File name: Pandora206s1_BuffaloNY_20250411_L2Fit_fout2c6d20240814p1-8.txt
File generation date: 20250412T051827.8Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: Kang Sun
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 206
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora206_OF_v3d20211008.txt
Instrument calibration file used: Pandora206s1_CF_v6d20240814.txt
Level 1 file used: Pandora206s1_BuffaloNY_20250411_L1_smca1c6d20240814p1-8.txt
Full location name: University at Buffalo
Short location name: BuffaloNY
Country of location: United States
Location latitude [deg]: 43.0015
Location longitude [deg]: -78.7869
Location altitude [m]: 190
Local noon date: 20250411
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0348 305.1758 305.3167 305.4577 305.5987 305.7396 305.8805 306.0215 306.1624 306.3033 306.4442 306.5850 306.7259 306.8668 307.0076 307.1484 307.2893 307.4301 307.5709 307.7117 307.8524 307.9932 308.1340 308.2747 308.4154 308.5561 308.6968 308.8375 308.9782 309.1189 309.2596 309.4002 309.5408 309.6815 309.8221 309.9627 310.1033 310.2438 310.3844 310.5250 310.6655 310.8060 310.9466 311.0871 311.2276 311.3681 311.5085 311.6490 311.7894 311.9299 312.0703 312.2107 312.3511 312.4915 312.6319 312.7723 312.9126 313.0530 313.1933 313.3336 313.4740 313.6143 313.7545 313.8948 314.0351 314.1753 314.3156 314.4558 314.5960 314.7362 314.8764 315.0166 315.1568 315.2970 315.4371 315.5772 315.7174 315.8575 315.9976 316.1377 316.2777 316.4178 316.5579 316.6979 316.8379 316.9780 317.1180 317.2580 317.3980 317.5379 317.6779 317.8178 317.9578 318.0977 318.2376 318.3775 318.5174 318.6573 318.7972 318.9370 319.0769 319.2167 319.3565 319.4963 319.6361 319.7759 319.9157 320.0554 320.1952 320.3349 320.4747 320.6144 320.7541 320.8938 321.0335 321.1731 321.3128 321.4524 321.5921 321.7317 321.8713 322.0109 322.1505 322.2900 322.4296 322.5692 322.7087 322.8482 322.9877 323.1272 323.2667 323.4062 323.5457 323.6851 323.8246 323.9640 324.1034 324.2428 324.3822 324.5216 324.6610 324.8003 324.9397
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Spectrometer control temperature [°C], 999=no temperature signal
Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 96: Temperature in head sensor [°C], 999=no temperature signal
Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250411T164605.1Z 9232.698670 359 1 26.99 2 35.04 167.00 141.13 9.70 0.00 1 0.00 1 0 25 4.154e-01 2.794e-02 1.460e-01 2.694e-02 2.332150e-01 1.329252e-02 2.770575e-03 -6.000000e+00 2.332961e-01 227.94 -2.00 3.55 -2.00 317.92 0.00e+00 3.652838e-03 2.190136e-03 4.914630e-04 -6.000000e+00 1.005681e-02 277.46 -2.00 20.00 -2.00 317.28 0.00e+00 1.220 0.000 302.00 328.00 3 8.1508e+00 3.5506e-02 1.7412e-02 -6.0000e+00 5.8126e-01 -3.2528e-02 4.0089e-02 1.3621e-02 -6.0000e+00 6.3183e-01 5.4917e-02 2.5355e-02 5.9965e-03 -6.0000e+00 3.7515e-01 -2.0324e-02 1.2955e-02 3.6719e-03 -6.0000e+00 1.5938e-01 3.3521e-05 1.0118e-03 7.5555e-04 3.1607e-05 -6.0000e+00 1.0581e-02 -1.4803e-03 0.0000e+00 12 8 8 10 0 0 -33.71 17.84 1.31 -0.00148 0.00612 18 18 1 8 0 1499.160 15.00 17.84 10.22 21.48 21.27 24.4 989.55 10762 469446 22629 18951 28678 34027 15339 4892 -19669 69672 9436 24117 -20711 30526 7800 10780 10333 -30959 13282 -4612 16115 -13314 -5834 -1758 -9830 -1038 2934 -5536 1339 -2566 6011 6269 5736 11902 223 4691 -9270 2149 25507 86 -4698 -2607 982 363 1081 -989 -1533 -539 1981 -7409 -2311 3007 3315 1029 2906 -506 1260 -1359 -5701 -3280 94 -1414 -1460 1721 -2547 -729 -8387 -3263 -1425 277 13769 1403 5258 2830 -107 320 -215 1770 -4103 -4489 -143 2870 -562 -1822 1032 2589 2383 1617 20 2749 53 -585 1725 -1390 -3444 -1862 -7444 2496 31 483 768 -46 -372 63 -193 -1557 1831 724 -1071 1524 -1528 1609 -2365 2479 -411 440 -2326 68 -2092 2502 -885 -1025 698 570 -4572 2671 402 2486 -1404 1767 413 578 -975 -277 594 697 960 230 1309 -1575 -738 -2361 1891 858 12332 1865 1545 1910 2011 1098 425 -2423 3856 897 2059 -3039 3125 1159 1690 1701 -7997 2382 -993 2992 -3148 -1287 -389 -2436 -252 694 -1349 283 -556 1279 1431 1434 2943 57 1096 -2721 644 7232 37 -2250 -1271 480 182 556 -524 -805 -273 956 -3893 -1214 1607 1856 621 1774 -322 802 -885 -3796 -2122 61 -999 -1124 1379 -2139 -549 -6275 -2232 -999 218 10439 1259 4549 2420 -88 235 -147 1118 -2840 -3529 -121 2513 -544 -1854 1094 2908 2826 2000 25 3275 60 -625 1635 -1292 -3437 -2022 -9484 3210 42 640 985 -54 -414 72 -243 -2089 2477 1039 -1633 2406 -2537 2712 -3981 3686 -573 567 -3062 92 -3080 3778 -1419 -1622 1062 830 -6606 3553 516 3110 -1957 2451 610 876 -1517 -442 1000 1233 1733 429 2439 -2932 -1314 -4127 3195
SS 20250411T183341.7Z 9232.773399 417 1 24.01 2 38.36 211.96 132.58 45.81 0.00 1 0.00 1 0 25 7.750e-02 1.974e-02 6.382e-02 1.712e-02 2.527835e-01 8.479159e-03 3.176454e-03 -6.000000e+00 4.352370e-02 227.94 -2.00 3.55 -2.00 317.69 0.00e+00 1.652585e-03 1.301007e-03 3.366399e-04 -6.000000e+00 1.876236e-03 277.47 -2.00 20.00 -2.00 317.04 0.00e+00 1.274 0.000 302.00 328.00 3 7.9081e+00 2.2525e-02 1.8520e-02 -6.0000e+00 1.0844e-01 3.9888e-02 2.5389e-02 1.3681e-02 -6.0000e+00 1.1788e-01 1.3602e-02 1.5706e-02 6.5733e-03 -6.0000e+00 6.9989e-02 -8.0600e-03 7.9184e-03 2.2904e-03 -6.0000e+00 2.9733e-02 3.8865e-05 -1.2104e-03 4.7727e-04 2.3292e-05 -6.0000e+00 1.9740e-03 -1.3430e-03 0.0000e+00 12 8 8 10 0 0 56.17 17.83 1.91 -0.00134 -0.01044 6 6 2 8 0 4000.000 14.99 17.83 10.90 21.48 21.27 24.8 995.43 5141 21491 17456 -21314 12077 -30096 -41834 23570 -11498 25854 7451 2469 6890 22672 11764 10963 15424 7400 12149 -1642 -9367 -12456 15008 1654 1132 -9674 230 -3613 9373 7184 8429 1209 -2862 5126 -7334 7337 -7688 -3908 3359 1953 -4240 -1635 1555 1204 2420 -2506 -411 -258 5351 -829 3473 -2399 -2309 -545 2342 159 -1073 1904 -2721 -3305 304 3059 -999 3629 -1360 3014 -2733 -949 -679 -2174 4913 -2600 475 808 2299 -1522 4315 -1818 -2771 -7957 -618 306 -2342 -1024 -1231 2346 1093 -804 285 3381 -357 2386 -180 523 -2193 1038 393 1499 1303 477 460 -3217 127 -360 467 -3129 228 1698 -915 665 1852 2321 -2235 -240 76 842 -880 -1744 -951 -1238 476 -371 -333 498 -2816 1243 -840 2077 -593 187 312 640 846 -1991 189 1623 834 531 924 -230 270 -1643 -679 460 1829 1617 -2713 989 -3469 -5633 1876 -1406 2417 799 275 820 2662 1768 1872 2642 1419 2316 -372 -2356 -3180 2918 387 278 -2746 60 -932 2014 1527 1876 311 -832 1464 -2212 1793 -2357 -1318 1258 854 -2186 -856 816 645 1272 -1389 -220 -138 2650 -432 1811 -1427 -1398 -342 1481 104 -724 1288 -1880 -2268 205 2152 -770 2881 -1153 2325 -2048 -670 -493 -1823 4262 -2470 441 746 1957 -1208 2891 -1249 -1894 -6448 -524 285 -2410 -1078 -1341 2657 1322 -1026 364 4058 -411 2512 -177 482 -2160 1092 462 1879 1762 642 602 -4025 142 -410 579 -4251 311 2323 -1343 1019 2978 3786 -3687 -361 107 1095 -1149 -2380 -1378 -1872 729 -584 -513 730 -4013 1623 -1092 2586 -783 261 460 971 1296 -3225 318 2846 1461 955 1677 -410 476 -2851 -1129