File name: Pandora206s1_BuffaloNY_20250416_L2Fit_fnvs4c6d20240814p1-8.txt File generation date: 20250417T051938.1Z Data description: Level 2 spectral fitting results file Data file version: fnvs4c6p1-8 Local principal investigator: Kang Sun Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 206 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora206_OF_v3d20211008.txt Instrument calibration file used: Pandora206s1_CF_v6d20240814.txt Level 1 file used: Pandora206s1_BuffaloNY_20250416_L1_smca1c6d20240814p1-8.txt Full location name: University at Buffalo Short location name: BuffaloNY Country of location: United States Location latitude [deg]: 43.0015 Location longitude [deg]: -78.7869 Location altitude [m]: 190 Local noon date: 20250416 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 918 1463 Nominal wavelengths inside fitting window [nm]: 400.0868 400.2190 400.3512 400.4834 400.6156 400.7477 400.8799 401.0120 401.1441 401.2763 401.4083 401.5404 401.6725 401.8045 401.9366 402.0686 402.2006 402.3326 402.4646 402.5965 402.7285 402.8604 402.9923 403.1242 403.2561 403.3880 403.5199 403.6517 403.7836 403.9154 404.0472 404.1790 404.3108 404.4425 404.5743 404.7060 404.8377 404.9694 405.1011 405.2328 405.3645 405.4961 405.6278 405.7594 405.8910 406.0226 406.1542 406.2857 406.4173 406.5488 406.6803 406.8118 406.9433 407.0748 407.2063 407.3377 407.4692 407.6006 407.7320 407.8634 407.9948 408.1261 408.2575 408.3888 408.5201 408.6514 408.7827 408.9140 409.0453 409.1765 409.3078 409.4390 409.5702 409.7014 409.8326 409.9637 410.0949 410.2260 410.3571 410.4882 410.6193 410.7504 410.8815 411.0125 411.1435 411.2746 411.4056 411.5366 411.6675 411.7985 411.9294 412.0604 412.1913 412.3222 412.4531 412.5840 412.7148 412.8457 412.9765 413.1073 413.2381 413.3689 413.4997 413.6304 413.7612 413.8919 414.0226 414.1533 414.2840 414.4147 414.5453 414.6760 414.8066 414.9372 415.0678 415.1984 415.3290 415.4595 415.5901 415.7206 415.8511 415.9816 416.1121 416.2425 416.3730 416.5034 416.6338 416.7643 416.8947 417.0250 417.1554 417.2857 417.4161 417.5464 417.6767 417.8070 417.9373 418.0675 418.1978 418.3280 418.4582 418.5884 418.7186 418.8488 418.9790 419.1091 419.2392 419.3694 419.4995 419.6295 419.7596 419.8897 420.0197 420.1497 420.2797 420.4097 420.5397 420.6697 420.7997 420.9296 421.0595 421.1894 421.3193 421.4492 421.5791 421.7089 421.8388 421.9686 422.0984 422.2282 422.3579 422.4877 422.6175 422.7472 422.8769 423.0066 423.1363 423.2660 423.3956 423.5253 423.6549 423.7845 423.9141 424.0437 424.1733 424.3028 424.4324 424.5619 424.6914 424.8209 424.9504 425.0798 425.2093 425.3387 425.4681 425.5976 425.7269 425.8563 425.9857 426.1150 426.2444 426.3737 426.5030 426.6323 426.7615 426.8908 427.0200 427.1493 427.2785 427.4077 427.5369 427.6660 427.7952 427.9243 428.0534 428.1826 428.3116 428.4407 428.5698 428.6988 428.8279 428.9569 429.0859 429.2149 429.3439 429.4728 429.6018 429.7307 429.8596 429.9885 430.1174 430.2463 430.3751 430.5039 430.6328 430.7616 430.8904 431.0191 431.1479 431.2767 431.4054 431.5341 431.6628 431.7915 431.9202 432.0488 432.1775 