File name: Pandora118s1_Cabauw_20170714_L2Fit_fwvt1c10d20170202p1-8.txt File generation date: 20241116T025419.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 118 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora118_of_v2d20160829.txt Instrument calibration file used: Pandora118s1_CF_v10d20170202.txt Level 1 file used: Pandora118s1_Cabauw_20170714_L1_smca1c10d20170202p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20170714 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1801 Nominal wavelengths inside fitting window [nm]: 492.0580 492.1793 492.3007 492.4221 492.5434 492.6647 492.7860 492.9073 493.0286 493.1498 493.2711 493.3923 493.5135 493.6347 493.7558 493.8770 493.9981 494.1192 494.2403 494.3614 494.4825 494.6035 494.7246 494.8456 494.9666 495.0875 495.2085 495.3295 495.4504 495.5713 495.6922 495.8131 495.9339 496.0548 496.1756 496.2964 496.4172 496.5380 496.6588 496.7795 496.9002 497.0209 497.1416 497.2623 497.3830 497.5036 497.6242 497.7448 497.8654 497.9860 498.1065 498.2271 498.3476 498.4681 498.5886 498.7091 498.8295 498.9499 499.0704 499.1908 499.3112 499.4315 499.5519 499.6722 499.7925 499.9128 500.0331 500.1534 500.2736 500.3938 500.5140 500.6342 500.7544 500.8746 500.9947 501.1149 501.2350 501.3551 501.4751 501.5952 501.7152 501.8352 501.9553 502.0752 502.1952 502.3152 502.4351 502.5550 502.6749 502.7948 502.9147 503.0345 503.1544 503.2742 503.3940 503.5138 503.6335 503.7533 503.8730 503.9927 504.1124 504.2321 504.3517 504.4714 504.5910 504.7106 504.8302 504.9498 505.0693 505.1889 505.3084 505.4279 505.5474 505.6668 505.7863 505.9057 506.0251 506.1445 506.2639 506.3833 506.5026 506.6219 506.7413 506.8605 506.9798 507.0991 507.2183 507.3375 507.4567 507.5759 507.6951 507.8143 507.9334 508.0525 508.1716 508.2907 508.4098 508.5288 508.6478 508.7668 508.8858 509.0048 509.1238 509.2427 509.3616 509.4805 509.5994 509.7183 509.8371 509.9560 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170714T034533.0Z 6404.156632 251 1 32.01 2 89.83 53.48 59.18 183.20 0.00 1 0.00 1 0 15 1.854e-02 1.853e-02 1.511e-02 1.502e-02 4.562025e+03 1.022068e+03 3.220086e+02 -6.000000e+00 1.070048e+03 283.23 -2.00 20.00 -2.00 505.31 0.00e+00 2.583122e-03 4.212172e-04 1.256203e-04 -6.000000e+00 5.279032e-04 283.23 -2.00 20.00 -2.00 500.29 0.00e+00 2.431044e+00 3.088147e-01 3.701446e-02 -6.000000e+00 3.754611e-01 233.97 -2.00 3.84 -2.00 501.90 0.00e+00 20.089 0.180 489.00 513.00 1 8.1859e+00 2.3744e-02 3.8860e-02 -6.0000e+00 2.8858e-02 1.1557e-01 5.9623e-03 2.2580e-03 -6.0000e+00 7.3722e-03 2.4884e-05 -1.9984e-03 1.6415e-03 5.6902e-05 -6.0000e+00 2.1161e-03 9.4737e-03 7.1797e-05 12 8 8 10 0 0 -73.89 22.55 2.83 0.00947 -0.00439 8 2 1 4 0 4000.000 26.83 20.00 22.55 -2770 27 -3161 20 -1339 -1067 830 1135 -295 -784 548 -753 -708 -3362 3067 446 -887 1084 3132 5449 795 -83 2556 -122 -3483 195 -1774 2964 -4345 703 -692 281 1790 -1868 1419 -2986 284 -2247 1990 46 666 -1673 1737 1320 -64 646 -65 2118 -512 2694 -1517 -1327 1196 -43 34 -104 -411 -1140 2494 801 3200 -2127 -1024 699 1042 -2163 -63 558 498 -547 705 3712 -1498 1242 -2872 902 -307 701 94 2670 1449 -2763 474 -3231 -289 -1870 2118 -2291 845 3496 1760 450 22 -1613 2540 2282 -2092 2153 -3504 141 423 467 -2440 -1572 2583 2484 67 -379 -731 -2055 61 -719 -1955 3512 996 896 1408 2725 -1367 -295 -2688 -632 -2681 2597 -2139 1245 2355 1556 -1133 -2851 -912 785 1218 -794 1296 276 1113 1484 -3145 -2325 -25 -1114 604 1055 -1430 2174 -526 3040 -2305 -1548 -2689 26 -3200 20 -1407 -1143 886 1213 -320 -844 573 -786 -729 -3518 3008 450 -921 1126 3250 5590 856 -90 2715 -133 -3932 213 -1961 3080 -4747 715 -702 284 1816 -2014 1512 -3334 307 -2456 2071 49 700 -1808 1834 1414 -71 703 -71 2224 -541 2688 -1538 -1317 1154 -43 35 -108 -433 -1214 2575 838 3283 -2300 -1096 732 1077 -2274 -64 553 488 -535 677 3481 -1486 1208 -2906 873 -295 659 89 2432 1339 -2667 446 -3168 -278 -1829 1998 -2248 803 3246 1677 437 22 -1606 2393 2117 -1972 1903 -3198 123 369 414 -2293 -1501 2404 2317 63 -358 -691 -1980 59 -704 -1953 3364 981 889 1396 2662 -1375 -290 -2664 -609 -2628 2431 -2100 1186 2219 1476 -1103 -2799 -873 728 1113 -737 1186 259 1053 1421 -3188 -2353 -25 -1127 604 1050 -1452 2103 -513 2821 -2228 -1489 SO 20170714T034940.0Z 6404.159491 255 1 32.01 2 89.32 54.28 59.20 184.36 0.00 1 0.00 1 0 15 1.186e-02 1.170e-02 1.056e-02 1.051e-02 5.956326e+03 7.278368e+02 3.945499e+02 -6.000000e+00 6.846807e+02 283.23 -2.00 20.00 -2.00 505.34 0.00e+00 3.127689e-03 2.949397e-04 1.684843e-04 -6.000000e+00 3.379461e-04 283.23 -2.00 20.00 -2.00 500.43 0.00e+00 2.233990e+00 2.146422e-01 5.211646e-02 -6.000000e+00 2.408008e-01 233.97 -2.00 3.84 -2.00 502.03 0.00e+00 19.231 0.158 489.00 513.00 1 7.9331e+00 1.6484e-02 3.6110e-02 -6.0000e+00 1.8501e-02 8.9909e-02 4.1294e-03 2.2320e-03 -6.0000e+00 4.7396e-03 3.6371e-05 9.3735e-04 1.1503e-03 7.4090e-05 -6.0000e+00 1.3552e-03 9.5637e-03 -1.0187e-04 12 8 8 10 0 0 68.56 22.55 0.92 0.00956 0.01607 8 2 1 4 0 4000.000 26.83 20.00 22.55 -263 -1241 1120 -152 -1963 105 -792 -152 -1724 688 -58 -10 484 2673 -1017 127 -1322 1275 -1190 -116 463 283 739 -375 -1580 287 835 -1561 -197 907 604 2581 113 -835 -36 147 943 -1766 1303 -1691 2111 501 1807 903 709 -733 -597 -593 1502 -707 -682 -97 -572 680 86 -396 -766 471 -457 1508 763 1181 -862 -134 1068 -740 -724 517 -1073 -498 1261 686 -728 -565 -1785 -399 -1219 1749 -297 -130 1062 479 1536 -822 280 1509 -1629 -493 2027 -2005 -466 684 93 -186 -631 942 3516 -3019 1504 -2087 -244 824 -828 1657 -2522 294 405 257 335 -1171 -864 -328 -157 380 -219 -519 3914 489 85 87 2200 -317 403 870 -1244 2025 57 -58 -2207 -34 -1150 -50 903 -907 -1004 1840 836 -1922 1364 -1868 2094 -831 446 -1324 -975 -440 -121 213 -320 395 -244 -1173 1063 -151 -2026 109 -837 -161 -1851 714 -60 -10 484 2586 -1013 126 -1347 1293 -1258 -122 488 300 780 -402 -1716 307 884 -1663 -203 906 597 2512 115 -877 -38 157 994 -1895 1348 -1788 2162 524 1887 959 761 -800 -647 -634 1548 -724 -683 -94 -558 662 86 -408 -804 493 -484 1566 800 1233 -920 -141 1103 -767 -739 515 -1073 -490 1211 664 -718 -561 -1798 -393 -1192 1641 -281 -122 988 451 1440 -792 269 1438 -1602 -479 1917 -1973 -455 668 92 -184 -618 887 3157 -2812 1316 -1869 -215 733 -770 1543 -2485 283 388 244 317 -1135 -843 -323 -157 379 -222 -530 3851 496 86 87 2120 -310 390 842 -1231 1953 56 -57 -2212 -33 -1125 -48 845 -861 -960 1738 809 -1940 1351 -1925 2097 -859 458 -1378 -1010 -448 -121 208 -311 383 SO 20170714T035340.0Z 6404.162269 259 1 32.00 2 88.82 55.07 59.25 185.49 0.00 1 0.00 1 0 22 7.942e-03 7.874e-03 4.251e-03 4.220e-03 1.094886e+04 3.066485e+02 7.248180e+02 -6.000000e+00 4.584577e+02 283.23 -2.00 20.00 -2.00 505.55 0.00e+00 4.797326e-03 1.199385e-04 2.635410e-04 -6.000000e+00 2.262551e-04 283.23 -2.00 20.00 -2.00 501.12 0.00e+00 1.695870e+00 8.375710e-02 9.196335e-02 -6.000000e+00 1.611697e-01 233.97 -2.00 3.84 -2.00 502.66 0.00e+00 18.090 0.131 489.00 513.00 1 7.0779e+00 6.4357e-03 3.3529e-02 -6.0000e+00 1.2383e-02 -5.6047e-03 1.5641e-03 2.6887e-03 -6.0000e+00 3.1709e-03 1.0167e-04 2.1850e-03 4.5557e-04 1.2387e-04 -6.0000e+00 9.0727e-04 1.4446e-02 -1.0127e-04 12 8 8 10 0 0 81.69 22.54 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