File name: Pandora118s1_Cabauw_20190212_L2Fit_fwvt1c13d20181201p1-8.txt File generation date: 20241121T213535.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 118 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora118_of_v4d20181020.txt Instrument calibration file used: Pandora118s1_CF_v13d20181201.txt Level 1 file used: Pandora118s1_Cabauw_20190212_L1_smca1c13d20181201p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20190212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: For 2019Data new WL applied First and last pixel inside fitting window: 1652 1800 Nominal wavelengths inside fitting window [nm]: 492.1196 492.2409 492.3623 492.4836 492.6049 492.7262 492.8475 492.9687 493.0900 493.2112 493.3324 493.4536 493.5747 493.6959 493.8170 493.9382 494.0593 494.1803 494.3014 494.4225 494.5435 494.6645 494.7855 494.9065 495.0275 495.1484 495.2693 495.3903 495.5112 495.6320 495.7529 495.8737 495.9946 496.1154 496.2362 496.3570 496.4777 496.5985 496.7192 496.8399 496.9606 497.0813 497.2019 497.3226 497.4432 497.5638 497.6844 497.8050 497.9255 498.0461 498.1666 498.2871 498.4076 498.5281 498.6485 498.7689 498.8894 499.0098 499.1302 499.2505 499.3709 499.4912 499.6115 499.7318 499.8521 499.9724 500.0926 500.2129 500.3331 500.4533 500.5734 500.6936 500.8138 500.9339 501.0540 501.1741 501.2942 501.4142 501.5343 501.6543 501.7743 501.8943 502.0143 502.1342 502.2542 502.3741 502.4940 502.6139 502.7337 502.8536 502.9734 503.0933 503.2131 503.3328 503.4526 503.5724 503.6921 503.8118 503.9315 504.0512 504.1709 504.2905 504.4101 504.5297 504.6493 504.7689 504.8885 505.0080 505.1276 505.2471 505.3666 505.4860 505.6055 505.7249 505.8444 505.9638 506.0831 506.2025 506.3219 506.4412 506.5605 506.6798 506.7991 506.9184 507.0376 507.1569 507.2761 507.3953 507.5145 507.6336 507.7528 507.8719 507.9910 508.1101 508.2292 508.3482 508.4673 508.5863 508.7053 508.8243 508.9433 509.0622 509.1812 509.3001 509.4190 509.5379 509.6568 509.7756 509.8945 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190212T070847.0Z 6982.297766 502 1 20.01 2 89.82 112.96 112.23 31.21 0.00 1 0.00 1 0 15 2.844e-02 2.796e-02 3.294e-02 3.273e-02 3.697630e+03 2.111211e+03 3.116531e+02 -6.000000e+00 1.572639e+03 266.97 -2.00 20.00 -2.00 505.36 0.00e+00 4.138901e-03 8.949687e-04 2.237040e-04 -6.000000e+00 7.883026e-04 266.97 -2.00 20.00 -2.00 500.50 0.00e+00 3.719524e+00 6.759538e-01 4.855225e-02 -6.000000e+00 5.845746e-01 223.48 -2.00 3.84 -2.00 502.08 0.00e+00 20.582 0.193 489.00 513.00 1 8.4300e+00 5.1708e-02 4.0757e-02 -6.0000e+00 4.4726e-02 6.5428e-02 1.2894e-02 2.3743e-03 -6.0000e+00 1.1483e-02 1.6495e-05 4.6553e-03 3.8243e-03 1.1133e-04 -6.0000e+00 3.4524e-03 3.8120e-02 -4.4198e-05 12 8 8 10 0 0 -4.94 16.55 5.40 0.03812 0.07041 5 5 1 4 0 4000.000 21.17 14.98 16.55 3675 355 1065 -3944 3318 38 -2021 -3734 2626 4863 2480 4507 -719 -685 -133 4115 -1026 5487 -1684 -2621 590 -1794 -3884 1655 3076 -3588 7867 -4238 608 -3929 968 633 4352 -2622 -33 -1779 4682 -1371 -1625 -2402 -243 -7 287 -632 -124 -3537 3875 -891 -342 -3204 3391 -1180 5784 -2295 -1437 -685 -164 -3749 -1426 488 -3854 580 455 1806 -4404 2307 2904 -2244 -2154 -657 2153 -1536 5878 773 3816 -236 2303 -4538 1015 4916 -1360 3781 -960 4798 -2482 116 -4332 2608 -247 6556 -1284 -2889 -1741 -4292 -399 -508 -700 -159 2824 5512 -49 -3351 -1542 -2010 3274 5340 -3193 -2644 -4683 2818 -2190 1120 866 -365 74 1542 1393 -31 -2344 -661 450 -5094 4034 1616 1229 -5273 -1178 2280 4952 -1803 1590 5099 -2154 1373 -1142 1004 403 3795 1420 -3001 -822 -1200 1679 -1918 1110 2893 1387 -440 -1274 3289 336 1032 -4105 3296 39 -2162 -4044 