File name: Pandora118s1_Cabauw_20250702_L2Fit_fout2c7d20210820p1-8.txt File generation date: 20250702T235703.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Ankie Piters Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 118 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora118_OF_v3d20200505.txt Instrument calibration file used: Pandora118s1_CF_v7d20210820.txt Level 1 file used: Pandora118s1_Cabauw_20250702_L1_smca1c7d20210820p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20250702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: newDate as OF is out there First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0994 305.2405 305.3816 305.5226 305.6636 305.8047 305.9457 306.0867 306.2277 306.3686 306.5096 306.6506 306.7915 306.9324 307.0734 307.2143 307.3552 307.4961 307.6369 307.7778 307.9186 308.0595 308.2003 308.3411 308.4819 308.6227 308.7635 308.9043 309.0451 309.1858 309.3266 309.4673 309.6080 309.7487 309.8894 310.0301 310.1708 310.3114 310.4521 310.5927 310.7333 310.8739 311.0145 311.1551 311.2957 311.4363 311.5769 311.7174 311.8579 311.9985 312.1390 312.2795 312.4200 312.5604 312.7009 312.8414 312.9818 313.1222 313.2627 313.4031 313.5435 313.6839 313.8242 313.9646 314.1050 314.2453 314.3856 314.5259 314.6663 314.8065 314.9468 315.0871 315.2274 315.3676 315.5079 315.6481 315.7883 315.9285 316.0687 316.2089 316.3490 316.4892 316.6293 316.7695 316.9096 317.0497 317.1898 317.3299 317.4700 317.6101 317.7501 317.8902 318.0302 318.1702 318.3102 318.4502 318.5902 318.7302 318.8701 319.0101 319.1500 319.2900 319.4299 319.5698 319.7097 319.8496 319.9894 320.1293 320.2691 320.4090 320.5488 320.6886 320.8284 320.9682 321.1080 321.2477 321.3875 321.5272 321.6670 321.8067 321.9464 322.0861 322.2258 322.3654 322.5051 322.6448 322.7844 322.9240 323.0636 323.2032 323.3428 323.4824 323.6220 323.7615 323.9011 324.0406 324.1801 324.3197 324.4592 324.5986 324.7381 324.8776 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250702T044451.2Z 9314.197814 95 1 49.30 2 80.66 64.35 130.99 351.68 0.00 1 0.00 1 0 25 4.344e-01 2.481e-02 2.445e-01 8.444e-03 7.022756e-01 4.792337e-03 8.629662e-03 -6.000000e+00 2.600295e-01 233.79 -2.00 3.84 -2.00 321.34 0.00e+00 -2.270628e-03 2.212656e-03 6.898025e-04 -6.000000e+00 1.206348e-02 282.14 -2.00 20.00 -2.00 320.79 0.00e+00 5.858 0.004 302.00 328.00 3 2.9025e+00 1.6278e-02 7.2321e-02 -6.0000e+00 6.5764e-01 3.8616e-01 2.1648e-02 4.3093e-02 -6.0000e+00 7.1070e-01 -6.2860e-01 2.0005e-02 2.1733e-02 -6.0000e+00 4.1654e-01 2.7065e-01 9.5357e-03 7.3597e-03 -6.0000e+00 1.7684e-01 4.2048e-05 -1.8929e-03 2.4260e-04 8.3559e-05 -6.0000e+00 1.2189e-02 2.4542e-02 0.0000e+00 12 8 8 10 0 0 99.11 20.04 0.46 0.02454 0.01032 