File name: Pandora17s1_Busan_20180925_L2Fit_fwvt1c5d20180410p1-8.txt File generation date: 20250115T124433.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 17 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora17_OF_v2d20160305.txt Instrument calibration file used: Pandora17s1_CF_v5d20180410.txt Level 1 file used: Pandora17s1_Busan_20180925_L1_smca1c5d20180410p1-8.txt Full location name: Busan/South Korea Short location name: Busan Country of location: South Korea Location latitude [deg]: 35.2353 Location longitude [deg]: 129.0825 Location altitude [m]: 71 Local noon date: 20180925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 4 new wlc for VP from 20180410 and 20190912 First and last pixel inside fitting window: 1644 1793 Nominal wavelengths inside fitting window [nm]: 492.0102 492.1315 492.2528 492.3741 492.4954 492.6166 492.7379 492.8591 492.9803 493.1015 493.2227 493.3439 493.4650 493.5861 493.7073 493.8284 493.9494 494.0705 494.1916 494.3126 494.4336 494.5546 494.6756 494.7966 494.9175 495.0385 495.1594 495.2803 495.4012 495.5220 495.6429 495.7637 495.8846 496.0054 496.1261 496.2469 496.3677 496.4884 496.6091 496.7298 496.8505 496.9712 497.0919 497.2125 497.3331 497.4537 497.5743 497.6949 497.8155 497.9360 498.0565 498.1770 498.2975 498.4180 498.5385 498.6589 498.7793 498.8998 499.0201 499.1405 499.2609 499.3812 499.5016 499.6219 499.7422 499.8624 499.9827 500.1029 500.2232 500.3434 500.4636 500.5838 500.7039 500.8241 500.9442 501.0643 501.1844 501.3045 501.4245 501.5446 501.6646 501.7846 501.9046 502.0246 502.1446 502.2645 502.3844 502.5043 502.6242 502.7441 502.8640 502.9838 503.1037 503.2235 503.3433 503.4630 503.5828 503.7025 503.8223 503.9420 504.0617 504.1814 504.3010 504.4207 504.5403 504.6599 504.7795 504.8991 505.0186 505.1382 505.2577 505.3772 505.4967 505.6162 505.7356 505.8551 505.9745 506.0939 506.2133 506.3327 506.4520 506.5714 506.6907 506.8100 506.9293 507.0486 507.1678 507.2871 507.4063 507.5255 507.6447 507.7638 507.8830 508.0021 508.1213 508.2404 508.3594 508.4785 508.5976 508.7166 508.8356 508.9546 509.0736 509.1926 509.3115 509.4305 509.5494 509.6683 509.7872 509.9060 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180924T213418.0Z 6841.898819 3 1 20.00 2 86.59 93.29 97.69 269.73 0.00 1 0.00 1 0 29 2.925e-02 2.896e-02 2.048e-01 2.038e-01 4.644521e+03 1.292755e+04 4.267167e+02 -6.000000e+00 1.633808e+03 290.07 -2.00 20.00 -2.00 505.25 0.00e+00 1.187778e-03 5.681319e-03 4.612897e-05 -6.000000e+00 8.299239e-04 290.07 -2.00 20.00 -2.00 500.44 0.00e+00 1.048970e+00 3.987588e+00 1.133386e-02 -6.000000e+00 5.747043e-01 228.58 -2.00 3.40 -2.00 502.01 0.00e+00 12.589 0.031 489.00 513.00 1 8.2099e+00 3.0631e-01 1.8531e-02 -6.0000e+00 4.4067e-02 3.0368e-02 7.8998e-02 1.1082e-03 -6.0000e+00 1.1600e-02 8.0925e-05 4.1534e-03 1.7506e-02 4.7996e-05 -6.0000e+00 2.5884e-03 -2.6445e-02 -8.2978e-06 12 8 8 10 0 0 19.94 23.47 1.44 -0.02645 0.00236 5 5 1 4 0 4000.000 26.62 20.02 23.47 900000 -978 -1788 614 -25 -3202 904 3924 882 1631 -1980 9317 694 -4239 3745 253 -5291 1962 -2918 -1177 -1257 693 4073 4218 322 -1099 -1626 -2157 4234 150 -7368 -222 972 3154 2254 90 624 -1913 -1453 2386 -4088 1477 7608 -988 1854 -2341 348 -969 -4077 3500 235 -2476 -5601 1398 -2474 1115 419 1546 -4731 1217 1061 3589 -2313 -700 3491 -1279 -1436 3808 3030 -3443 2071 -1004 -10 1439 4719 -4119 -1412 7 -2530 -1206 2427 -1562 -933 1382 -400 2303 -4126 -2588 2141 5922 1320 1051 1373 92 5035 1170 697 -386 -774 -4576 212 -1634 -113 -183 1159 -380 3473 -2960 766 -3175 -7451 -1317 -1542 924 -1699 1797 -279 1906 1217 7529 -466 -601 -2959 -188 -1072 3588 -2381 2056 -1586 2198 -1596 -2219 4633 549 -1447 432 75 3326 -7476 -178 8354 3962 -1367 2095 3672 -1476 -1970 -98 -455 -3514 900000 -941 -1785 624 -26 -3545 985 4202 977 1777 -2192 8371 670 -4231 3427 240 -5369 1893 -3058 -1233 -1318 715 4066 4211 337 -1170 -1731 -2297 4156 147 -7600 -214 938 3096 2325 96 654 -2036 -1523 2381 -4353 1499 7341 -1052 1944 -2571 371 -1032 -4409 3436 231 -2430 -5592 1302 -2469 1113 432 1594 -5195 1255 1094 3643 -2501 -745 3543 -1340 -1481 3674 2924 -3494 1964 -986 -10 1412 4553 -4317 -1409 6 -2484 -1164 2261 -1534 -916 1334 -399 2260 -4325 -2670 2101 5616 1318 1067 1416 96 4943 1168 684 -373 -734 -4416 194 -1430 -101 -171 1104 -367 3200 -2863 706 -3072 -7666 -1295 -1539 908 -1722 1766 -283 1902 1214 6938 -458 -581 -2909 -182 -1053 3361 -2377 1958 -1559 2093 -1569 -2147 4127 506 -1356 405 72 3167 -8036 -180 7826 3894 -1428 2123 3666 -1541 -2027 -96 -440 -3508 SO 20180924T213604.0Z 6841.900046 5 1 20.00 2 86.23 93.54 98.03 269.99 0.00 1 0.00 1 0 15 3.176e-02 3.119e-02 1.739e-01 1.727e-01 5.326507e+03 1.122514e+04 4.563304e+02 -6.000000e+00 1.773625e+03 290.07 -2.00 20.00 -2.00 505.22 0.00e+00 2.024630e-03 4.819254e-03 1.000767e-04 -6.000000e+00 9.011465e-04 290.07 -2.00 20.00 -2.00 500.34 0.00e+00 7.646702e-01 3.419957e+00 1.892361e-02 -6.000000e+00 6.243005e-01 228.58 -2.00 3.40 -2.00 501.92 0.00e+00 11.862 0.026 489.00 513.00 1 8.1555e+00 2.6258e-01 1.7538e-02 -6.0000e+00 4.7863e-02 4.2250e-02 6.7807e-02 1.0942e-03 -6.0000e+00 1.2612e-02 9.5397e-05 4.6548e-03 1.4796e-02 5.3593e-05 -6.0000e+00 2.8105e-03 6.0161e-02 -5.8517e-04 12 8 8 10 0 0 20.46 23.48 -3.96 0.06016 0.09245 5 5 1 4 0 4000.000 26.73 20.02 23.48 900000 1658 -65 -4712 2321 -1535 -1886 7750 2218 -1613 -2251 3908 -4767 -2103 9300 166 -1510 2144 4019 -1356 -4147 1509 -2459 -3577 -1266 4250 987 415 1261 -2922 384 898 3616 1815 -3671 -225 1337 383 1988 -367 1085 -2156 1692 -3636 242 -4446 4306 1610 -3923 -2096 1633 -3872 -941 752 914 1610 18 -261 -4214 2107 1990 211 -3290 4765 4104 -2873 3575 -2042 8771 -5678 -5574 3382 -42 -30 72 2236 -1393 2441 -2766 -1752 1286 -489 74 647 3669 1712 6147 3053 2731 143 -735 -4724 -2770 2918 4036 -1050 -1907 4090 1962 -4660 -723 941 1147 1716 -4876 529 891 744 2489 -775 -4263 -35 2640 -1790 1283 5775 -1206 -4289 -1195 -1622 752 -1018 883 -4661 14 -1468 -1089 -5302 -1884 5589 2128 -1509 8640 521 -2687 1934 3319 -1909 -3236 746 -1223 -2137 -2731 5478 1496 -4241 1457 10009 -3254 2245 900000 1582 -65 -5147 2428 -1700 -2147 8106 2456 -1836 -2528 3747 -4907 -2076 8130 159 -1490 2086 3967 -1434 -4502 1554 -2635 -3883 -1357 4315 1030 433 1281 -2966 369 861 3416 1817 -4037 -241 1395 400 2019 -378 1102 -2280 1741 -3998 259 -5015 4432 1680 -4259 -2187 1588 -3876 -902 710 889 1612 19 -276 -4634 2169 2048 223 -3618 4837 4166 -3078 3529 -2102 8038 -5925 -5737 3195 -41 -30 74 2207 -1395 2306 -2730 -1704 1215 -475 72 629 3518 1690 5807 2970 2657 143 -746 -5062 -2969 2962 3984 -1065 -1909 3749 1798 -4468 -663 796 1000 1564 -4886 502 835 687 2235 -726 -4217 -33 2508 -1794 1253 5412 -1224 -4521 -1214 -1625 725 -980 828 -4671 13 -1433 -1063 -5382 -1839 5092 1994 -1434 7309 475 -2518 1762 3067 -1888 -3285 738 -1241 -2197 -2843 5276 1499 -4471 1422 8728 -3176 2075 SO 20180924T213746.0Z 6841.901227 7 1 20.00 2 85.89 93.79 98.37 270.23 0.00 1 0.00 1 0 15 2.700e-02 2.691e-02 1.548e-01 1.539e-01 8.265852e+03 1.040210e+04 5.560198e+02 -6.000000e+00 1.508603e+03 290.07 -2.00 20.00 -2.00 505.24 0.00e+00 1.634960e-03 4.304272e-03 8.815619e-05 -6.000000e+00 7.659437e-04 290.07 -2.00 20.00 -2.00 500.39 0.00e+00 2.589705e-01 3.032609e+00 4.803267e-02 -6.000000e+00 5.300010e-01 228.58 -2.00 3.40 -2.00 501.97 0.00e+00 11.219 0.022 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