2652 4751 2437 4303 -714 -677 -131 3952 -1055 5387 -1791 -2829 619 -1935 -4285 1740 3190 -3941 7633 -4536 608 -4043 955 638 4338 -2847 -35 -1925 4730 -1456 -1725 -2569 -257 -7 308 -688 -135 -3953 3984 -940 -352 -3315 3235 -1167 5407 -2362 -1503 -722 -173 -4119 -1532 515 -4247 614 481 1862 -4749 2297 2832 -2268 -2159 -644 2052 -1524 5476 756 3599 -227 2142 -4468 942 4403 -1296 3445 -920 4376 -2434 111 -4309 2427 -236 5929 -1266 -2907 -1731 -4330 -381 -474 -640 -142 2421 4594 -44 -3161 -1465 -1940 3011 4781 -3087 -2546 -4629 2633 -2180 1095 858 -368 74 1542 1394 -31 -2384 -655 438 -5224 3805 1565 1200 -5484 -1180 2207 4654 -1794 1517 4645 -2097 1301 -1126 985 403 3723 1441 -3200 -862 -1269 1728 -2032 1133 2855 1367 -438 -1279 SO 20190212T071245.0Z 6982.300521 506 1 20.01 2 89.26 113.74 111.91 32.16 0.00 1 0.00 1 0 22 1.924e-02 1.904e-02 2.325e-02 2.314e-02 8.514888e+03 1.610984e+03 5.308991e+02 -6.000000e+00 1.064265e+03 266.97 -2.00 20.00 -2.00 505.38 0.00e+00 4.376709e-03 6.362372e-04 2.367826e-04 -6.000000e+00 5.334386e-04 266.97 -2.00 20.00 -2.00 500.58 0.00e+00 2.490528e+00 4.773440e-01 9.135166e-02 -6.000000e+00 3.958872e-01 223.48 -2.00 3.84 -2.00 502.16 0.00e+00 19.539 0.165 489.00 513.00 1 8.2887e+00 3.6470e-02 3.7635e-02 -6.0000e+00 3.0285e-02 6.3502e-02 9.0677e-03 2.7542e-03 -6.0000e+00 7.7832e-03 2.3831e-05 4.6507e-04 2.6393e-03 1.1214e-04 -6.0000e+00 2.3379e-03 -2.3191e-02 2.1316e-04 12 8 8 10 0 0 -358.38 16.55 3.75 -0.02319 -0.01997 5 5 1 4 0 4000.000 21.17 15.01 16.55 1080 1557 -3241 -1575 1258 -37 -2164 -991 -920 -1886 639 -1413 -301 -2583 -1033 889 4069 -546 2362 577 -2999 991 410 -638 -1505 -1287 670 1914 1907 -1151 3051 -2080 1703 812 522 -522 2008 2516 1502 3074 -260 580 -2574 276 400 216 -2567 -5 -1116 -1938 -1322 366 1146 -264 -955 -1819 360 -1381 1185 -555 2748 1673 -164 333 3598 2197 -584 -59 -1980 3388 -467 123 -1046 2827 -2026 -456 -786 3899 3839 1047 -903 -2273 1454 1390 -61 -4854 -2674 -3775 -2598 -95 3198 3307 -63 2206 -1705 -1309 -913 -189 637 -1139 1576 -473 2926 229 2096 -3244 2824 2815 -1333 -1668 -235 3300 -373 1972 -2362 -962 -840 2191 81 -1927 1232 1465 591 -4529 1751 -2017 1290 -2105 1165 771 4685 2545 -807 2089 -1420 -1088 -1680 -604 -1653 1106 -2767 1251 -1892 -398 350 -1135 -521 3485 -1450 973 1430 -3196 -1573 1252 -38 -2280 -1033 -952 -1945 636 -1415 -295 -2564 -1013 865 3909 -556 2380 595 -3203 1024 427 -675 -1603 -1364 692 1918 1875 -1142 2903 -2110 1707 838 547 -551 2062 2550 1532 3090 -272 607 -2806 296 430 232 -2799 -5 -1159 -1983 -1322 356 1111 -263 -982 -1928 378 -1479 1240 -592 2845 1754 -174 351 3624 2211 -596 -59 -2000 3228 -459 121 -1047 2742 -2046 -447 -764 3591 3507 982 -862 -2214 1374 1324 -60 -4912 -2651 -3762 -2566 -92 3027 3151 -61 2098 -1642 -1226 -831 -168 552 -996 1363 -428 2638 217 1969 -3203 2621 2612 -1294 -1645 -231 3182 -375 1954 -2456 -994 -871 2198 82 -1967 1205 1422 580 -4687 1716 -2050 1269 -2137 1146 757 4387 2400 -783 1981 -1409 -1094 -1723 -622 -1736 1141 -2979 1303 -2032 -420 363 -1180 -532 3388 -1471 SO 20190212T071638.0Z 6982.303218 510 1 20.01 2 88.71 114.51 111.59 33.08 0.00 1 0.00 1 0 22 7.423e-03 7.381e-03 7.716e-03 7.685e-03 9.969306e+03 5.334155e+02 7.087116e+02 -6.000000e+00 4.104874e+02 266.97 -2.00 20.00 -2.00 505.43 0.00e+00 6.323473e-03 2.115503e-04 3.351411e-04 -6.000000e+00 2.057959e-04 266.97 -2.00 20.00 -2.00 500.94 0.00e+00 1.492725e+00 1.562089e-01 9.275747e-02 -6.000000e+00 1.528148e-01 223.48 -2.00 3.84 -2.00 502.45 0.00e+00 18.176 0.133 489.00 513.00 1 7.2901e+00 1.1923e-02 3.3982e-02 -6.0000e+00 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