21 5 1 5 0 2347.260 20.04 15.00 16.56 28.08 39.6 1014.35 -107614 -114576 6041 27632 900000 -91957 900000 900000 86068 900000 -102905 -94170 10757 -54113 278636 50304 -7585 45194 -18789 14526 -106193 -20787 60721 -45092 -55401 -93168 900000 -2148 900000 -110454 900000 28222 -10466 131479 7022 72224 -23759 24874 12700 64657 25568 44138 64377 -14042 900000 26804 28679 25084 12412 35215 27036 85183 12476 15677 2896 18695 32411 -815 18758 3245 15779 10780 17236 9940 19614 13881 6354 -2125 7831 7104 -227 290 4527 -3207 8884 6876 1805 -5036 -5813 -1935 -2274 977 -1302 -1140 -1797 -1365 -3557 -741 1507 -2165 875 -4732 4809 -1168 -1047 5311 -886 -581 -2438 -2194 414 -2150 -2067 -3972 -2964 -538 1490 -2177 -1225 -64 -2032 347 -211 259 1026 925 445 -1142 -982 -1095 1688 1999 2921 3657 328 750 642 1236 -261 442 765 762 672 48 445 -771 365 163 -541 -168 -1718 -804 -2146 -2646 50 227 900000 -1413 900000 900000 707 900000 -2601 -2505 127 -1455 2290 668 -190 729 -586 337 -7656 -666 951 -2134 -3062 -7591 900000 -67 900000 -10418 900000 966 -580 1876 311 1758 -1635 1292 899 3250 2014 3056 3759 -1708 900000 2227 2375 2209 1286 3195 2960 5948 1873 2465 538 3106 4819 -162 2982 588 2661 2122 3599 2430 4422 3198 1599 -613 2336 2414 -88 114 1653 -1176 2627 1882 503 -1592 -2133 -808 -1091 511 -742 -687 -1168 -932 -2571 -528 1039 -1466 540 -2935 2728 -757 -771 4238 -853 -620 -2753 -2395 410 -1990 -1832 -3775 -2986 -554 1599 -2587 -1590 -91 -3161 545 -330 390 1465 1308 650 -1781 -1598 -1808 2652 3038 4304 5181 465 1027 879 1832 -437 804 1487 1547 1426 107 1050 -1880 896 404 -1321 -391 -3848 -1718 SS 20250702T045636.2Z 9314.205975 101 1 49.48 2 79.02 66.53 131.23 355.41 0.00 1 0.00 1 0 25 3.432e-01 9.631e-03 1.612e-01 3.576e-03 6.173064e-01 1.925887e-03 7.622019e-03 -6.000000e+00 2.003707e-01 233.79 -2.00 3.84 -2.00 320.88 0.00e+00 1.972925e-03 8.099649e-04 4.616687e-04 -6.000000e+00 8.616809e-03 282.14 -2.00 20.00 -2.00 320.30 0.00e+00 5.057 0.003 302.00 328.00 3 2.3019e+00 6.2067e-03 6.2653e-02 -6.0000e+00 5.0555e-01 5.8443e-02 8.1341e-03 3.7195e-02 -6.0000e+00 5.4566e-01 -1.3060e-01 7.8718e-03 1.8843e-02 -6.0000e+00 3.2315e-01 4.7608e-02 3.8447e-03 5.9685e-03 -6.0000e+00 1.3726e-01 1.8430e-04 -8.5509e-04 1.0086e-04 6.4551e-05 -6.0000e+00 9.1829e-03 2.3699e-02 0.0000e+00 12 8 8 10 0 0 -1.82 20.04 0.42 0.02370 0.01727 64 14 1 5 0 773.040 20.04 15.01 16.59 28.57 39.8 1016.61 -143546 -105651 -35489 -136568 19668 -151629 103991 -65472 -53813 -86870 -137463 -110347 -73268 -37331 -52344 -19019 -42100 -18452 -33979 -31285 -51072 -34207 -4281 -39748 -36223 -45549 2204 -8893 -2106 -44777 23122 3063 -10541 13211 -17385 -234 -975 -2039 4806 6288 4204 3490 5436 -6616 25264 4895 4254 350 -1143 