File name: Pandora81s1_Cabauw_20240606_L2Fit_fwvt1c2d20240325p1-8.txt File generation date: 20240626T092506.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 81 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora81_OF_v3d20230613.txt Instrument calibration file used: Pandora81s1_CF_v2d20240325.txt Level 1 file used: Pandora81s1_Cabauw_20240606_L1_smca1c2d20240325p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20240606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 lab analysis First and last pixel inside fitting window: 1623 1773 Nominal wavelengths inside fitting window [nm]: 492.0675 492.1880 492.3085 492.4289 492.5493 492.6697 492.7901 492.9105 493.0309 493.1512 493.2715 493.3918 493.5121 493.6324 493.7526 493.8729 493.9931 494.1133 494.2335 494.3537 494.4738 494.5940 494.7141 494.8342 494.9543 495.0744 495.1944 495.3145 495.4345 495.5545 495.6745 495.7944 495.9144 496.0343 496.1542 496.2742 496.3940 496.5139 496.6338 496.7536 496.8734 496.9932 497.1130 497.2328 497.3525 497.4723 497.5920 497.7117 497.8314 497.9510 498.0707 498.1903 498.3099 498.4295 498.5491 498.6687 498.7882 498.9078 499.0273 499.1468 499.2663 499.3857 499.5052 499.6246 499.7440 499.8634 499.9828 500.1022 500.2215 500.3408 500.4601 500.5794 500.6987 500.8180 500.9372 501.0565 501.1757 501.2949 501.4140 501.5332 501.6523 501.7715 501.8906 502.0097 502.1287 502.2478 502.3668 502.4858 502.6049 502.7238 502.8428 502.9618 503.0807 503.1996 503.3185 503.4374 503.5563 503.6751 503.7940 503.9128 504.0316 504.1504 504.2691 504.3879 504.5066 504.6253 504.7440 504.8627 504.9814 505.1000 505.2187 505.3373 505.4559 505.5744 505.6930 505.8116 505.9301 506.0486 506.1671 506.2856 506.4040 506.5225 506.6409 506.7593 506.8777 506.9960 507.1144 507.2327 507.3511 507.4694 507.5877 507.7059 507.8242 507.9424 508.0606 508.1788 508.2970 508.4152 508.5333 508.6515 508.7696 508.8877 509.0057 509.1238 509.2419 509.3599 509.4779 509.5959 509.7139 509.8318 509.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- ID 20240606T042515.8Z 8923.184211 42 1 8.01 2 82.87 61.88 77.92 63.56 0.00 1 0.00 1 0 15 1.815e-02 1.805e-02 1.097e-02 1.091e-02 5.226999e+03 7.149881e+02 2.895551e+02 -6.000000e+00 1.004297e+03 279.64 -2.00 20.00 -2.00 505.29 0.00e+00 2.621210e-04 2.986780e-04 4.113128e-05 -6.000000e+00 5.052340e-04 279.64 -2.00 20.00 -2.00 500.24 0.00e+00 9.856388e-01 2.216001e-01 5.562658e-02 -6.000000e+00 3.631807e-01 232.88 -2.00 3.84 -2.00 501.88 0.00e+00 7.411 0.009 489.00 513.00 1 9.3858e+00 1.7001e-02 1.1612e-02 -6.0000e+00 2.7812e-02 3.3457e-02 4.3186e-03 1.2794e-03 -6.0000e+00 7.2039e-03 5.2568e-05 -1.8769e-03 1.0766e-03 2.5121e-05 -6.0000e+00 1.8825e-03 1.7574e-02 -1.5379e-04 12 8 8 10 0 0 999.00 25.45 1.52 0.01757 0.00455 2 1 1 4 0 4000.000 34.00 19.91 25.45 15.97 0.5 992.51 -800 -668 110 730 -1114 -2967 2715 -2338 1010 294 -1107 -27 -1090 -644 -713 -2018 2910 2120 -2345 -1970 164 -196 -273 -1785 1209 -537 2307 2635 -1882 -1248 212 -858 730 182 1126 558 -1253 950 -943 1210 3400 3411 601 938 -1238 328 922 -658 646 774 323 -1285 3137 464 1266 929 -1316 1856 -150 -714 -2476 -1405 2964 2093 -378 -1191 -2825 356 -2926 -12 -1987 -52 -564 -1548 3112 -266 1266 3491 949 509 314 -1454 -2241 -1870 3904 -1099 683 958 -7285 1182 35 353 1496 -464 -1527 119 1077 -919 84 1900 3537 -505 -2931 -184 -2285 1597 843 -1904 -755 5066 -1255 -427 2296 1648 99 1006 -162 -427 739 384 2703 1087 130 -470 -1657 -109 1224 1432 -520 -4407 476 873 -421 -895 1100 1460 -3237 -647 -465 -57 1906 5008 658 -2051 -1096 -3760 2042 -1542 -466 -330 -1030 -755 -637 107 732 -1169 -3244 2855 -2612 1091 317 -1193 -29 -1140 -661 -729 -2096 2917 2190 -2594 -2206 180 -217 -303 -2014 1328 -601 2499 2812 -2055 -1315 216 -881 750 194 1222 578 -1318 1032 -1031 1282 3515 3541 647 1018 -1299 340 947 -678 690 806 328 -1292 2971 452 1248 946 -1316 1945 -151 -722 -2542 -1431 2901 2066 -380 -1193 -2832 363 -2854 -12 -2002 -51 -563 -1481 3061 -254 1252 3318 912 488 301 -1429 -2097 -1759 3736 -1047 643 899 -7417 1106 33 338 1432 -455 -1503 114 991 -840 79 1719 3118 -467 -2671 -169 -2221 1520 809 -1858 -720 4545 -1209 -413 2190 1598 98 993 -162 -432 739 382 2588 1040 124 -450 -1611 -105 1162 1356 -501 -4408 451 816 -392 -829 992 1319 -3116 -619 -452 -56 1857 4764 658 -2117 -1123 -3946 2001 -1538 -450 -315 -987 ID 20240606T042617.7Z 8923.184927 43 1 8.01 2 82.73 62.07 77.79 63.73 0.00 1 0.00 1 0 15 2.006e-02 1.986e-02 1.178e-02 1.170e-02 4.753845e+03 7.547740e+02 1.721116e+02 -6.000000e+00 1.110391e+03 279.64 -2.00 20.00 -2.00 505.22 0.00e+00 5.053123e-04 3.183857e-04 4.803414e-05 -6.000000e+00 5.584893e-04 279.64 -2.00 20.00 -2.00 500.25 0.00e+00 8.284024e-01 2.365307e-01 6.902838e-02 -6.000000e+00 4.011341e-01 232.88 -2.00 3.84 -2.00 501.85 0.00e+00 7.291 0.008 489.00 513.00 1 9.4987e+00 1.8115e-02 1.1849e-02 -6.0000e+00 3.0724e-02 4.2185e-02 4.6447e-03 1.3704e-03 -6.0000e+00 7.9479e-03 4.8207e-05 2.9562e-04 1.1634e-03 1.3248e-05 -6.0000e+00 2.0807e-03 9.7856e-03 -2.9244e-05 12 8 8 10 0 0 999.00 25.45 1.34 0.00979 0.01184 2 1 1 4 0 4000.000 34.00 20.02 25.45 16.12 0.5 992.67 -1483 924 -888 381 90 -2357 162 -1751 -2018 -1921 -575 -997 -351 -1075 -928 76 330 4157 -2109 -1273 507 -647 237 2338 -1512 1064 62 1477 -679 -1937 289 -1789 2254 1566 416 -1128 96 2868 -1160 530 2124 2759 -1198 -899 1850 1557 -1652 -1315 2853 1385 -386 462 1780 1289 1271 -899 -106 4801 2347 -1499 -2250 -1620 1940 2504 1090 434 -494 -1388 -1203 1491 -2628 -787 -1117 -746 2701 1673 1262 3720 893 -2016 -309 -845 -2805 -1300 1155 -1897 1014 81 -8876 812 702 -229 1646 1820 -5094 -1320 1074 -123 402 4143 3711 -480 -2816 1427 -1585 3537 -725 -1059 127 6232 -88 1359 1686 1463 797 -1113 328 793 -1141 1195 2237 1053 -834 -942 -627 -1833 1911 1928 -2422 -2725 1790 1457 -556 407 -2138 2855 -5163 -2434 -244 703 -1018 2975 1117 -833 -1068 -4354 785 -157 256 -1663 1040 -1397 864 -872 382 93 -2547 173 -1927 -2220 -2087 -608 -1043 -359 -1094 -939 77 337 4176 -2308 -1399 549 -709 258 2497 -1684 1156 67 1566 -717 -2013 289 -1830 2258 1629 450 -1250 105 3000 -1247 556 2190 2843 -1297 -981 1980 1675 -1825 -1429 2921 1403 -387 447 1681 1230 1241 -923 -110 4820 2419 -1602 -2422 -1739 2016 2585 1133 448 -507 -1414 -1208 1439 -2620 -771 -1107 -745 2627 1639 1224 3459 843 -1948 -294 -814 -2775 -1278 1120 -1913 997 81 -9022 801 697 -232 1654 1831 -5101 -1332 1033 -116 370 3602 3218 -439 -2711 1366 -1612 3461 -692 -1002 125 5785 -88 1272 1592 1397 771 -1103 322 778 -1138 1152 2100 985 -787 -889 -592 -1757 1766 1780 -2329 -2623 1638 1323 -507 363 -1949 2495 -4974 -2327 -232 672 -999 2821 1085 -829 -1066 -4473 756 -149 239 -1559 951 ID 20240606T042719.7Z 8923.185645 44 1 8.01 2 82.59 62.27 77.65 63.91 0.00 1 0.00 1 0 15 2.090e-02 2.076e-02 1.184e-02 1.176e-02 5.447620e+03 7.671497e+02 3.022304e+02 -6.000000e+00 1.156454e+03 279.64 -2.00 20.00 -2.00 505.21 0.00e+00 9.869772e-04 3.192380e-04 6.547814e-05 -6.000000e+00 5.816888e-04 279.64 -2.00 20.00 -2.00 500.23 0.00e+00 6.242159e-01 2.379618e-01 5.585662e-02 -6.000000e+00 4.179090e-01 232.88 -2.00 3.84 -2.00 501.83 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