432.3061 432.4347 432.5633 432.6919 432.8205 432.9490 433.0776 433.2061 433.3346 433.4631 433.5916 433.7200 433.8485 433.9769 434.1053 434.2337 434.3621 434.4905 434.6189 434.7472 434.8755 435.0038 435.1321 435.2604 435.3887 435.5169 435.6452 435.7734 435.9016 436.0298 436.1580 436.2861 436.4143 436.5424 436.6705 436.7986 436.9267 437.0548 437.1828 437.3109 437.4389 437.5669 437.6949 437.8229 437.9508 438.0788 438.2067 438.3346 438.4625 438.5904 438.7183 438.8462 438.9740 439.1018 439.2296 439.3574 439.4852 439.6130 439.7407 439.8685 439.9962 440.1239 440.2516 440.3793 440.5069 440.6346 440.7622 440.8898 441.0174 441.1450 441.2726 441.4001 441.5277 441.6552 441.7827 441.9102 442.0376 442.1651 442.2926 442.4200 442.5474 442.6748 442.8022 442.9296 443.0569 443.1842 443.3116 443.4389 443.5662 443.6934 443.8207 443.9480 444.0752 444.2024 444.3296 444.4568 444.5840 444.7111 444.8383 444.9654 445.0925 445.2196 445.3467 445.4737 445.6008 445.7278 445.8548 445.9818 446.1088 446.2358 446.3627 446.4897 446.6166 446.7435 446.8704 446.9973 447.1241 447.2510 447.3778 447.5046 447.6314 447.7582 447.8850 448.0117 448.1385 448.2652 448.3919 448.5186 448.6453 448.7719 448.8986 449.0252 449.1518 449.2784 449.4050 449.5316 449.6581 449.7847 449.9112 450.0377 450.1642 450.2907 450.4171 450.5436 450.6700 450.7964 450.9228 451.0492 451.1756 451.3019 451.4283 451.5546 451.6809 451.8072 451.9335 452.0597 452.1860 452.3122 452.4384 452.5646 452.6908 452.8169 452.9431 453.0692 453.1953 453.3214 453.4475 453.5736 453.6997 453.8257 453.9517 454.0777 454.2037 454.3297 454.4557 454.5816 454.7076 454.8335 454.9594 455.0853 455.2111 455.3370 455.4628 455.5886 455.7145 455.8402 455.9660 456.0918 456.2175 456.3433 456.4690 456.5947 456.7203 456.8460 456.9717 457.0973 457.2229 457.3485 457.4741 457.5997 457.7252 457.8508 457.9763 458.1018 458.2273 458.3528 458.4783 458.6037 458.7291 458.8545 458.9799 459.1053 459.2307 459.3560 459.4814 459.6067 459.7320 459.8573 459.9826 460.1078 460.2331 460.3583 460.4835 460.6087 460.7339 460.8591 460.9842 461.1093 461.2344 461.3596 461.4846 461.6097 461.7348 461.8598 461.9848 462.1098 462.2348 462.3598 462.4847 462.6097 462.7346 462.8595 462.9844 463.1093 463.2342 463.3590 463.4838 463.6087 463.7335 463.8582 463.9830 464.1078 464.2325 464.3572 464.4819 464.6066 464.7313 464.8559 464.9806 465.1052 465.2298 465.3544 465.4790 465.6036 465.7281 465.8526 465.9772 466.1017 466.2261 466.3506 466.4751 466.5995 466.7239 466.8483 466.9727 467.0971 467.2214 467.3458 467.4701 467.5944 467.7187 467.8430 467.9672 468.0915 468.2157 468.3399 468.4641 468.5883 468.7124 468.8366 468.9607 469.0848 469.2089 469.3330 469.4571 469.5811 469.7052 469.8292 469.9532 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Spectrometer control temperature [°C], 999=no temperature signal Column 159: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 160: Temperature in head sensor [°C], 999=no temperature signal Column 161: Temperature at electronics board 1 [°C], 999=no temperature signal Column 162: Temperature at electronics board 2 [°C], 999=no temperature