File name: Pandora141s1_Calakmul_20250209_L2Fit_fout2c3d20231011p1-8.txt File generation date: 20250210T061836.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 141 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora141_OF_v2d20230802.txt Instrument calibration file used: Pandora141s1_CF_v3d20231011.txt Level 1 file used: Pandora141s1_Calakmul_20250209_L1_smca1c3d20231011p1-8.txt Full location name: Calakmul Atmospheric Observatory Short location name: Calakmul Country of location: Mexico Location latitude [deg]: 18.5956 Location longitude [deg]: -89.4137 Location altitude [m]: 275 Local noon date: 20250209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 2 First and last pixel inside fitting window: 238 379 Nominal wavelengths inside fitting window [nm]: 305.1074 305.2483 305.3892 305.5302 305.6711 305.8120 305.9528 306.0937 306.2346 306.3754 306.5163 306.6571 306.7979 306.9387 307.0795 307.2203 307.3611 307.5018 307.6426 307.7833 307.9240 308.0647 308.2054 308.3461 308.4868 308.6275 308.7681 308.9088 309.0494 309.1900 309.3306 309.4712 309.6118 309.7524 309.8930 310.0335 310.1741 310.3146 310.4551 310.5956 310.7361 310.8766 311.0171 311.1575 311.2980 311.4384 311.5788 311.7192 311.8596 312.0000 312.1404 312.2808 312.4211 312.5615 312.7018 312.8421 312.9824 313.1227 313.2630 313.4033 313.5435 313.6838 313.8240 313.9643 314.1045 314.2447 314.3849 314.5251 314.6652 314.8054 314.9455 315.0857 315.2258 315.3659 315.5060 315.6461 315.7862 315.9262 316.0663 316.2063 316.3463 316.4864 316.6264 316.7664 316.9063 317.0463 317.1863 317.3262 317.4662 317.6061 317.7460 317.8859 318.0258 318.1657 318.3055 318.4454 318.5852 318.7250 318.8649 319.0047 319.1445 319.2842 319.4240 319.5638 319.7035 319.8433 319.9830 320.1227 320.2624 320.4021 320.5418 320.6814 320.8211 320.9607 321.1003 321.2400 321.3796 321.5192 321.6588 321.7983 321.9379 322.0774 322.2170 322.3565 322.4960 322.6355 322.7750 322.9145 323.0539 323.1934 323.3328 323.4723 323.6117 323.7511 323.8905 324.0299 324.1692 324.3086 324.4479 324.5873 324.7266 324.8659 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250209T135723.1Z 9171.581517 237 1 60.81 2 70.85 113.33 127.70 329.62 0.00 1 0.00 1 0 25 6.039e-02 9.806e-03 5.031e-02 6.269e-03 3.470137e-01 3.361709e-03 3.869430e-03 -6.000000e+00 3.660911e-02 224.98 -2.00 3.11 -2.00 318.86 0.00e+00 1.116658e-03 7.775080e-04 9.446502e-04 -6.000000e+00 1.665872e-03 290.57 -2.00 20.00 -2.00 318.04 0.00e+00 3.012 0.000 302.00 328.00 3 6.1386e+00 9.1964e-03 3.3224e-02 -6.0000e+00 9.0051e-02 1.0385e-01 1.0607e-02 1.6784e-02 -6.0000e+00 9.7037e-02 9.0587e-03 7.2666e-03 8.0765e-03 -6.0000e+00 5.8240e-02 -1.2274e-02 3.8291e-03 2.2662e-03 -6.0000e+00 2.5402e-02 3.8836e-05 -1.8809e-03 2.0373e-04 2.9832e-05 -6.0000e+00 1.8632e-03 -6.5005e-02 -1.2340e-04 12 9 8 11 8 0 99.97 19.93 0.32 -0.06500 -0.07914 19 19 1 5 0 3199.860 26.11 19.97 19.93 30.49 38.1 987.53 3077 -33846 -6224 -6611 19688 11989 -4896 -18009 718 -5900 38471 -9058 -14624 8527 -2496 9079 -3390 -6181 1500 -4013 825 -11799 -5591 -8332 977 4582 -2673 10629 -2155 10128 -2288 3573 356 -2864 -3881 -1620 -3878 -3641 2944 -93 -874 -2334 934 344 -1859 2147 -3084 664 1739 2941 -472 2109 -3147 3774 3841 830 1700 321 239 -1955 1503 453 319 3320 2260 998 490 595 -1164 2002 768 2035 748 -984 -758 -604 567 -4659 -2636 -2566 -1896 -382 -2067 -1262 -624 693 -547 1356 68 1617 216 -893 -1215 -201 211 -740 -156 -320 1073 112 -1373 -1510 -1322 -441 -663 -279 -1133 -370 693 823 961 838 1243 427 -319 -969 -330 75 56 812 19 675 -21 693 56 -16 -193 -330 394 161 -485 -135 -27 -186 -694 -358 743 428 190 486 -360 -1004 107 -1857 -277 -288 625 392 -195 -899 33 -311 1380 -533 -1020 559 -210 772 -351 -696 165 -485 98 -1596 -728 -1173 134 632 -398 1352 -299 1248 -337 549 62 -532 -717 -290 -755 -816 734 -28 -289 -835 337 127 -705 788 -1185 245 635 1083 -189 885 -1483 1759 1861 426 881 169 124 -1034 790 256 196 2108 1477 637 299 358 -751 1383 582 1595 597 -773 -559 -409 350 -2917 -1685 -1814 -1489 -325 -1919 -1226 -638 741 -619 1556 79 1808 231 -902 -1152 -186 202 -782 -181 -405 1421 151 -1785 -1837 -1534 -512 -809 -358 -1530 -519 1012 1276 1559 1390 2026 670 -475 -1387 -466 108 85 1279 31 1078 -32 1049 83 -22 -265 -455 568 248 -792 -227 -47 -333 -1300 -696 1470 863 385 967 -702 -1902 SS 20250209T140753.4Z 9171.588812 243 1 59.78 2 68.57 114.53 128.86 332.02 0.00 1 0.00 1 0 25 2.925e-02 9.135e-03 3.510e-02 5.922e-03 3.192929e-01 3.164139e-03 3.472682e-03 -6.000000e+00 1.773687e-02 224.98 -2.00 3.11 -2.00 318.45 0.00e+00 4.382575e-04 6.453824e-04 4.539230e-04 -6.000000e+00 8.067118e-04 290.57 -2.00 20.00 -2.00 317.61 0.00e+00 2.712 0.000 302.00 328.00 3 6.3974e+00 8.5086e-03 2.9920e-02 -6.0000e+00 4.3630e-02 1.0825e-01 9.7179e-03 1.4881e-02 -6.0000e+00 4.7007e-02 6.9228e-03 6.3898e-03 7.2726e-03 -6.0000e+00 2.8215e-02 -1.0287e-02 3.3396e-03 2.0795e-03 -6.0000e+00 1.2312e-02 4.1335e-05 -1.4404e-03 1.9280e-04 2.6845e-05 -6.0000e+00 9.0225e-04 -6.5330e-02 7.1225e-07 11 8 0 10 0 0 99.89 19.92 0.39 -0.06533 -0.07615 15 15 1 5 0 3985.040 26.11 20.00 19.92 30.79 38.1 987.62 6650 -9558 2726 -12338 3606 -4765 -2261 -10942 -4096 -4944 -5848 8195 -8903 4952 2419 7985 -4497 4364 3184 -3564 3230 4148 487 -538 -2506 5473 1525 -281 -1010 3655 