File name: Pandora81s1_Cabauw_20240614_L2Fit_fwvt1c2d20240325p1-8.txt File generation date: 20240626T094526.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 81 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora81_OF_v3d20230613.txt Instrument calibration file used: Pandora81s1_CF_v2d20240325.txt Level 1 file used: Pandora81s1_Cabauw_20240614_L1_smca1c2d20240325p1-8.txt Full location name: Cabauw Short location name: Cabauw Country of location: Netherlands Location latitude [deg]: 51.9704 Location longitude [deg]: 4.9262 Location altitude [m]: 0 Local noon date: 20240614 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 lab analysis First and last pixel inside fitting window: 1623 1773 Nominal wavelengths inside fitting window [nm]: 492.0675 492.1880 492.3085 492.4289 492.5493 492.6697 492.7901 492.9105 493.0309 493.1512 493.2715 493.3918 493.5121 493.6324 493.7526 493.8729 493.9931 494.1133 494.2335 494.3537 494.4738 494.5940 494.7141 494.8342 494.9543 495.0744 495.1944 495.3145 495.4345 495.5545 495.6745 495.7944 495.9144 496.0343 496.1542 496.2742 496.3940 496.5139 496.6338 496.7536 496.8734 496.9932 497.1130 497.2328 497.3525 497.4723 497.5920 497.7117 497.8314 497.9510 498.0707 498.1903 498.3099 498.4295 498.5491 498.6687 498.7882 498.9078 499.0273 499.1468 499.2663 499.3857 499.5052 499.6246 499.7440 499.8634 499.9828 500.1022 500.2215 500.3408 500.4601 500.5794 500.6987 500.8180 500.9372 501.0565 501.1757 501.2949 501.4140 501.5332 501.6523 501.7715 501.8906 502.0097 502.1287 502.2478 502.3668 502.4858 502.6049 502.7238 502.8428 502.9618 503.0807 503.1996 503.3185 503.4374 503.5563 503.6751 503.7940 503.9128 504.0316 504.1504 504.2691 504.3879 504.5066 504.6253 504.7440 504.8627 504.9814 505.1000 505.2187 505.3373 505.4559 505.5744 505.6930 505.8116 505.9301 506.0486 506.1671 506.2856 506.4040 506.5225 506.6409 506.7593 506.8777 506.9960 507.1144 507.2327 507.3511 507.4694 507.5877 507.7059 507.8242 507.9424 508.0606 508.1788 508.2970 508.4152 508.5333 508.6515 508.7696 508.8877 509.0057 509.1238 509.2419 509.3599 509.4779 509.5959 509.7139 509.8318 509.9498 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- ID 20240614T042516.1Z 8931.184214 54 1 8.01 2 82.62 61.23 121.97 336.19 0.00 1 0.00 1 0 15 3.687e-02 3.733e-02 2.123e-02 2.106e-02 9.735456e+03 1.469535e+03 4.775330e+02 -6.000000e+00 2.048337e+03 280.59 -2.00 20.00 -2.00 505.24 0.00e+00 -3.529616e-04 5.719870e-04 6.765099e-05 -6.000000e+00 1.028684e-03 280.59 -2.00 20.00 -2.00 500.24 0.00e+00 -3.317921e-01 4.274256e-01 1.030058e-01 -6.000000e+00 7.371859e-01 233.51 -2.00 3.84 -2.00 501.85 0.00e+00 7.192 0.008 489.00 513.00 1 1.0288e+01 3.2630e-02 1.3294e-02 -6.0000e+00 5.6483e-02 7.0391e-02 8.4193e-03 2.1029e-03 -6.0000e+00 1.4605e-02 2.4259e-05 -3.5512e-03 2.0235e-03 4.1705e-05 -6.0000e+00 3.8239e-03 9.1694e-04 4.1123e-05 12 8 8 10 0 0 999.00 25.78 1.59 0.00092 -0.02372 2 1 1 4 0 4000.000 34.25 20.00 25.78 19.18 0.3 991.95 1748 3502 -2163 1947 2774 -7339 -1853 -3809 -807 3587 47 -405 -2686 2117 -3769 277 3978 2059 -480 -2348 426 -273 -2146 -147 413 -3770 1149 2593 -418 -1722 -1075 -2063 1536 -515 3794 -440 1773 3305 -5334 593 4003 7933 621 4316 23 3514 2963 -2047 4223 3002 397 -337 1635 -546 4384 676 -2749 3808 393 -2984 -4467 -7236 5085 65 -1641 -885 -1021 2776 -1976 347 -9862 -77 -2337 -1616 2812 2163 -755 6359 106 1503 3320 3709 -1883 919 5866 1026 -1866 -996 -18043 3647 -528 -1879 -1223 4260 260 -570 2473 -9315 1872 6738 2399 -1296 -4613 4908 -4770 4528 1443 323 -5549 7029 97 2511 1168 4550 -1348 -4259 2798 -2032 -119 2550 4358 1392 2244 4770 589 -2704 2668 1835 -743 -3900 