File name: Pandora81s1_Cabauw_20240530_L2Fit_fwvt1c2d20240325p1-8.txt File generation date: 20240606T140000.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 81 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora81_OF_v3d20230613.txt Instrument calibration file used: Pandora81s1_CF_v2d20240325.txt Level 1 file used: Pandora81s1_Cabauw_20240530_L1_smca1c2d20240325p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20240530 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 lab analysis First and last pixel inside fitting window: 1623 1773 Nominal wavelengths inside fitting window [nm]: 492.0675 492.1880 492.3085 492.4289 492.5493 492.6697 492.7901 492.9105 493.0309 493.1512 493.2715 493.3918 493.5121 493.6324 493.7526 493.8729 493.9931 494.1133 494.2335 494.3537 494.4738 494.5940 494.7141 494.8342 494.9543 495.0744 495.1944 495.3145 495.4345 495.5545 495.6745 495.7944 495.9144 496.0343 496.1542 496.2742 496.3940 496.5139 496.6338 496.7536 496.8734 496.9932 497.1130 497.2328 497.3525 497.4723 497.5920 497.7117 497.8314 497.9510 498.0707 498.1903 498.3099 498.4295 498.5491 498.6687 498.7882 498.9078 499.0273 499.1468 499.2663 499.3857 499.5052 499.6246 499.7440 499.8634 499.9828 500.1022 500.2215 500.3408 500.4601 500.5794 500.6987 500.8180 500.9372 501.0565 501.1757 501.2949 501.4140 501.5332 501.6523 501.7715 501.8906 502.0097 502.1287 502.2478 502.3668 502.4858 502.6049 502.7238 502.8428 502.9618 503.0807 503.1996 503.3185 503.4374 503.5563 503.6751 503.7940 503.9128 504.0316 504.1504 504.2691 504.3879 504.5066 504.6253 504.7440 504.8627 504.9814 505.1000 505.2187 505.3373 505.4559 505.5744 505.6930 505.8116 505.9301 506.0486 506.1671 506.2856 506.4040 506.5225 506.6409 506.7593 506.8777 506.9960 507.1144 507.2327 507.3511 507.4694 507.5877 507.7059 507.8242 507.9424 508.0606 508.1788 508.2970 508.4152 508.5333 508.6515 508.7696 508.8877 509.0057 509.1238 509.2419 509.3599 509.4779 509.5959 509.7139 509.8318 509.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- ID 20240530T042516.9Z 8916.184223 101 1 8.01 2 83.41 62.61 68.19 163.06 0.00 1 0.00 1 0 15 4.525e-02 4.667e-02 2.439e-02 2.415e-02 9.225970e+03 1.719917e+03 4.834960e+02 -6.000000e+00 2.495905e+03 278.81 -2.00 20.00 -2.00 505.35 0.00e+00 -5.741699e-04 6.650911e-04 5.676327e-05 -6.000000e+00 1.256984e-03 278.81 -2.00 20.00 -2.00 500.28 0.00e+00 8.880225e-01 4.919788e-01 9.583034e-02 -6.000000e+00 9.043729e-01 232.33 -2.00 3.84 -2.00 501.93 0.00e+00 7.911 0.011 489.00 513.00 1 1.0249e+01 3.7662e-02 1.3826e-02 -6.0000e+00 6.9253e-02 4.8613e-02 9.4533e-03 2.0456e-03 -6.0000e+00 1.7914e-02 2.0839e-05 -3.9201e-03 2.3136e-03 3.7699e-05 -6.0000e+00 4.6920e-03 -9.5280e-03 9.6827e-05 12 8 8 10 0 0 999.00 25.78 0.82 -0.00953 -0.03672 2 1 1 4 0 4000.000 34.25 20.00 25.78 18.93 0.3 980.66 -3954 -2540 -4226 37 326 -6244 5575 -2100 1251 2275 -4339 2845 -3937 -5460 -3862 -3218 2481 7653 -4180 -1352 1410 -2310 4648 3021 959 -3699 5697 3431 -1856 -3541 439 -5195 1946 2870 462 -1278 4579 1862 -4430 -623 2269 6636 2883 1907 701 6212 -484 -1943 -2111 -626 -700 5415 -596 -26 3649 -2210 -4928 10187 -609 -972 3662 -742 4747 4752 -996 1920 -9169 -1224 -25 255 -1447 8111 2452 -2219 5453 -2794 1478 10738 -2043 -3784 1842 505 -3685 6339 7470 313 2082 6810 -25097 3873 -52 -4662 3801 490 1524 -4165 7656 -191 1348 12300 5595 -4167 -7147 851 -19 5937 5469 1287 2124 5715 -1156 1663 4731 3199 -1413 456 2632 -4661 483 -1720 1772 2383 4454 -1284 -3299 -6776 -372 3179 -596 -3956 7603 -3592 -5096 -37 -6474 1885 -1694 527 -843 -3714 1850 7112 