File name: Pandora20s1_Busan_20240606_L2Fit_fout2c7d20220623p1-8.txt File generation date: 20240606T153018.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Jae Hwan Kim Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 20 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora20_OF_v4d20201001.txt Instrument calibration file used: Pandora20s1_CF_v7d20220623.txt Level 1 file used: Pandora20s1_Busan_20240606_L1_smca1c7d20220623p1-8.txt Full location name: Busan/South Korea Short location name: Busan Country of location: South Korea Location latitude [deg]: 35.2353 Location longitude [deg]: 129.0825 Location altitude [m]: 71 Local noon date: 20240606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Fiel cal based on session 6 First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.0522 305.1935 305.3348 305.4760 305.6172 305.7584 305.8996 306.0408 306.1820 306.3231 306.4642 306.6053 306.7464 306.8875 307.0285 307.1696 307.3106 307.4516 307.5926 307.7336 307.8745 308.0154 308.1564 308.2973 308.4381 308.5790 308.7198 308.8607 309.0015 309.1423 309.2831 309.4238 309.5646 309.7053 309.8460 309.9867 310.1274 310.2680 310.4087 310.5493 310.6899 310.8305 310.9710 311.1116 311.2521 311.3926 311.5331 311.6736 311.8141 311.9545 312.0949 312.2354 312.3757 312.5161 312.6565 312.7968 312.9372 313.0775 313.2178 313.3580 313.4983 313.6385 313.7788 313.9190 314.0592 314.1993 314.3395 314.4796 314.6198 314.7599 314.9000 315.0400 315.1801 315.3201 315.4602 315.6002 315.7402 315.8802 316.0201 316.1601 316.3000 316.4399 316.5798 316.7197 316.8596 316.9994 317.1393 317.2791 317.4189 317.5587 317.6985 317.8382 317.9780 318.1177 318.2575 318.3972 318.5368 318.6765 318.8162 318.9558 319.0955 319.2351 319.3747 319.5143 319.6539 319.7934 319.9330 320.0725 320.2120 320.3515 320.4910 320.6305 320.7700 320.9094 321.0489 321.1883 321.3277 321.4671 321.6065 321.7459 321.8852 322.0246 322.1639 322.3032 322.4426 322.5819 322.7211 322.8604 322.9997 323.1389 323.2782 323.4174 323.5566 323.6958 323.8350 323.9741 324.1133 324.2525 324.3916 324.5307 324.6698 324.8089 324.9480 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240605T223350.4Z 8922.940167 112 1 49.84 2 63.03 80.21 55.30 81.43 0.00 1 0.00 1 0 57 6.032e-02 4.011e-02 5.850e-03 2.033e-03 2.411505e-01 1.079355e-03 9.697562e-04 -6.000000e+00 3.833163e-02 232.34 -2.00 3.40 -2.00 317.37 0.00e+00 6.679464e-03 1.595235e-04 8.906343e-05 -6.000000e+00 1.539702e-03 288.79 -2.00 20.00 -2.00 317.03 0.00e+00 2.193 0.000 302.00 328.00 3 4.9507e+00 2.8682e-03 2.2791e-02 -6.0000e+00 9.6850e-02 -1.1716e-01 3.2345e-03 6.9671e-03 -6.0000e+00 1.0490e-01 -2.2485e-02 1.9215e-03 3.1013e-03 -6.0000e+00 6.1436e-02 1.9838e-02 8.8895e-04 8.9861e-04 -6.0000e+00 2.4866e-02 3.5591e-04 4.3394e-02 6.9684e-05 6.1165e-06 -6.0000e+00 2.0793e-03 1.1058e-01 -2.4529e-04 12 8 8 10 0 0 99.98 22.48 0.12 0.11058 0.43666 28 5 1 5 0 1779.710 26.32 20.00 22.48 27.13 30.2 1024.97 -1644 -420 -10134 -11766 -13592 -9031 -18359 -14448 -13413 -5345 -5072 3498 6151 11845 11115 10387 12196 12379 8730 2561 3263 -1583 -1641 -5632 -6649 -6566 -11247 -8616 -6508 -7594 -8193 -12013 -11650 -8745 -2025 818 3714 4863 5539 4851 5980 6305 4872 3977 1954 1751 1360 1341 2264 