314.4558 314.5960 314.7362 314.8764 315.0166 315.1568 315.2970 315.4371 315.5772 315.7174 315.8575 315.9976 316.1377 316.2777 316.4178 316.5579 316.6979 316.8379 316.9780 317.1180 317.2580 317.3980 317.5379 317.6779 317.8178 317.9578 318.0977 318.2376 318.3775 318.5174 318.6573 318.7972 318.9370 319.0769 319.2167 319.3565 319.4963 319.6361 319.7759 319.9157 320.0554 320.1952 320.3349 320.4747 320.6144 320.7541 320.8938 321.0335 321.1731 321.3128 321.4524 321.5921 321.7317 321.8713 322.0109 322.1505 322.2900 322.4296 322.5692 322.7087 322.8482 322.9877 323.1272 323.2667 323.4062 323.5457 323.6851 323.8246 323.9640 324.1034 324.2428 324.3822 324.5216 324.6610 324.8003 324.9397
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Spectrometer control temperature [°C], 999=no temperature signal
Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 96: Temperature in head sensor [°C], 999=no temperature signal
Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250408T141023.8Z 9229.590553 262 1 7.01 2 54.11 117.15 124.11 357.28 0.00 1 0.00 1 0 17 2.712e-02 8.077e-03 3.667e-02 7.025e-03 3.260658e-01 3.484984e-03 4.013841e-03 -6.000000e+00 1.519210e-02 227.70 -2.00 3.55 -2.00 318.12 0.00e+00 1.042550e-03 6.149422e-04 2.097169e-04 -6.000000e+00 6.553386e-04 277.11 -2.00 20.00 -2.00 317.49 0.00e+00 1.701 0.000 302.00 328.00 3 5.0884e+00 9.3459e-03 2.4096e-02 -6.0000e+00 3.7832e-02 -4.4104e-03 1.0579e-02 1.7107e-02 -6.0000e+00 4.1160e-02 3.5976e-03 6.9227e-03 8.4995e-03 -6.0000e+00 2.4436e-02 -6.4209e-03 3.6041e-03 2.4455e-03 -6.0000e+00 1.0362e-02 3.9613e-04 -1.7927e-03 1.9388e-04 2.5830e-05 -6.0000e+00 6.9085e-04 1.1326e-02 0.0000e+00 12 9 1 12 9 1 99.93 17.75 0.20 0.01133 -0.00215 3 15 2 8 0 1750.390 15.00 17.75 2.94 21.38 21.17 23.5 938.27 3432 2644 4702 -7185 -4111 -18928 -489 -7527 4247 2086 14700 -795 -4162 -1081 -742 1436 -4797 1918 -364 457 -3043 1326 -110 2158 -1008 2922 -1432 83 1371 -316 3116 3457 3097 -1618 -253 -4595 -2539 -659 1055 -2405 -1439 -2683 350 -1401 56 -1433 -1017 -608 -858 410 475 1229 -827 2346 1074 1652 725 76 91 -947 184 1070 1942 2040 260 -1199 971 -1629 1281 448 1539 1377 267 1657 919 39 -398 -582 -284 -982 -1437 -508 -1875 -1534 -1142 -507 -471 -749 42 565 1298 -245 -195 271 851 751 1828 605 444 -350 -810 -1237 -352 -1057 -939 -1084 -1588 -780 -900 -151 845 596 292 585 77 -98 -332 -71 475 46 568 145 597 -270 749 -76 1026 1121 1015 207 491 241 -339 -164 -149 -113 -716 -281 -378 269 -315 -466 398 188 165 304 -504 -245 -1230 -28 -514 291 158 1007 -63 -388 -115 -92 198 -728 294 -60 78 -538 228 -19 400 -203 593 -310 17 253 -59 606 733 728 -414 -61 -1106 -654 -186 354 -970 -639 -1230 162 -671 26 -689 -496 -290 -406 192 237 642 -468 1369 644 1003 455 48 58 -597 117 708 1397 1555 206 -893 677 -1136 910 358 1315 1235 243 1429 764 30 -285 -396 -200 -775 -1259 -479 -1888 -1602 -1241 -575 -562 -906 51 673 1452 -261 -195 260 860 826 2169 779 602 -473 -1055 -1520 -404 -1244 -1183 -1409 -2167 -1087 -1293 -226 1341 953 464 889 111 -135 -452 -101 699 71 891 224 897 -401 1067 -104 1349 1471 1410 306 751 383 -542 -270 -257 -201 -1310 -514 -699 488 -563 -800 671
SS 20250408T145727.7Z 9229.623237 289 1 45.91 2 46.89 129.06 123.71 10.55 0.00 1 0.00 1 0 17 1.029e-02 5.271e-03 2.112e-03 5.881e-04 2.787622e-01 2.919980e-04 3.403802e-03 -6.000000e+00 5.773520e-03 227.70 -2.00 3.55 -2.00 317.56 0.00e+00 4.677699e-04 4.377565e-05 6.535651e-05 -6.000000e+00 2.487629e-04 277.12 -2.00 20.00 -2.00 316.92 0.00e+00 1.461 0.000 302.00 328.00 3 2.5743e+00 7.7315e-04 2.0558e-02 -6.0000e+00 1.4378e-02 -1.8791e-02 8.6968e-04 1.4482e-02 -6.0000e+00 1.5634e-02 1.8802e-03 5.3655e-04 7.1800e-03 -6.0000e+00 9.2823e-03 -3.1329e-03 2.7054e-04 2.0660e-03 -6.0000e+00 3.9438e-03 6.7151e-03 -1.9186e-04 1.6343e-05 2.1390e-05 -6.0000e+00 2.6210e-04 -6.9618e-04 0.0000e+00 10 0 0 10 0 0 99.99 17.73 0.29 -0.00070 -0.00214 518 160 1 8 0 88.440 15.01 17.73 3.14 21.38 21.17 23.9 941.77 -2096 -2565 -2210 -3263 -5568 -2351 -2582 -1226 -199 -1962 -1607 -1946 -1531 -880 -386 -107 -198 360 155 904 461 10 567 -39 171 115 243 -728 -771 35 1475 758 1688 34 -2056 -2001 -1772 -1325 -377 -450 -719 -855 -464 -591 -190 -337 -365 -442 -467 -291 868 846 658 1198 785 1048 954 542 589 509 959 1170 1417 1642 536 -51 -170 -495 445 418 287 244 -21 434 130 34 -143 -683 -124 -587 -941 -806 -1902 -1656 -1262 -882 -401 -309 200 250 350 398 207 518 572 116 474 736 237 -155 -178 -524 -545 -16 -560 -802 -690 -608 -304 177 314 239 128 58 -29 206 138 252 130 84 -333 -59 134 214 641 498 452 1121 714 408 323 33 -122 -20 12 -88 -145 130 -110 -236 -173 -451 -418 -191 -263 -235 -337 -512 -196 -227 -118 -21 -232 -187 -228 -201 -132 -67 -21 -40 76 34 205 108 2 132 -10 45 32 68 -193 -188 8 366 205 493 11 -616 -568 -547 -468 -145 -206 -365 -454 -254 -329 -104 -187 -199 -235 -244 -151 470 495 407 782 535 723 675 385 408 348 668 873 1054 1317 441 -39 -131 -370 343 338 257 230 -20 395 111 28 -108 -485 -91 -487 -811 -772 -1980 -1788 -1341 -1007 -480 -382 248 300 387 436 207 494 574 130 541 939 327 -211 -228 -619 -646 -19 -688 -1043 -935 -865 -453 260 490 380 197 84 -42 272 180 343 190 122 -500 -87 208 317 894 665 570 1397 961 591 496 53 -183 -31 19 -153 -258 236 -203 -425 -298 -753 -677
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