File name: Pandora206s1_BuffaloNY_20250505_L2Fit_fwvt1c6d20240814p1-8.txt
File generation date: 20250506T051603.9Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c6p1-8
Local principal investigator: Kang Sun
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 206
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora206_OF_v3d20211008.txt
Instrument calibration file used: Pandora206s1_CF_v6d20240814.txt
Level 1 file used: Pandora206s1_BuffaloNY_20250505_L1_smca1c6d20240814p1-8.txt
Full location name: University at Buffalo
Short location name: BuffaloNY
Country of location: United States
Location latitude [deg]: 43.0015
Location longitude [deg]: -78.7869
Location altitude [m]: 190
Local noon date: 20250505
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1643 1793
Nominal wavelengths inside fitting window [nm]: 492.0089 492.1299 492.2509 492.3719 492.4929 492.6139 492.7349 492.8558 492.9767 493.0976 493.2185 493.3394 493.4602 493.5810 493.7019 493.8227 493.9434 494.0642 494.1850 494.3057 494.4264 494.5471 494.6678 494.7885 494.9091 495.0297 495.1504 495.2709 495.3915 495.5121 495.6326 495.7532 495.8737 495.9942 496.1147 496.2351 496.3556 496.4760 496.5964 496.7168 496.8372 496.9575 497.0779 497.1982 497.3185 497.4388 497.5591 497.6793 497.7996 497.9198 498.0400 498.1602 498.2804 498.4005 498.5207 498.6408 498.7609 498.8810 499.0011 499.1211 499.2411 499.3612 499.4812 499.6012 499.7211 499.8411 499.9610 500.0809 500.2008 500.3207 500.4406 500.5604 500.6803 500.8001 500.9199 501.0396 501.1594 501.2792 501.3989 501.5186 501.6383 501.7580 501.8776 501.9973 502.1169 502.2365 502.3561 502.4757 502.5952 502.7148 502.8343 502.9538 503.0733 503.1927 503.3122 503.4316 503.5511 503.6705 503.7898 503.9092 504.0286 504.1479 504.2672 504.3865 504.5058 504.6250 504.7443 504.8635 504.9827 505.1019 505.2211 505.3403 505.4594 505.5785 505.6976 505.8167 505.9358 506.0549 506.1739 506.2929 506.4119 506.5309 506.6499 506.7688 506.8878 507.0067 507.1256 507.2445 507.3633 507.4822 507.6010 507.7198 507.8386 507.9574 508.0761 508.1949 508.3136 508.4323 508.5510 508.6697 508.7883 508.9070 509.0256 509.1442 509.2628 509.3814 509.4999 509.6184 509.7370 509.8555 509.9739
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250505T123734.2Z 9256.526090 169 1 24.01 2 63.32 92.07 122.49 5.35 0.00 1 0.00 1 0 15 4.337e-03 4.314e-03 2.759e-03 2.747e-03 4.079106e+03 1.761637e+02 2.940313e+02 -6.000000e+00 2.447825e+02 280.17 -2.00 20.00 -2.00 505.23 0.00e+00 6.018728e-04 7.580294e-05 3.730819e-05 -6.000000e+00 1.219543e-04 280.17 -2.00 20.00 -2.00 500.22 0.00e+00 1.764126e-01 5.554697e-02 2.862107e-02 -6.000000e+00 8.687075e-02 230.01 -2.00 3.55 -2.00 501.84 0.00e+00 2.215 0.000 489.00 513.00 1 8.3259e+00 4.2694e-03 4.0450e-03 -6.0000e+00 6.6704e-03 9.4258e-03 1.0830e-03 7.1411e-04 -6.0000e+00 1.7025e-03 3.3873e-04 1.4504e-03 2.8814e-04 3.3614e-05 -6.0000e+00 4.7485e-04 -5.0615e-03 1.3146e-04 11 8 0 10 0 0 83.75 18.12 2.58 -0.00506 0.00500 6 6 2 2 0 4000.000 14.99 18.12 20.42 21.69 21.48 25.8 1040.56 -1005 -281 -48 -139 115 260 301 559 891 409 198 -147 -276 -343 -592 -594 91 -206 -304 363 387 501 77 456 204 134 77 -331 492 -294 -338 -156 -672 -490 345 85 227 -142 -281 -68 -112 -145 80 -74 181 514 678 744 -138 -338 -806 -356 