File name: Pandora81s1_Cabauw_20240529_L2Fit_fwvt1c2d20240325p1-8.txt File generation date: 20240606T135919.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 81 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora81_OF_v3d20230613.txt Instrument calibration file used: Pandora81s1_CF_v2d20240325.txt Level 1 file used: Pandora81s1_Cabauw_20240529_L1_smca1c2d20240325p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20240529 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 lab analysis First and last pixel inside fitting window: 1623 1773 Nominal wavelengths inside fitting window [nm]: 492.0675 492.1880 492.3085 492.4289 492.5493 492.6697 492.7901 492.9105 493.0309 493.1512 493.2715 493.3918 493.5121 493.6324 493.7526 493.8729 493.9931 494.1133 494.2335 494.3537 494.4738 494.5940 494.7141 494.8342 494.9543 495.0744 495.1944 495.3145 495.4345 495.5545 495.6745 495.7944 495.9144 496.0343 496.1542 496.2742 496.3940 496.5139 496.6338 496.7536 496.8734 496.9932 497.1130 497.2328 497.3525 497.4723 497.5920 497.7117 497.8314 497.9510 498.0707 498.1903 498.3099 498.4295 498.5491 498.6687 498.7882 498.9078 499.0273 499.1468 499.2663 499.3857 499.5052 499.6246 499.7440 499.8634 499.9828 500.1022 500.2215 500.3408 500.4601 500.5794 500.6987 500.8180 500.9372 501.0565 501.1757 501.2949 501.4140 501.5332 501.6523 501.7715 501.8906 502.0097 502.1287 502.2478 502.3668 502.4858 502.6049 502.7238 502.8428 502.9618 503.0807 503.1996 503.3185 503.4374 503.5563 503.6751 503.7940 503.9128 504.0316 504.1504 504.2691 504.3879 504.5066 504.6253 504.7440 504.8627 504.9814 505.1000 505.2187 505.3373 505.4559 505.5744 505.6930 505.8116 505.9301 506.0486 506.1671 506.2856 506.4040 506.5225 506.6409 506.7593 506.8777 506.9960 507.1144 507.2327 507.3511 507.4694 507.5877 507.7059 507.8242 507.9424 508.0606 508.1788 508.2970 508.4152 508.5333 508.6515 508.7696 508.8877 509.0057 509.1238 509.2419 509.3599 509.4779 509.5959 509.7139 509.8318 509.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- ID 20240529T042518.6Z 8915.184243 115 1 8.01 2 83.51 62.73 72.33 176.38 0.00 1 0.00 1 0 22 5.851e-02 6.124e-02 3.554e-02 3.492e-02 8.763754e+03 2.497917e+03 1.467460e+02 -6.000000e+00 3.226131e+03 278.69 -2.00 20.00 -2.00 505.29 0.00e+00 -9.835235e-04 9.622505e-04 8.440452e-05 -6.000000e+00 1.625399e-03 278.69 -2.00 20.00 -2.00 500.00 0.00e+00 1.011492e-01 7.217590e-01 1.551488e-01 -6.000000e+00 1.170830e+00 232.25 -2.00 3.84 -2.00 501.69 0.00e+00 8.008 0.011 489.00 513.00 1 1.0708e+01 5.5279e-02 1.6663e-02 -6.0000e+00 8.9636e-02 7.0667e-02 1.3943e-02 2.6706e-03 -6.0000e+00 2.3220e-02 1.3845e-05 -5.7296e-03 3.3222e-03 9.6537e-06 -6.0000e+00 6.0691e-03 -2.3008e-02 9.0173e-05 12 8 8 10 0 0 999.00 25.86 1.14 -0.02301 -0.06275 2 1 1 4 0 4000.000 34.25 20.01 25.86 19.47 0.2 992.66 1865 6050 -7505 1608 535 -7046 2800 -4089 1209 -226 -2958 -362 -2584 -5713 -3510 -3208 1841 2379 1686 1395 4504 -4922 10394 11991 1478 -4036 -1310 6217 358 -8089 -7378 -2279 1828 2026 -616 -443 -3609 3706 -4576 1964 9221 5236 1720 973 1643 2794 1602 -5591 2097 -383 7277 4134 5729 3405 3272 -2502 -5633 12250 -3628 -923 -3986 1929 9197 3155 -2361 5711 -6132 -2426 -1562 5837 -11681 -952 8876 -8483 10233 -1217 5657 9230 675 -5522 1034 1190 -7821 10552 10231 1240 -1637 4217 -31664 3387 -1263 -793 5881 -4760 -2974 1194 -336 -122 -3727 11227 8783 -68 -9797 3005 -1384 7736 5856 1546 3771 5776 64 -716 10872 2927 5083 5642 42 -4744 907 5684 2696 7719 7133 -1690 -6145 -4102 -2215 1891 2179 -10613 8280 2079 2466 5611 -3052 3571 -5182 -8894 2783 