File name: Pandora118s1_Cabauw_20250216_L2Fit_fout2c7d20210820p1-8.txt File generation date: 20250217T000036.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 118 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora118_OF_v3d20200505.txt Instrument calibration file used: Pandora118s1_CF_v7d20210820.txt Level 1 file used: Pandora118s1_Cabauw_20250216_L1_smca1c7d20210820p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20250216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: newDate as OF is out there First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0994 305.2405 305.3816 305.5226 305.6636 305.8047 305.9457 306.0867 306.2277 306.3686 306.5096 306.6506 306.7915 306.9324 307.0734 307.2143 307.3552 307.4961 307.6369 307.7778 307.9186 308.0595 308.2003 308.3411 308.4819 308.6227 308.7635 308.9043 309.0451 309.1858 309.3266 309.4673 309.6080 309.7487 309.8894 310.0301 310.1708 310.3114 310.4521 310.5927 310.7333 310.8739 311.0145 311.1551 311.2957 311.4363 311.5769 311.7174 311.8579 311.9985 312.1390 312.2795 312.4200 312.5604 312.7009 312.8414 312.9818 313.1222 313.2627 313.4031 313.5435 313.6839 313.8242 313.9646 314.1050 314.2453 314.3856 314.5259 314.6663 314.8065 314.9468 315.0871 315.2274 315.3676 315.5079 315.6481 315.7883 315.9285 316.0687 316.2089 316.3490 316.4892 316.6293 316.7695 316.9096 317.0497 317.1898 317.3299 317.4700 317.6101 317.7501 317.8902 318.0302 318.1702 318.3102 318.4502 318.5902 318.7302 318.8701 319.0101 319.1500 319.2900 319.4299 319.5698 319.7097 319.8496 319.9894 320.1293 320.2691 320.4090 320.5488 320.6886 320.8284 320.9682 321.1080 321.2477 321.3875 321.5272 321.6670 321.8067 321.9464 322.0861 322.2258 322.3654 322.5051 322.6448 322.7844 322.9240 323.0636 323.2032 323.3428 323.4824 323.6220 323.7615 323.9011 324.0406 324.1801 324.3197 324.4592 324.5986 324.7381 324.8776 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250216T074503.8Z 9178.322961 280 1 49.62 2 83.50 119.41 88.15 258.28 0.00 1 0.00 1 0 17 8.811e-01 4.019e-02 3.701e-01 1.614e-02 1.080890e+00 9.455630e-03 1.311203e-02 -6.000000e+00 5.121376e-01 223.72 -2.00 3.84 -2.00 322.22 0.00e+00 -2.812888e-02 3.589965e-03 6.119856e-03 -6.000000e+00 2.414407e-02 267.13 -2.00 20.00 -2.00 321.80 0.00e+00 8.025 0.011 302.00 328.00 3 1.1916e+00 3.1128e-02 1.1675e-01 -6.0000e+00 1.2775e+00 1.7671e+00 3.8960e-02 1.1185e-01 -6.0000e+00 1.3977e+00 -2.2941e+00 3.1792e-02 3.5617e-02 -6.0000e+00 8.1323e-01 8.9506e-01 1.6932e-02 2.4190e-02 -6.0000e+00 3.4700e-01 1.7856e-05 -1.6177e-03 4.1320e-04 2.6336e-04 -6.0000e+00 2.5379e-02 4.3952e-02 0.0000e+00 12 8 8 10 0 0 44.76 20.04 0.85 0.04395 0.03180 27 6 1 5 0 1837.700 20.04 15.01 15.90 5.59 38.0 