File name: Pandora81s1_Cabauw_20240610_L2Fit_fwvt1c2d20240325p1-8.txt File generation date: 20240626T094019.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 81 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora81_OF_v3d20230613.txt Instrument calibration file used: Pandora81s1_CF_v2d20240325.txt Level 1 file used: Pandora81s1_Cabauw_20240610_L1_smca1c2d20240325p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20240610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 lab analysis First and last pixel inside fitting window: 1623 1773 Nominal wavelengths inside fitting window [nm]: 492.0675 492.1880 492.3085 492.4289 492.5493 492.6697 492.7901 492.9105 493.0309 493.1512 493.2715 493.3918 493.5121 493.6324 493.7526 493.8729 493.9931 494.1133 494.2335 494.3537 494.4738 494.5940 494.7141 494.8342 494.9543 495.0744 495.1944 495.3145 495.4345 495.5545 495.6745 495.7944 495.9144 496.0343 496.1542 496.2742 496.3940 496.5139 496.6338 496.7536 496.8734 496.9932 497.1130 497.2328 497.3525 497.4723 497.5920 497.7117 497.8314 497.9510 498.0707 498.1903 498.3099 498.4295 498.5491 498.6687 498.7882 498.9078 499.0273 499.1468 499.2663 499.3857 499.5052 499.6246 499.7440 499.8634 499.9828 500.1022 500.2215 500.3408 500.4601 500.5794 500.6987 500.8180 500.9372 501.0565 501.1757 501.2949 501.4140 501.5332 501.6523 501.7715 501.8906 502.0097 502.1287 502.2478 502.3668 502.4858 502.6049 502.7238 502.8428 502.9618 503.0807 503.1996 503.3185 503.4374 503.5563 503.6751 503.7940 503.9128 504.0316 504.1504 504.2691 504.3879 504.5066 504.6253 504.7440 504.8627 504.9814 505.1000 505.2187 505.3373 505.4559 505.5744 505.6930 505.8116 505.9301 506.0486 506.1671 506.2856 506.4040 506.5225 506.6409 506.7593 506.8777 506.9960 507.1144 507.2327 507.3511 507.4694 507.5877 507.7059 507.8242 507.9424 508.0606 508.1788 508.2970 508.4152 508.5333 508.6515 508.7696 508.8877 509.0057 509.1238 509.2419 509.3599 509.4779 509.5959 509.7139 509.8318 509.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- ID 20240610T042516.5Z 8927.184219 42 1 8.01 2 82.70 61.53 102.90 20.50 0.00 1 0.00 1 0 15 5.039e-02 4.816e-02 2.797e-02 2.767e-02 6.489419e+03 1.892085e+03 3.243999e+02 -6.000000e+00 2.794050e+03 280.11 -2.00 20.00 -2.00 505.35 0.00e+00 -7.134709e-04 7.639409e-04 9.901233e-05 -6.000000e+00 1.404597e-03 280.11 -2.00 20.00 -2.00 500.31 0.00e+00 1.583491e+00 5.615632e-01 7.924011e-02 -6.000000e+00 1.008769e+00 233.20 -2.00 3.84 -2.00 501.96 0.00e+00 7.259 0.008 489.00 513.00 1 1.0445e+01 4.3035e-02 1.2398e-02 -6.0000e+00 7.7260e-02 2.3171e-02 1.0786e-02 1.6326e-03 -6.0000e+00 2.0014e-02 1.7967e-05 -1.7675e-03 2.7176e-03 4.3044e-05 -6.0000e+00 5.2279e-03 8.1564e-03 -1.1016e-04 12 8 8 10 0 0 999.00 25.68 1.76 0.00816 -0.00410 2 1 1 4 0 4000.000 34.25 19.99 25.68 17.00 0.4 988.99 -8728 -1525 -2519 -1070 -3406 -5731 2590 -3143 -1294 187 2242 -53 -2681 -3056 -5356 -7735 10817 7645 -505 -1074 -2613 -121 6419 -1496 1340 -14 1316 4092 -2584 828 -1237 -3265 4937 2606 3660 -4826 4504 1917 -4054 -205 931 6063 2046 7443 -1065 1221 78 -1984 -2471 541 542 -1597 7224 2328 15318 5376 -3306 7996 465 1391 -2717 -11261 3887 5645 195 3411 445 -718 -2088 -407 -4388 5314 -3468 -1948 9400 -4875 -3630 5464 4410 -3739 4388 5165 -9313 -341 13176 -1229 -83 -1207 -3492 5406 -3458 -4318 3969 3712 -4068 1142 -449 -2830 5450 13853 1612 -860 -8007 5983 -6420 1833 3638 -3224 -3026 16966 -387 -3101 3516 3709 4826 -4719 -1525 -2378 -5728 1075 9068 7188 2742 3582 -1172 -2553 -832 -1408 1580 -10788 3446 3499 1830 -599 -441 10654 -12254 483 6829 -3131 -2326 8091 1259 -3542 -4702 -7920 3182 1446 -3210 92 -3481 -9282 -1526 -2622 -1136 -3807 -6225 2841 -3426 -1385 211 2441 -59 -2980 -3365 -5569 -8268 10489 7828 -534 -1160 -2884 -131 6488 -1639 1432 -15 1402 4192 -2767 832 -1244 -3345 4733 2635 3770 -5485 4649 2008 -4451 -215 960 5952 2108 7336 -1153 1296 83 -2140 -2632 546 531 -1556 6337 2146 12636 5038 -3463 7587 478 1412 -2867 -12974 3861 5510 200 3342 442 -711 -2066 -391 -4342 4765 -3418 -1912 8318 -4975 -3613 4878 3920 -3577 3866 4541 -9540 -322 10997 -1197 -80 -1182 -3496 4951 -3475 -4415 3773 3551 -4167 1088 -423 -2658 4591 10516 1370 -756 -7768 5249 -6613 1774 3466 -3259 -3017 13799 -376 -3140 3370 3576 4626 -4999 -1574 -2492 -6212 1081 8289 6583 2591 3343 -1151 -2551 -819 -1393 1515 -11678 3223 3239 1697 -563 -412 8954 -13170 466 6308 -3244 -2419 7646 1283 -3807 -5126 -8302 3167 1439 -3283 89 -3518 ID 20240610T042618.6Z 8927.184938 43 1 8.01 2 82.56 61.72 102.85 20.73 0.00 1 0.00 1 0 22 5.673e-02 5.481e-02 3.111e-02 3.069e-02 7.800963e+03 2.158946e+03 2.149665e+02 -6.000000e+00 3.145653e+03 280.11 -2.00 20.00 -2.00 505.36 0.00e+00 -2.519292e-03 8.449839e-04 1.555309e-04 -6.000000e+00 1.581123e-03 280.11 -2.00 20.00 -2.00 500.25 0.00e+00 2.201614e+00 6.222253e-01 1.278922e-01 -6.000000e+00 1.134852e+00 233.20 -2.00 3.84 -2.00 501.92 0.00e+00 7.143 0.008 489.00 513.00 1 1.0552e+01 4.7622e-02 1.4701e-02 -6.0000e+00 8.6930e-02 7.5815e-03 1.1872e-02 2.2848e-03 -6.0000e+00 2.2497e-02 1.6045e-05 2.9674e-03 2.9311e-03 5.3992e-05 -6.0000e+00 5.8845e-03 -4.4483e-03 2.3749e-05 12 8 8 10 0 0 999.00 25.68 1.68 -0.00445 0.01613 2 1 1 4 0 4000.000 34.25 19.99 25.68 17.14 0.4 989.18 -8793 1139 -1157 3272 4321 -4036 1366 -7090 -5537 -2016 -1831 4296 -6975 687 -634 -1957 3064 6945 -1108 -2145 -1288 -3434 -3969 -1280 -274 158 463 9245 -4714 12 -1602 -5051 4650 3346 8006 -2753 4700 3667 -4058 3503 8893 13822 1003 431 2047 3465 2715 -2966 944 380 395 -8769 3046 1114 14093 5289 -4017 5645 -582 3780 -3288 -7404 -2821 8165 -3684 -66 -409 3448 -1489 1790 -8872 524 -2608 -2308 6640 3355 -2281 8919 8114 -3303 7922 -804 -6180 -2013 8379 -4794 3169 25 -7193 6463 -1020 -8570 333 5403 -7403 -441 1523 -3950 5483 7094 11065 3478 -11421 7375 -6660 7278 3007 -953 -9151 18065 -5228 -1884 8118 4444 -2425 341 625 -430 3589 3895 7268 8428 3517 2213 -1676 -2695 -405 -677 655 -12375 8329 1466 3146 -5238 -247 14544 -15367 -495 -202 -3091 6256 8287 -2299 -6275 -4165 -11422 4832 7521 2842 -1521 -3032 -9356 1118 -1199 3353 4497 -4668 1523 -8056 -6185 -2318 -2076 4521 -7521 731 -682 -2150 3260 7293 -1200 -2377 -1422 -3880 -4509 -1418 -301 173 501 9035 -5164 12 -1631 -5349 4564 3435 8047 -3105 4886 3804 -4489 3559 8538 12677 1054 460 2159 3602 2822 -3217 965 380 383 -9097 2774 1041 11835 4987 -4245 5468 -600 3718 -3467 -8158 -2975 7698 -3878 -66 -404 3229 -1446 1661 -9090 490 -2538 -2265 6004 3120 -2210 7586 6866 -3114 6687 -746 -6106 -1929 7325 -4829 2961 24 -7447 5844 -999 -9130 327 5025 -7696 -417 1370 -3648 4499 5638 8437 2913 -11505 6431 -6923 6690 2881 -940 -9690 14550 -5356 -1886 7410 4229 -2480 341 627 -439 3515 3765 6681 7531 3263 2077 -1642 -2675 -393 -659 627 -13476 7335 1367 2845 -5108 -229 11777 -17130 -486 -202 -3220 6006 7867 -2444 -6982 -4544 -12456 4743 7060 2747 -1523 -3094 ID 20240610T042720.4Z 8927.185653 44 1 8.01 2 82.42 61.92 102.79 20.96 0.00 1 0.00 1 0 15 5.633e-02 5.507e-02 3.359e-02 3.303e-02 1.165864e+04 2.447588e+03 7.043670e+02 -6.000000e+00 3.123237e+03 280.11 -2.00 20.00 -2.00 505.34 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