3152 2697 3153 120 -1093 -1856 -1803 -707 1854 4900 6109 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7507 9934 10377 8220 5226 762 -3193 -5269 -5067 -2921 571 2952 4372 3933 2473 -300 -3573 -6568 -9015 -8301 -7044 -5660 -4118 -3943 -2789 -1197 998 3327 4466 5041 4580 3576 852 -1474 -1776 -955 1248 900000 SS 20240605T224253.2Z 8922.946450 118 1 50.49 2 61.21 81.36 53.52 82.48 0.00 1 0.00 1 0 57 5.700e-02 4.159e-02 1.418e-03 6.701e-04 2.264988e-01 3.578054e-04 9.876846e-04 -6.000000e+00 3.619719e-02 232.34 -2.00 3.40 -2.00 316.55 0.00e+00 5.493205e-03 4.328630e-05 6.874954e-05 -6.000000e+00 1.455483e-03 288.79 -2.00 20.00 -2.00 316.21 0.00e+00 2.066 0.000 302.00 328.00 3 3.1112e+00 9.4112e-04 2.1555e-02 -6.0000e+00 9.1453e-02 -1.3669e-01 1.0591e-03 6.7731e-03 -6.0000e+00 9.9079e-02 -1.9681e-02 6.0732e-04 2.9759e-03 -6.0000e+00 5.8027e-02 2.0782e-02 2.6626e-04 8.2946e-04 -6.0000e+00 2.3468e-02 2.6185e-03 4.2605e-02 2.2805e-05 5.2716e-06 -6.0000e+00 1.9652e-03 1.1246e-01 -3.8227e-04 12 8 8 10 0 0 99.29 22.51 0.27 0.11246 0.43262 109 21 1 5 0 463.050 26.32 20.00 22.51 27.97 30.1 1030.17 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2243 1429 443 286 805 1552 1888 1780 1331 705 -6 -815 -911 -268 1540 3480 5052 4731 2449 -423 -2916 -3461 -1512 665 1686 2266 1354 -528 -3664 -7194 -10897 -12320 -10438 -8084 -5394 -3464 -2106 -104 2479 4575 6687 7447 6623 4458 859 -3432 -7135 -7584 -6006 -2817 664 3405 3435 1832 -1621 -4580 -4230 -2226 -524 1397 3652 5428 7763 10081 10145 8549 5419 1254 -2797 -4954 -4645 -2585 466 2961 4043 3794 2447 -69 -3075 -6300 -8444 -8111 -6912 -5331 -4189 -3849 -2953 -1082 893 2752 4223 4857 4348 3176 1161 -1201 -1790 -1032 1178 900000 SS 20240605T224805.8Z 8922.950067 121 1 23.46 2 60.15 82.02 52.49 83.09 0.00 1 0.00 1 0 57 5.571e-02 4.158e-02 2.292e-03 1.137e-03 2.223844e-01 6.077486e-04 1.006128e-03 -6.000000e+00 3.535115e-02 232.34 -2.00 3.40 -2.00 316.40 0.00e+00 5.214549e-03 7.049561e-05 6.573504e-05 -6.000000e+00 1.422801e-03 288.79 -2.00 20.00 -2.00 316.06 0.00e+00 2.000 0.000 302.00 328.00 3 3.4419e+00 1.5945e-03 2.0953e-02 -6.0000e+00 8.9313e-02 -1.2953e-01 1.7933e-03 6.7742e-03 -6.0000e+00 9.6781e-02 -1.8063e-02 1.0266e-03 2.9831e-03 -6.0000e+00 5.6681e-02 1.8229e-02 4.4626e-04 8.2636e-04 -6.0000e+00 2.2908e-02 2.0090e-03 4.1817e-02 3.8644e-05 4.4326e-06 -6.0000e+00 1.9204e-03 1.1614e-01 -4.1745e-04 12 9 9 12 1 1 85.18 22.52 0.40 0.11614 0.43037 31 13 1 5 0 732.700 26.32 20.00 22.52 28.35 30.2 1032.69 2899 -2591 -7807 -9098 -9435 -8472 -12131 -12155 -11246 -5395 -176 5445 7440 9873 9257 10043 10031 9753 6461 4548 2694 427 -2023 -4254 -7172 -9228 -9155 -8203 -6198 -6451 -9159 -12561 -11680 -8275 -3252 1662 4494 4752 6035 6017 6252 6180 5678 3440 2103 256 346 1052 1817 2595 2831 1911 1227 331 -994 -1206 -171 2170 4358 6422 5627 3042 -684 -3451 -4332 -1556 814 2142 2418 1599 -591 -3766 -8178 -12397 -13795 -12083 -8731 -5648 -3436 -2009 60 2219 4168 5678 6518 5668 3842 824 -2988 -6583 -7085 -5462 -2330 620 2870 2837 1671 -1515 -3836 -3824 -1795 -566 1087 2886 4183 5757 7194 7360 6319 3964 963 -2039 -3737 -3710 -2025 255 2056 3039 2481 2054 60 -1934 -4782 -6238 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