signal Column 163: Humidity in head sensor [%], -9=no humidity signal Column 164: Pressure in head sensor [hPa], -9=no pressure signal Columns 165-710: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 711-1256: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250416T173642.5Z 9237.733825 391 1 25.81 2 32.95 189.91 148.09 289.58 0.00 1 0.00 1 0 33 3.786e-03 3.738e-03 3.632e-03 3.592e-03 3.556702e+02 7.010333e+02 7.283053e+01 3.539736e+02 7.573369e+02 278.03 -2.00 20.00 -2.00 443.97 0.00e+00 5.083223e-04 3.863492e-04 9.222428e-06 1.391622e-05 4.156916e-04 278.03 -2.00 20.00 -2.00 453.55 0.00e+00 2.158363e-04 3.839537e-05 1.546454e-05 4.921314e-06 4.072900e-05 278.03 -2.00 20.00 -2.00 432.78 0.00e+00 8.453455e+05 5.115969e+05 2.644867e+04 2.194695e+05 5.454540e+05 260.14 -2.00 11.28 -2.00 456.91 0.00e+00 1.114920e-01 1.088000e-01 4.241928e-03 1.043653e-02 1.188994e-01 228.34 -2.00 3.55 -2.00 452.90 0.00e+00 -1.179098e-05 1.346675e-05 5.148873e-07 1.094716e-06 1.446810e-05 278.03 -2.00 20.00 -2.00 454.58 0.00e+00 1.191 0.000 397.00 473.00 4 8.9502e+00 3.9237e-03 3.0504e-03 3.7254e-04 3.9497e-03 6.8471e-02 4.3951e-03 6.2066e-04 2.1415e-04 4.7335e-03 -1.2002e-02 2.5942e-03 8.2647e-05 8.9472e-05 2.7667e-03 -3.3228e-03 8.5435e-04 2.3811e-05 2.3501e-05 9.2066e-04 1.0237e-03 4.3469e-04 1.6852e-05 1.2795e-05 4.6166e-04 2.0749e-04 1.9522e-02 2.6636e-03 7.5448e-05 3.7665e-05 2.3909e-03 8.8349e-05 4.1978e-05 1.9097e-07 3.7149e-07 4.2904e-05 -7.8471e-06 5.4389e-05 3.2906e-07 4.4504e-07 5.7363e-05 -3.9366e-03 1.0272e-04 -3.2982e-01 3.4040e-01 5.0595e-03 1.9936e-03 3.4090e-01 12 8 8 10 0 0 -10.62 17.82 2.47 -0.00394 -0.00133 18 18 1 2 0 1433.790 14.99 17.82 9.36 21.48 21.27 24.4 981.88 41 682 -45 -149 195 -146 506 -23 291 -134 -20 -192 117 -737 -825 329 -126 15 -386 305 -505 -113 -179 -295 -83 264 -10 -145 14 946 500 63 503 -176 -123 -788 391 55 819 -174 318 232 -748 -224 46 -411 -81 -99 -430 -74 -440 184 -196 248 -487 -6 59 -412 -730 48 -259 -458 498 -32 285 261 246 163 -67 399 177 625 21 504 -946 -41 -515 -185 -655 59 282 182 -473 531 -53 333 335 539 111 -226 223 163 -153 -140 288 -31 -22 98 65 86 -286 -566 -278 942 65 77 415 351 -364 1039 -583 364 110 -152 67 -1220 -110 -322 54 -242 -214 268 112 237 411 22 190 -81 -132 -341 -181 54 -65 -308 -221 90 -368 223 16 262 -277 347 27 -590 69 0 188 -434 -92 -84 729 -508 -496 -371 -221 -32 1053 -24 -175 128 78 -730 129 -24 -189 242 291 60 -13 373 -606 -354 455 281 -68 -70 91 -347 -25 50 29 50 130 -157 153 -510 -274 -469 572 -53 -147 -184 -149 300 67 62 56 162 -544 828 -839 114 65 -110 369 -474 245 216 216 219 -63 -48 235 626 357 69 274 -111 -72 -10 334 -61 246 25 -145 175 -659 265 -175 1740 -73 -346 221 -486 124 -706 372 -77 152 -189 609 22 -497 126 -159 -55 430 23 -12 -61 -308 103 -218 181 430 265 -559 317 -174 -271 23 9 -239 -173 -458 -774 99 -225 -146 299 -302 -431 570 238 105 -20 -245 -714 30 -341 -281 124 125 351 570 121 197 -27 -149 2 -337 -126 -21 853 423 57 43 64 62 -303 900 -237 87 261 -271 407 -126 481 412 -585 -123 -152 341 710 -700 -382 367 -609 609 -38 -274 -423 -129 280 -270 -237 675 