6490 2188 11035 3524 3955 2047 1604 5387 -2371 2071 2627 3688 1412 5626 1854 1986 1542 849 1346 2071 2213 125 565 391 -32 -786 1317 -1757 -2554 702 -1910 -1268 -1816 -1273 -1333 -891 367 -522 379 151 154 525 -796 1068 -233 -49 376 1064 235 -460 -508 -386 -44 -1325 -1061 -1907 -555 -551 -776 -517 218 -419 289 126 122 640 782 -86 399 -615 -802 -6 427 981 1471 218 -123 1534 666 314 -47 133 370 144 -119 -347 -313 381 -181 -347 -212 -358 46 -1820 -1142 -198 -1952 69 -2432 363 -571 -469 -1121 -2832 -2270 -1328 -599 -1204 -365 -1130 -431 -995 -938 -1716 -1085 -109 -1436 -1355 -1963 65 -279 -62 -2100 725 138 -561 617 -953 -11 -55 -142 384 580 434 386 615 -858 2426 590 527 47 -163 936 371 1896 714 862 478 391 1291 -603 492 624 927 408 1626 609 651 491 274 459 802 977 60 278 186 -14 -318 474 -630 -980 304 -1005 -765 -1238 -853 -951 -683 294 -441 323 127 121 384 -557 783 -172 -41 367 1189 277 -564 -598 -417 -46 -1351 -1152 -2082 -628 -665 -1014 -746 325 -679 475 203 187 982 1180 -126 620 -1025 -1363 -10 674 1493 2285 331 -180 2202 991 530 -88 251 731 300 -266 -783 -728 899 -434 -815 -470 -799 98 SS 20250702T050324.9Z 9314.210705 104 1 49.47 2 78.05 67.79 131.32 357.59 0.00 1 0.00 1 0 22 2.724e-01 7.623e-03 1.270e-01 2.603e-03 5.752981e-01 1.387614e-03 7.159390e-03 -6.000000e+00 1.590690e-01 233.79 -2.00 3.84 -2.00 320.58 0.00e+00 1.503013e-03 5.321118e-04 4.292522e-04 -6.000000e+00 6.840193e-03 282.14 -2.00 20.00 -2.00 319.97 0.00e+00 4.680 0.002 302.00 328.00 3 2.1836e+00 4.3044e-03 5.7994e-02 -6.0000e+00 4.0134e-01 1.1295e-02 5.4781e-03 3.4252e-02 -6.0000e+00 4.3317e-01 -6.7218e-02 5.1638e-03 1.7278e-02 -6.0000e+00 2.5653e-01 2.1076e-02 2.5748e-03 5.2437e-03 -6.0000e+00 1.0898e-01 3.1161e-04 -9.3871e-04 7.3461e-05 5.4433e-05 -6.0000e+00 7.2888e-03 2.2690e-02 0.0000e+00 11 8 0 10 0 0 30.35 20.04 0.26 0.02269 0.01564 88 19 1 5 0 562.100 20.04 15.01 16.61 28.47 39.6 1015.92 -125746 -103791 -83167 -104804 133151 -89335 52957 -42715 -40490 -49346 -88600 -55574 -44967 -6321 -25386 -4268 -28147 -34887 -20744 -19084 -28957 -11625 -5227 -27469 -26490 -29588 -877 -10698 10194 -24334 1221 -5429 -7511 -2868 -6887 -4541 -1653 -1912 -3042 -143 -3517 5056 3117 756 16153 3276 1221 -1317 416 708 3375 6860 3341 2389 1507 1416 1381 -667 -2212 1361 2238 1591 2810 1335 2859 1821 2029 986 1217 639 421 393 454 232 907 898 -726 -2791 -1255 -1980 -217 -1348 -1514 -1388 -709 -738 -695 405 834 504 335 220 957 324 196 714 1384 118 -654 -760 -496 -417 -573 -572 -1954 -838 -974 -578 97 -52 282 247 353 139 431 477 -113 334 -407 -466 129 368 410 550 507 70 1539 553 84 157 -199 -15 24 157 -112 -329 380 -183 -382 -170 -220 21 -1886 -1413 -959 -1403 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