73 -737 -447 248 20 341 259 537 244 586 919 163 746 -234 -142 -892 390 -184 99 -39 -570 -26 -118 -711 -556 -384 -496 -363 -276 -705 -207 394 -84 -198 76 -378 -266 -152 8 202 559 560 -100 -148 229 765 -10 -804 -524 -943 -563 -232 1078 -36 80 -197 -189 -67 91 27 430 589 1314 61 -431 272 539 132 155 -303 59 -347 597 -123 -399 67 213 -223 702 -302 -571 228 -313 438 -176 192 -592 299 577 81 -446 445 474 125 57 34 -224 -520 -733 -1013 -284 -50 -143 121 280 319 598 950 435 208 -158 -292 -359 -616 -620 96 -214 -323 390 417 541 84 494 222 146 83 -357 514 -301 -340 -157 -688 -515 369 92 245 -153 -299 -72 -118 -153 85 -80 190 538 730 791 -145 -348 -812 -349 70 -717 -443 250 21 345 264 545 248 596 934 167 753 -236 -140 -907 387 -181 97 -38 -564 -26 -118 -692 -551 -374 -478 -348 -265 -682 -201 384 -81 -191 73 -368 -259 -148 8 199 556 558 -100 -144 218 730 -9 -748 -484 -885 -524 -223 1048 -35 77 -193 -184 -65 89 26 417 576 1284 61 -433 272 534 130 150 -291 56 -330 564 -117 -382 64 202 -212 655 -281 -525 213 -283 398 -164 181 -572 290 562 77 -430 427 454 120 54 32 -210 -485 -689
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SQ 20250505T131844.6Z 9256.554683 198 1 27.28 2 55.83 99.55 121.26 16.53 0.00 1 0.00 1 0 15 2.946e-03 2.948e-03 9.270e-04 9.233e-04 2.728448e+03 5.736306e+01 2.047686e+02 -6.000000e+00 1.662259e+02 280.17 -2.00 20.00 -2.00 505.23 0.00e+00 5.348088e-04 2.545193e-05 3.186923e-05 -6.000000e+00 8.282810e-05 280.17 -2.00 20.00 -2.00 500.23 0.00e+00 1.283982e-01 1.867174e-02 1.869571e-02 -6.000000e+00 5.902278e-02 230.02 -2.00 3.55 -2.00 501.85 0.00e+00 1.775 0.000 489.00 513.00 1 6.4404e+00 1.4354e-03 3.0538e-03 -6.0000e+00 4.5317e-03 1.2351e-02 3.6459e-04 4.8006e-04 -6.0000e+00 1.1573e-03 2.3904e-03 2.2315e-03 9.7665e-05 2.5926e-05 -6.0000e+00 3.2246e-04 -2.7158e-03 7.7691e-05 10 0 0 10 0 0 99.97 18.13 2.35 -0.00272 0.01276 35 35 1 2 0 779.310 15.00 18.13 21.36 21.69 21.48 26.1 1047.38 -609 -485 -305 -159 93 513 448 574 575 581 135 -29 -248 -36 -353 -259 -316 -231 4 226 164 275 120 119 387 314 163 -6 183 -381 -401 -458 -250 115 303 192 25 158 -24 -187 -136 -81 56 256 322 192 322 87 -62 -182 -571 -673 -648 -764 -393 -176 29 39 257 317 446 289 477 381 268 -29 126 -316 -21 -188 -220 -290 -169 -111 -55 -66 -268 -378 -363 -246 -335 -230 -168 -169 -198 -61 53 -64 -100 -105 58 38 231 408 346 168 145 -103 42 -374 -630 -532 -523 -321 -93 -84 -126 -315 -269 -101 34 37 292 235 556 436 424 392 330 203 167 162 -59 153 271 62 169 320 63 77 269 -122 -137 -235 -241 -220 -20 107 -45 311 316 94 203 187 240 107 -88 -238 -400 -517 -208 -612 -491 -306 -165 98 539 480 620 622 622 143 -30 -265 -38 -369 -271 -334 -242 5 245 178 300 131 127 412 335 173 -6 193 -394 -406 -464 -256 121 317 204 26 166 -25 -198 -144 -83 59 268 339 203 339 91 -63 -188 -576 -664 -631 -746 -390 -179 29 40 263 324 456 297 490 392 274 -30 126 -312 -21 -186 -216 -284 -167 -111 -54 -64 -266 -370 -351 -237 -322 -222 -159 -162 -192 -59 52 -63 -98 -103 57 38 226 401 338 166 140 -97 40 -352 -590 -489 -494 -313 -90 -82 -122 -303 -256 -96 33 36 287 233 555 438 416 385 322 201 163 156 -56 146 260 60 163 307 61 74 255 -114 -127 -216 -220 -203 -19 102 -42 296 302 91 197 182 233 103 -83 -222 -378 -484 -195
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