4548 -6267 10198 1370 -619 -1846 -7495 -1270 1099 -2930 1685 -3943 1787 5589 -8138 1647 570 -8290 3044 -4822 1355 -256 -3386 -398 -2864 -6436 -3834 -3495 1929 2529 1850 1564 4932 -5933 10752 12214 1677 -4844 -1524 6644 397 -9496 -8389 -2447 1906 2165 -697 -510 -3978 4048 -4977 2130 9247 5471 1874 1078 1825 3081 1656 -6149 2101 -385 7087 4036 5398 3271 3195 -2471 -5893 11736 -3804 -940 -4180 1910 8496 3100 -2441 5388 -6415 -2407 -1516 5193 -12248 -894 7592 -8729 8828 -1180 5075 7851 616 -5304 927 1070 -7761 8794 8652 1160 -1588 3865 -41481 3121 -1223 -769 5390 -4874 -2966 1118 -310 -109 -3361 8534 6762 -58 -9362 2629 -1319 6920 5381 1474 3474 5181 61 -695 9486 2783 4746 5254 42 -4963 900 5348 2576 6886 6294 -1615 -6143 -4030 -2139 1752 2008 -11076 7123 1885 2194 4773 -2812 3090 -4965 -9022 2557 4168 -6479 9023 1333 -618 -1867 -8006 -1264 1050 -2857 1544 -3807 ID 20240529T042620.7Z 8915.184962 116 1 8.01 2 83.37 62.92 72.32 176.63 0.00 1 0.00 1 0 15 4.692e-02 4.953e-02 2.911e-02 2.880e-02 8.110741e+03 2.017586e+03 4.416578e+02 -6.000000e+00 2.587134e+03 278.69 -2.00 20.00 -2.00 505.34 0.00e+00 -4.548647e-04 7.919314e-04 5.500712e-05 -6.000000e+00 1.303183e-03 278.69 -2.00 20.00 -2.00 500.27 0.00e+00 4.997897e-01 5.867994e-01 8.390339e-02 -6.000000e+00 9.379065e-01 232.25 -2.00 3.84 -2.00 501.93 0.00e+00 7.867 0.011 489.00 513.00 1 1.0479e+01 4.4871e-02 1.3263e-02 -6.0000e+00 7.1818e-02 5.2261e-02 1.1268e-02 1.8257e-03 -6.0000e+00 1.8579e-02 1.7139e-05 7.5502e-04 2.7816e-03 4.3593e-05 -6.0000e+00 4.8657e-03 -2.5634e-02 1.8896e-04 12 8 8 10 0 0 999.00 25.86 2.26 -0.02563 -0.02040 2 1 1 4 0 4000.000 34.25 20.01 25.86 19.51 0.2 992.76 -5325 -1002 1240 4360 1794 -7747 4604 -817 -466 533 -3537 -311 1553 -704 -3354 24 4903 3948 -2510 -5414 -4649 -2173 3326 4909 1921 -1309 2610 2805 -484 -7599 937 2454 2720 1422 -3483 -2211 3048 1284 -3008 901 4740 10253 -229 3109 419 1346 -1686 -713 126 770 1123 4196 8620 -3784 2046 -5417 -6188 2118 -687 -5287 -378 4153 5272 4353 -1951 3107 -7344 -1606 794 4062 -841 316 -1757 -1412 9108 -5532 125 5787 -1910 1133 6651 7782 -1823 3036 6637 2784 857 4003 -28574 4722 3930 2748 -866 -2494 -4910 -861 2968 2798 1437 6901 6917 -993 -5269 2583 -5512 4380 3904 4156 1432 6738 3439 -619 5517 6750 459 -1890 -2379 -2712 1749 142 3154 -1088 6805 -3436 -7267 -786 -4540 4089 1247 -5175 15128 -4183 -3420 -635 -4475 2904 -4639 -2247 2105 402 -2331 8512 -1764 -1336 -1089 574 4212 -1173 -2469 2318 -2870 -5503 -1007 1257 4429 1920 -8652 4977 -941 -533 597 -4070 -341 1649 -755 -3677 26 5056 4208 -2712 -6100 -5219 -2383 3453 5026 2033 -1430 2726 2883 -501 -8211 914 2364 2665 1456 -3848 -2434 3164 1340 -3238 925 4672 9610 -241 3189 446 1419 -1822 -753 130 766 1082 3823 7419 -3707 1934 -5678 -6685 2130 -712 -5723 -390 4102 5164 4300 -2037 3043 -7861 -1599 761 3726 -804 299 -1710 -1386 8115 -5687 120 5144 -1809 1035 5752 6698 -1741 2791 5953 2621 826 3736 -36863 4369 3683 2631 -868 -2538 -5047 -829 2674 2453 1246 5564 5549 -874 -5003 2364 -5667 4149 3714 3904 1369 6098 3244 -615 5205 6327 460 -1947 -2479 -2854 1759 144 3045 -1077 6145 -3428 -7559 -768 -4612 3808 1191 -5257 12472 -4132 -3303 -590 -4312 2623 -4601 -2219 2024 398 -2401 7927 -1831 -1387 -1128 582 4067 -1173 -2454 2173 -2840 ID 20240529T042722.6Z 8915.185678 117 1 8.01 2 83.22 63.12 72.31 176.87 0.00 1 0.00 1 0 15 4.822e-02 4.908e-02 2.833e-02 2.805e-02 1.039058e+04 2.015805e+03 4.994495e+02 -6.000000e+00 2.658889e+03 278.69 -2.00 20.00 -2.00 505.34 0.00e+00 -9.689286e-04 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