128 605 -160 -228 -229 -167 -254 429 -45 200 -681 536 -369 -187 558 -343 -497 -244 605 54 174 -168 -509 -539 243 -1222 36 -33 155 632 218 -97 5 268 185 119 -163 193 163 456 -140 -269 -274 42 -54 441 -809 -259 -173 -154 106 -87 -355 -80 501 -332 -264 45 126 408 -51 147 258 78 -222 -124 66 -12 -433 -143 1 534 -10 -399 -278 322 330 -12 207 473 431 -286 230 -194 224 -573 1440 223 95 154 -374 57 84 1933 509 -1212 -163 -140 -88 291 7 528 564 157 -318 322 -163 -119 -301 -148 12 -204 -404 -520 -427 334 -178 -653 376 32 -7 -36 -187 471 335 -476 21 -144 -780 -228 -300 -45 455 198 -209 -597 185 -242 139 235 562 181 168 -236 271 81 -321 4 -329 802 -38 160 126 227 174 -379 220 250 435 457 340 -1109 232 517 -151 -86 281 -400 -3 -190 -248 -278 24 -1048 79 245 252 -204 -419 267 -243 -192 -307 202 23 161 -191 374 -421 91 -325 -399 270 753 420 113 -682 -214 136 -173 37 261 -161 -360 275 163 228 15 29 424 -372 71 -96 463 -610 -77 79 94 494 40 660 -42 -137 177 -134 481 -23 291 -135 -21 -192 118 -747 -838 335 -128 15 -396 314 -523 -113 -173 -271 -74 240 -9 -147 15 992 524 63 468 -156 -107 -703 372 56 838 -176 313 222 -708 -212 44 -390 -75 -89 -381 -70 -418 179 -189 239 -473 -5 55 -387 -681 45 -256 -469 510 -32 293 275 267 180 -73 431 186 637 21 483 -868 -37 -455 -163 -606 55 278 185 -490 549 -56 358 369 599 122 -248 241 174 -165 -153 310 -33 -23 103 67 86 -285 -572 -289 1013 73 88 458 371 -376 1045 -604 386 119 -165 72 -1297 -114 -331 56 -252 -228 294 126 270 468 25 211 -89 -141 -358 -185 54 -65 -309 -227 94 -386 232 16 272 -285 352 27 -607 72 0 194 -446 -98 -85 712 -495 -481 -368 -226 -34 1071 -25 -186 136 84 -783 135 -25 -192 244 299 64 -13 378 -609 -324 400 254 -67 -70 93 -356 -25 48 27 48 127 -156 155 -532 -284 -479 562 -51 -138 -175 -143 293 67 61 54 154 -514 775 -827 116 69 -115 370 -449 217 183 192 190 -59 -47 231 617 351 67 264 -106 -68 -10 295 -54 219 22 -134 159 -574 213 -140 1282 -53 -255 164 -361 89 -500 259 -56 119 -156 558 22 -514 134 -171 -57 409 21 -10 -53 -285 97 -218 186 444 272 -564 300 -162 -230 18 8 -207 -162 -433 -767 99 -226 -143 284 -284 -408 551 236 106 -20 -253 -753 32 -366 -300 130 129 356 571 119 191 -26 -144 1 -338 -125 -20 731 348 47 36 58 58 -290 856 -229 85 260 -261 390 -121 455 400 -555 -115 -142 318 685 -680 -383 370 -616 596 -37 -268 -425 -133 289 -279 -242 675 130 613 -163 -233 -233 -166 -249 418 -45 201 -672 552 -379 -189 559 -333 -492 -244 599 53 170 -160 -473 -488 224 -1141 34 -30 139 578 204 -93 5 257 177 115 -161 194 167 470 -146 -275 -274 41 -52 426 -813 -265 -177 -156 105 -86 -353 -79 496 -333 -267 46 130 402 -51 149 264 80 -230 -128 68 -12 -439 -143 1 522 -10 -397 -277 318 325 -12 205 454 404 -265 212 -181 209 -544 1359 218 95 157 -388 59 86 1933 514 -1227 -160 -137 -86 283 7 516 556 158 -326 335 -172 -126 -316 -153 12 -209 -419 -543 -447 346 -186 -688 395 33 -7 -37 -188 464 327 -470 21 -145 -799 -235 -309 -46 458 198 -210 -602 185 -242 140 236 563 184 172 -245 283 86 -340 4 -345 829 -40 166 131 237 182 -401 232 264 459 481 359 -1187 245 542 -159 -95 305 -434 -4 -204 -267 -302 26 -1134 83 254 260 -213 -443 