4425 -4339 -1936 -972 -1501 4819 -96 -547 -5550 -4066 -2603 -4531 39 355 -6902 6008 -2293 1322 2538 -4738 3071 -4159 -5777 -3995 -3318 2638 7898 -4621 -1476 1506 -2565 4815 3186 1036 -4190 5845 3560 -1986 -3741 437 -5453 1930 2906 494 -1409 4745 1961 -4905 -657 2316 6505 2957 1995 749 6299 -523 -2105 -2252 -642 -698 4943 -569 -24 3399 -2245 -5273 9505 -635 -1015 3645 -773 4702 4707 -1039 1921 -10090 -1225 -25 245 -1399 7115 2292 -2198 5050 -2810 1406 9147 -1947 -3639 1672 467 -3581 5625 6629 302 1981 6181 -31264 3607 -51 -4783 3617 483 1468 -4146 6574 -172 1164 9334 4502 -3733 -6789 778 -18 5500 5112 1245 2014 5207 -1135 1605 4470 3088 -1433 456 2589 -4971 491 -1773 1737 2280 4110 -1248 -3279 -6998 -361 2976 -578 -3958 6747 -3527 -5004 -34 -6347 1711 -1620 503 -831 -3823 1823 6708 4315 -4643 -2026 -1003 -1543 4569 -93 -529 -5647 ID 20240530T042618.9Z 8916.184941 102 1 8.01 2 83.27 62.80 68.14 163.32 0.00 1 0.00 1 0 22 4.827e-02 4.918e-02 2.433e-02 2.410e-02 9.272250e+03 1.701288e+03 7.232967e+02 -6.000000e+00 2.662376e+03 278.81 -2.00 20.00 -2.00 505.30 0.00e+00 1.244909e-04 6.579349e-04 3.546936e-05 -6.000000e+00 1.341112e-03 278.81 -2.00 20.00 -2.00 500.24 0.00e+00 3.952173e-01 4.910729e-01 4.633688e-02 -6.000000e+00 9.657499e-01 232.33 -2.00 3.84 -2.00 501.87 0.00e+00 7.774 0.010 489.00 513.00 1 1.0295e+01 3.7589e-02 1.1997e-02 -6.0000e+00 7.3939e-02 6.4949e-02 9.4871e-03 1.4913e-03 -6.0000e+00 1.9152e-02 2.0844e-05 2.2163e-03 2.3032e-03 8.4808e-05 -6.0000e+00 5.0066e-03 2.0385e-03 -5.6052e-05 12 8 8 10 0 0 999.00 25.78 -0.19 0.00204 0.01741 2 1 1 4 0 4000.000 34.25 20.00 25.78 19.00 0.3 980.79 -3011 1604 -1927 3261 -160 -6178 1001 -2293 2401 -676 -3523 3066 -5479 -5481 -4991 133 3017 6012 -1180 -3012 93 -4067 -738 3391 2119 1602 1134 1153 -3130 -132 -294 147 1242 6041 -2102 -635 4100 2741 -582 2266 2462 3975 -922 5759 2964 1225 6137 2700 -952 -3187 -3529 1299 6827 1147 6498 -2246 -8763 3439 -1311 1206 501 -618 5781 3807 -4840 -1112 -6715 1966 1499 -1328 -2678 -359 4036 -6450 9828 -4905 -2908 8647 -5392 -9427 4888 136 -682 1691 12611 725 6057 8711 -24100 10287 1234 256 6232 -491 2795 -1714 3779 2893 1892 9984 5232 -6908 -12182 -3709 -4349 4341 6332 -2857 2724 7206 -1741 -1285 8600 -3171 300 -620 3983 -870 -1186 -3151 5849 4548 5756 559 -708 1337 734 843 378 -7530 4862 -760 -1579 -1369 1722 1303 540 2655 -3524 378 2632 9632 5510 -3818 -3180 -8120 -4351 -1623 1149 1867 -8343 -3117 1611 -2068 3435 -167 -6960 1067 -2545 2535 -728 -3844 3087 -5914 -5842 -5269 134 3002 5942 -1282 -3373 101 -4623 -811 3586 2277 1730 1222 1225 -3383 -135 -295 148 1254 6001 -2326 -699 4274 2862 -621 2327 2520 4029 -990 5847 3120 1314 6231 2801 -1005 -3354 -3619 1238 6079 1087 5973 -2318 -9872 3469 -1388 1243 520 -651 5724 3840 -5281 -1153 -7248 1917 1448 -1304 -2642 -347 3757 -6744 8801 -5071 -2904 7555 -5347 -9666 4344 127 -650 1588 10741 702 5578 7801 -29874 9039 1192 253 5834 -491 2663 -1665 3371 2528 1627 7779 4253 -6431 -12348 -3603 -4408 4107 5873 -2876 2568 6490 -1730 -1285 7861 -3278 301 -629 3889 -898 -1228 -3295 5494 4250 5242 535 -687 1277 705 809 364 -7810 4428 -723 -1491 -1277 1554 1191 507 2486 -3566 373 2566 8821 5288 -4038 -3119 -8321 -4239 -1618 1093 1744 -8077 ID 20240530T042720.9Z 8916.185659 103 1 8.01 2 83.13 63.00 68.09 163.58 0.00 1 0.00 1 0 22 4.091e-02 4.202e-02 2.389e-02 2.370e-02 7.596676e+03 1.635571e+03 2.252074e+02 -6.000000e+00 2.256657e+03 278.81 -2.00 20.00 -2.00 505.30 0.00e+00 2.096468e-04 6.501854e-04 9.131871e-05 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