1004.37 119305 285872 173322 -52248 900000 11696 900000 900000 900000 900000 7734 67769 149691 145986 193940 900000 98257 186613 89814 104215 -19396 900000 440492 157613 9925 -81512 900000 41606 900000 -57173 900000 52208 -23547 95543 53067 198853 61666 900000 113288 181238 151503 67789 101381 34101 900000 265175 118026 181098 66802 95263 172308 900000 71959 61548 41345 27087 251128 60688 160328 83236 24798 39608 32783 29810 43469 18225 23484 15079 48017 19136 25176 20556 25623 36835 46968 81229 19701 -12395 4432 1578 -8788 9572 1040 -1270 1214 3595 -2388 -4977 3727 16084 4080 -5853 -4863 -1833 -3861 6528 1315 -3797 -3689 -8768 -4639 -9395 -7743 -4807 -3324 5200 2014 -5510 -5314 -4725 -2991 744 504 36 1322 -1309 -705 1073 1732 444 5994 2637 1296 8368 -1330 2093 2503 1257 2265 -2254 322 -1832 382 -739 2361 1960 907 -747 -1180 -1025 -1284 -1665 3628 4487 2720 -5084 900000 527 900000 900000 900000 900000 546 2752 2814 2967 3044 900000 3353 2929 2990 2765 -1551 900000 6913 2982 857 -16487 900000 1771 900000 -5825 900000 2268 -2245 2669 2008 3121 2408 900000 4036 3813 4506 4465 4432 2553 900000 4162 3191 2842 3213 3826 3648 900000 4865 4995 4356 3441 3941 5116 4515 4519 2363 3577 3588 3675 4726 2530 3274 2503 6665 3896 5059 4251 4681 5357 5353 6038 2663 -2516 914 398 -2875 2999 380 -503 495 1479 -1052 -2220 1471 5271 1420 -2239 -1966 -828 -2098 3773 928 -3166 -3179 -7588 -3506 -6568 -5051 -3210 -2325 3536 1532 -5024 -5621 -5789 -4042 1034 714 50 1777 -1803 -1000 1565 2578 653 7921 3413 1655 9760 -1658 2467 3055 1794 3759 -4414 679 -4225 927 -1942 6359 5387 2527 -2100 -3180 -2555 -2957 -3625 SS 20250216T075604.7Z 9178.330610 283 1 49.02 2 82.04 121.68 89.81 260.37 0.00 1 0.00 1 0 25 5.405e-01 2.408e-02 2.308e-01 6.233e-03 9.529811e-01 3.465299e-03 1.135536e-02 -6.000000e+00 3.084127e-01 223.72 -2.00 3.84 -2.00 321.90 0.00e+00 3.418211e-03 1.582254e-03 1.426309e-03 -6.000000e+00 1.328948e-02 267.13 -2.00 20.00 -2.00 321.51 0.00e+00 6.757 0.007 302.00 328.00 3 1.0505e+00 1.1421e-02 8.7131e-02 -6.0000e+00 7.6594e-01 9.0715e-01 1.6275e-02 5.7009e-02 -6.0000e+00 8.3791e-01 -1.1898e+00 1.7297e-02 3.1851e-02 -6.0000e+00 4.9107e-01 4.8439e-01 8.3125e-03 1.0958e-02 -6.0000e+00 2.0775e-01 8.0823e-05 -1.9373e-03 1.5973e-04 1.4076e-04 -6.0000e+00 1.4685e-02 4.4345e-02 0.0000e+00 12 8 8 10 0 0 75.02 20.04 0.47 0.04434 0.02979 68 15 1 5 0 720.730 20.04 15.00 15.90 6.15 37.8 1006.83 -157447 -125330 -163378 -176454 900000 -121415 900000 -61444 900000 -127576 -144619 -100594 -35700 112613 -56788 900000 -61591 48271 12304 16954 -7329 34422 48406 -47978 -62980 -147069 135765 49616 81769 -25837 56783 25743 -42621 72583 39478 65928 97989 11940 74278 11203 50797 32651 