285 -261 -207 -330 218 25 178 -212 413 -461 97 -336 -402 267 746 425 117 -730 -231 147 -187 39 277 -170 -380 290 174 246 17 32 455 -401 76 -103 498 -665 -83 84 99 508 SQ 20250416T192115.7Z 9237.806432 449 1 24.00 2 42.61 229.58 162.28 332.97 0.00 1 0.00 1 0 33 3.081e-03 3.066e-03 2.702e-03 2.683e-03 -2.486579e+02 5.211055e+02 4.375125e+01 3.539779e+02 6.164583e+02 278.03 -2.00 20.00 -2.00 443.94 0.00e+00 2.023559e-04 2.879579e-04 8.019309e-06 1.373726e-05 3.377875e-04 278.03 -2.00 20.00 -2.00 453.39 0.00e+00 2.277970e-04 2.859413e-05 1.455163e-05 4.919674e-06 3.314348e-05 278.03 -2.00 20.00 -2.00 432.85 0.00e+00 8.218700e+05 3.811523e+05 1.885482e+04 2.195153e+05 4.438354e+05 260.15 -2.00 11.28 -2.00 456.61 0.00e+00 1.668061e-01 8.065584e-02 3.600406e-03 1.055530e-02 9.671905e-02 228.35 -2.00 3.55 -2.00 452.77 0.00e+00 -1.334555e-05 1.000381e-05 5.780557e-07 1.094122e-06 1.177298e-05 278.03 -2.00 20.00 -2.00 454.39 0.00e+00 1.357 0.000 397.00 473.00 4 8.7365e+00 2.8869e-03 3.4506e-03 3.7326e-04 3.2156e-03 7.2799e-02 3.2830e-03 7.0724e-04 2.1208e-04 3.8536e-03 -1.0561e-02 1.9264e-03 9.3728e-05 8.8095e-05 2.2452e-03 -2.0252e-03 6.3653e-04 1.9899e-05 2.3367e-05 7.4820e-04 1.0554e-03 3.2491e-04 1.5207e-05 1.2783e-05 3.7562e-04 2.4749e-04 1.7877e-02 1.9342e-03 8.3884e-05 3.4807e-05 1.9424e-03 -1.7494e-05 3.1146e-05 2.5265e-07 3.7400e-07 3.4927e-05 -9.8206e-06 4.0603e-05 4.6542e-07 4.4352e-07 4.6696e-05 -2.4971e-03 1.0067e-04 -2.6736e-01 2.5051e-01 5.3864e-03 2.0054e-03 2.7718e-01 12 8 8 10 0 0 83.01 17.80 2.14 -0.00250 -0.00205 6 6 2 2 0 4000.000 15.00 17.80 10.10 21.38 21.17 24.5 987.04 392 108 237 175 -256 -331 311 4 406 63 107 -445 -127 -924 -230 50 -127 469 -249 -24 -553 209 -270 -360 -213 -399 76 158 233 -327 -303 84 305 -330 45 -309 465 -589 649 43 456 174 -4 243 509 197 171 -249 -416 -22 208 -147 99 589 -430 139 -179 -526 380 145 -80 70 401 -13 415 305 -191 272 -20 116 308 151 -316 437 -297 399 -58 544 -214 -489 -92 -56 -104 -357 115 14 -126 -179 256 -163 440 172 -53 -295 554 -234 -154 -265 111 166 176 158 -656 139 -151 398 -211 23 -338 102 64 25 -64 1 56 -337 -90 23 198 -330 224 60 50 151 121 -2 74 326 -605 -780 -6 232 -74 327 -217 152 -191 -97 -308 -28 34 733 174 -114 110 313 96 -511 331 -364 123 -159 -235 -229 393 198 -204 163 163 208 -434 113 -261 86 120 168 -89 54 229 -186 2 -84 24 290 -164 -296 -21 -234 389 403 106 -7 -182 253 -105 -212 -435 -410 -357 244 -166 277 -182 521 183 -64 73 59 -540 52 -61 -280 -83 -148 216 -191 459 -583 -562 -190 -92 47 14 -34 571 491 -98 -521 -127 296 -449 34 -7 -45 242 30 -263 -15 -31 -46 354 -800 234 -161 419 -313 469 -404 416 -498 449 470 134 447 220 268 -77 -82 223 232 -101 -447 321 -218 243 20 -511 -5 -263 242 11 -476 -402 -151 598 -398 230 -354 -95 -561 -113 -422 132 -259 225 61 -25 -800 -62 1434 -186 169 -740 601 -119 -1126 633 -37 -376 -75 20 144 3 388 -405 172 -70 -470 -3 -249 64 9 216 221 219 568 -24 485 435 -59 188 -65 209 627 71 -300 288 -281 526 615 -335 53 -95 38 351 -136 315 111 -353 -57 213 -325 31 172 143 12 195 -563 287 484 -91 162 -548 -66 109 130 -228 42 95 -260 -227 -166 -568 -47 331 169 420 511 -224 -85 -512 -159 23 211 115 -53 416 -178 116 145 209 -281 -169 -662 -328 -613 51 -307 -155 -91 408 -521 232 -371 82 -353 74 74 -58 318 365 376 -464 292 -32 3 -80 182 -560 86 385 -177 276 428 45 -170 140 394 221 180 -57 408 132 483 209 -57 -336 -88 220 -196 20 324 -274 -171 -302 -154 180 -41 -213 -294 -518 26 54 342 -31 177 55 -298 138 -329 -456 -25 212 150 -3 -9 193 508 5 206 354 146 94 -698 106 -335 -120 -371 -136 935 -262 201 -76 135 -47 -128 -95 223 -64 272 115 113 -100 -50 -10 -497 -29 17 141 -132 -188 41 -151 383 199 -49 -235 -193 -537 605 -135 217 29 13 -105 -109 -38 -330 256 -182 -926 210 -172 52 -128 -361 5 -162 66 -79 1 3 -113 304 152 108 -260 -108 -473 149 651 415 221 53 515 -111 156 -290 106 80 -7 737 -255 351 -126 -256 -65 -95 42 -269 66 -407 -350 -142 -5 897 382 106 222 160 -234 -305 297 4 407 64 109 -449 -128 -942 -233 51 -130 476 -256 -23 -547 210 -261 -332 -201 -366 74 160 233 -332 -306 86 285 -310 41 -290 443 -606 668 44 450 168 -4 229 487 187 166 -239 -390 -21 197 -144 95 569 -419 133 -170 -497 371 137 -80 72 413 -13 428 323 -199 288 -21 120 326 156 -319 422 -287 359 -51 472 -196 -460 -91 -58 -108 -374 122 14 -134 -192 271 -172 453 176 -55 -309 570 -242 -158 -281 114 168 177 160 -689 145 -163 433 -225 23 -351 104 66 25 -66 1 57 -341 -95 23 203 -331 229 63 54 166 132 -2 79 342 -627 -788 -6 233 -74 329 -225 152 -192 -97 -310 -28 34 746 170 -112 110 324 101 -536 337 -358 122 -156 -229 -228 382 199 -215 175 176 226 -455 123 -281 90 125 173 -94 55 246 -194 2 -78 22 264 -154 -301 -22 -245 392 395 102 -7 -181 256 -109 -215 -442 -429 -362 238 -160 269 -178 518 187 -65 72 57 -521 50 -61 -282 -85 -151 212 -185 415 -537 -509 -169 -88 47 14 -33 573 487 -97 -514 -123 275 -408 31 -6 -42 228 28 -234 -13 -25 -37 274 -632 186 -127 321 -236 348 -313 329 -421 423 466 137 471 233 272 -76 -78 200 208 -95 -436 331 -223 250 20 -511 -5 -239 210 9 -401 -358 -139 580 -390 229 -352 -92 -558 -110 -415 127 -256 224 62 -25 -837 -65 1502 -196 176 -765 604 -119 -1117 605 -36 -362 -73 20 141 3 347 -349 146 -62 -440 -3 -236 61 8 210 219 220 570 -25 481 420 -55 174 -60 194 602 69 -302 293 -285 519 598 -330 53 -98 40 362 -140 319 113 -364 -58 218 -333 31 169 141 12 198 -564 287 476 -88 157 -542 -66 111 131 -231 41 92 -246 -217 -155 -531 -44 311 155 393 486 -218 -83 -503 -156 23 212 113 -54 421 -181 116 141 207 -276 -167 -650 -328 -617 51 -301 -151 -88 395 -511 227 -368 82 -357 75 76 -60 334 386 399 -477 308 -34 3 -83 185 -570 87 390 -181 281 432 45 -165 138 377 208 169 -54 388 127 469 208 -55 -338 -89 222 -198 20 321 -270 -172 -302 -154 178 -40 -214 -299 -513 26 55 353 -33 181 56 -300 138 -334 -467 -25 216 153 -3 -10 200 517 5 211 357 146 94 -710 109 -348 -126 -391 -142 957 -270 205 -78 138 -48 -131 -98 229 -67 284 122 121 -108 -53 -10 -532 -30 18 150 -141 -201 44 -162 412 215 -53 -255 -209 -583 650 -146 232 31 14 -110 -114 -40 -346 268 -192 -972 214 -181 54 -134 -371 6 -170 69 -82 1 3 -121 327 163 115 -269 -112 -483 149 653 425 232 55 535 -116 164 -304 110 82 -7 752 -266 367 -133 -270 -68 -99 43 -282 69 -431 -369 -148 -5 930