4086 1346 1504 2070 -445 5057 -9016 -1194 3386 -3843 7482 5022 -620 -3740 -1715 -6175 -1129 -744 2587 -2120 -3987 1728 3441 -2149 1920 2788 -8340 -2029 -4295 -883 3717 50 -424 -2835 2100 -3939 279 3911 2109 -517 -2613 464 -299 -2398 -161 451 -4301 1242 2728 -443 -1794 -1090 -2110 1540 -543 3942 -483 1897 3444 -5983 620 4035 7717 655 4434 24 3682 3109 -2233 4251 2987 394 -328 1535 -524 4090 673 -2905 3823 409 -3210 -4872 -8137 5073 68 -1741 -921 -1047 2701 -1989 338 -10509 -75 -2325 -1615 2714 2101 -745 5745 100 1394 3020 3378 -1829 877 5386 1000 -1881 -995 -19905 3467 -525 -1910 -1247 4119 258 -557 2274 -9349 1636 5502 2030 -1149 -4358 4398 -4900 4338 1432 322 -5790 6443 96 2450 1165 4413 -1390 -4236 2796 -2004 -124 2559 4226 1364 2147 4422 570 -2714 2540 1761 -729 -3937 3788 1267 1392 1882 -413 4472 -8707 -1087 2995 -3706 6981 4518 -593 -3710 -1668 -6252 -1075 -693 2285 -1936 -3708 ID 20240614T042618.6Z 8931.184938 55 1 8.01 2 82.48 61.43 122.04 336.47 0.00 1 0.00 1 0 15 3.956e-02 4.051e-02 2.168e-02 2.148e-02 1.095797e+04 1.550247e+03 6.430453e+02 -6.000000e+00 2.197465e+03 280.59 -2.00 20.00 -2.00 505.29 0.00e+00 -9.731037e-04 5.876248e-04 7.286581e-05 -6.000000e+00 1.103516e-03 280.59 -2.00 20.00 -2.00 500.24 0.00e+00 3.901930e-01 4.367673e-01 9.203457e-02 -6.000000e+00 7.905760e-01 233.51 -2.00 3.84 -2.00 501.87 0.00e+00 7.077 0.008 489.00 513.00 1 1.0278e+01 3.3345e-02 1.2778e-02 -6.0000e+00 6.0577e-02 4.9171e-02 8.5142e-03 2.0713e-03 -6.0000e+00 1.5657e-02 2.3748e-05 4.7874e-04 2.0337e-03 5.8659e-05 -6.0000e+00 4.1014e-03 2.1753e-05 7.1924e-05 12 8 8 10 0 0 999.00 25.78 0.96 0.00002 0.00334 2 1 1 4 0 4000.000 34.25 20.00 25.78 19.27 0.3 992.02 -1760 1497 -1016 1064 1712 -8023 1995 -3871 -2100 -875 1016 1953 -4069 248 -5231 1248 3942 1310 3314 332 3949 -819 -2961 -3024 615 -2594 -147 3489 928 -1534 152 4642 3583 147 -739 62 1213 -829 -1954 681 1804 3728 1682 3367 -3667 2906 1276 -3527 1453 473 -546 -2434 -237 -554 5742 2303 -4935 6340 2979 1408 -2370 -9757 5697 3613 -2533 2524 -3206 2647 -1266 1992 -2196 1536 -374 -2231 6805 1332 -339 1150 3530 409 4080 3410 -3193 2567 3157 393 4201 1733 -21129 2193 3749 -1814 -2261 40 -1977 3617 1871 -1199 -474 3180 5665 5747 -6063 3628 -6084 5398 -4588 3144 -916 8337 5043 -461 1899 4405 -4313 -4348 3625 1286 794 -6013 6629 1259 1563 3595 -3551 -2672 -908 -60 -358 -8672 5041 997 165 3859 -3650 3852 -11513 1418 2601 -4889 3636 4940 741 -1618 382 -5561 6620 -1780 2840 -447 -5097 -1793 1501 -1000 1060 1740 -9180 2099 -4354 -2314 -942 1059 1988 -4331 250 -5545 1247 3900 1363 3459 362 4162 -906 -3348 -3428 674 -2933 -161 3635 967 -1591 153 4473 3561 156 -812 68 1310 -903 -2124 714 1869 3806 1768 3513 -4135 3072 1362 -3898 1499 480 -544 -2408 -226 -535 5327 2275 -5357 6216 3023 1448 -2530 -11253 5645 3650 -2700 2524 -3340 2563 -1258 1893 -2159 1458 -364 -2245 6303 1297 -331 1086 3211 382 3669 3107 -3135 2404 2976 384 3973 1678 -23928 2107 3562 -1838 -2319 40 -1977 3323 1694 -1085 -416 2644 4583 4726 -5817 3305 -6349 5121 -4815 3026 -909 7534 4747 -463 1876 4259 -4559 -4616 3581 1311 814 -6100 6239 1227 1497 3362 -3577 -2676 -894 -59 -350 -8555 4616 939 154 3446 -3512 3475 -11520 1363 2343 -4816 3327 4500 709 -1589 368 -5650 6301 -1688 2527 -407 -4878 ID 20240614T042720.5Z 8931.185654 56 1 8.01 2 82.34 61.62 122.10 336.76 0.00 1 0.00 1 0 15 4.188e-02 4.216e-02 2.259e-02 2.238e-02 1.107373e+04 1.610661e+03 6.894877e+02 -6.000000e+00 2.326440e+03 280.59 -2.00 20.00 -2.00 505.29 0.00e+00 -1.077688e-03 6.091133e-04 6.834734e-05 -6.000000e+00 1.168280e-03 280.59 -2.00 20.00 -2.00 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