48056 57232 219334 104052 12913 40125 35561 27499 68937 109176 46658 24705 22999 19753 45052 28879 41457 44075 8130 22826 16619 20527 21893 11735 20048 5225 20549 6131 15443 10565 7136 17494 7415 15187 -3706 -4088 916 1301 571 997 -321 -3658 -917 551 -1237 2209 295 3899 -2759 -2451 -4472 -1251 -1550 -1318 839 -3466 -1272 -4065 -1196 -1193 -2501 -2703 -4200 -857 -1703 -2643 -1640 -895 -689 -1391 -475 -1001 649 207 305 980 847 981 1819 2630 679 3257 1553 1949 2456 -210 349 -341 942 763 739 -40 171 558 -175 -617 -898 -288 -390 -1589 -4223 -2601 -4796 -5090 900000 -1877 900000 -577 900000 -2465 -3513 -1944 -473 684 -1474 900000 -2108 586 217 281 -146 437 561 -1536 -2399 -11909 825 548 677 -756 909 668 -2447 1282 894 1165 1407 481 1927 625 2047 1640 2096 2243 1865 2585 827 2082 2081 1943 3654 4280 3735 2646 2603 2367 4154 2966 3525 3577 1005 2785 2313 3075 3302 1966 3237 1066 4139 1604 3877 2759 1799 3559 1463 2536 -758 -948 247 423 220 435 -152 -1897 -491 304 -713 1232 162 1938 -1374 -1190 -2315 -717 -985 -997 736 -3612 -1348 -4231 -1088 -950 -1898 -2166 -3634 -755 -1641 -2868 -2041 -1195 -1024 -2184 -741 -1522 935 299 459 1541 1382 1569 2720 3701 943 4252 2006 2622 3160 -322 628 -657 1979 1725 1792 -99 445 1476 -470 -1662 -2310 -722 -900 -3476 SS 20250216T080749.5Z 9178.338767 286 1 49.39 2 80.52 124.15 91.58 262.60 0.00 1 0.00 1 0 17 6.354e-01 1.139e-02 1.352e-01 3.040e-03 8.464608e-01 1.629814e-03 1.018508e-02 -6.000000e+00 3.561987e-01 223.72 -2.00 3.84 -2.00 321.46 0.00e+00 4.952630e-03 7.203259e-04 1.266372e-03 -6.000000e+00 1.499974e-02 267.13 -2.00 20.00 -2.00 321.08 0.00e+00 5.788 0.004 302.00 328.00 3 9.7750e-01 5.1686e-03 7.5845e-02 -6.0000e+00 8.8175e-01 3.2691e-01 7.8115e-03 5.1600e-02 -6.0000e+00 9.6220e-01 -3.8450e-01 9.2263e-03 2.8840e-02 -6.0000e+00 5.6956e-01 1.4850e-01 4.4202e-03 1.1258e-02 -6.0000e+00 2.4337e-01 2.5989e-04 -1.0652e-03 7.7538e-05 1.2134e-04 -6.0000e+00 1.6966e-02 4.3730e-02 0.0000e+00 12 8 8 10 0 0 42.02 20.04 0.41 0.04373 0.03573 138 30 1 5 0 357.860 20.04 14.99 15.92 6.30 38.0 1008.13 -223653 -219029 -188987 -247653 -185181 -242357 -180170 -120114 -196696 -140479 -177592 -177946 -92675 -101546 -60691 -24024 -45485 -52611 -52216 -20222 -106063 -19964 -61284 -74187 -86741 -106172 -13340 -72286 -1828 -73574 -2176 -24728 -22892 5201 -24462 12647 721 -1135 2229 1364 12220 4036 9569 -3567 50641 14491 12469 2279 6345 9483 11702 24835 7833 10350 6139 5445 8563 125 9827 4103 4893 4900 8210 7382 3971 4804 2416 3595 2809 4357 4693 2043 1905 538 910 816 -2931 -825 -1298 271 -1135 -1572 -1284 -1141 -1149 -462 179 158 735 348 408 -772 -742 -689 -1274 329 788 74 -682 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