163 2105 -3331 -2252 1934 -6035 -6692 2570 640 -1981 -1178 -369 -763 1266 -1833 -224 1823 332 -391 -988 -2539 -263 1390 207 1323 1085 617 1993 -1322 57 -283 -252 2764 2665 834 -414 -1731 -458 -896 2462 1145 1363 678 -687 819 790 -2753 -2634 -1688 -809 -1162 -1982 -1814 -1057 289 -1263 917 1663 7 2028 -24 276 -1435 -1898 -239 -370 1594 529 326 -35 -138 -655 -503 -739 -1737 -703 -682 -579 234 1779 771 715 635 -84 -1109 -116 -382 274 -82 -67 -140 313 1084 401 27 243 -395 -439 -507 169 -269 -375 -505 89 193 -140 -101 688 -84 845 -3 -1068 306 -572 152 -770 180 -245 -118 -687 -268 -347 -426 544 -773 436 251 877 -598 561 433 -538 470 603 75 -88 -442 933 271 -49 -171 584 28 392 -709 -493 399 -1327 -1572 637 191 -699 -456 -151 -324 536 -802 -97 766 140 -165 -426 -1162 -126 699 111 727 614 357 1140 -771 33 -167 -157 1812 1852 599 -289 -1159 -298 -615 1801 918 1141 575 -573 635 564 -1867 -1716 -1127 -590 -945 -1781 -1742 -1061 303 -1417 1059 1965 9 2333 -27 285 -1405 -1825 -235 -396 1842 671 437 -47 -179 -797 -584 -868 -2163 -914 -925 -818 344 2729 1247 1177 1030 -131 -1643 -163 -531 390 -122 -104 -223 495 1668 602 39 339 -535 -597 -721 254 -427 -613 -846 154 346 -263 -193 1336 -165 1619 -6 -1960 SS 20250209T155740.2Z 9171.665049 252 1 60.03 2 46.73 132.70 134.71 2.23 0.00 1 0.00 1 0 17 8.370e-03 5.493e-03 4.565e-03 1.974e-03 1.758252e-01 1.043784e-03 1.938470e-03 -6.000000e+00 5.050090e-03 224.99 -2.00 3.11 -2.00 316.74 0.00e+00 7.377385e-05 1.336301e-04 1.147474e-04 -6.000000e+00 2.305926e-04 290.57 -2.00 20.00 -2.00 315.90 0.00e+00 1.457 0.000 302.00 328.00 3 5.1399e+00 2.7105e-03 1.6141e-02 -6.0000e+00 1.2421e-02 1.0248e-02 3.0321e-03 8.0516e-03 -6.0000e+00 1.3408e-02 2.3942e-02 1.7674e-03 3.9663e-03 -6.0000e+00 8.0474e-03 -1.4754e-02 8.4075e-04 1.1361e-03 -6.0000e+00 3.4874e-03 6.3706e-04 1.3457e-04 6.4601e-05 1.6106e-05 -6.0000e+00 2.5864e-04 -2.0397e-02 1.4948e-04 11 1 0 11 8 0 99.99 21.02 0.28 -0.02040 -0.01939 1481 1481 1 5 0 40.500 27.05 20.00 21.02 30.77 42.1 988.42 1552 -703 -1490 -188 -2894 1505 -49 341 -67 -396 107 -1098 436 780 143 -1003 227 -78 937 -269 1219 101 -450 451 588 1269 413 351 1494 2177 2802 2123 1132 -816 -1227 -1747 -1212 132 -110 -846 -1886 -1255 -1124 -1036 -968 -866 -1215 -839 -405 -699 -90 276 1000 113 460 733 629 300 294 832 691 1505 1259 1048 402 -205 -346 136 1455 914 535 508 840 750 335 -172 -552 -401 -303 -296 -1079 -1168 -1783 -1318 -1095 -280 -170 35 267 133 279 9 367 482 476 353 291 552 -129 -229 -960 -641 -23 -104 -494 -829 -713 -395 258 483 318 306 225 -4 -127 349 177 408 211 -107 -14 -310 -19 198 15 260 455 568 634 389 -171 -418 -156 82 -189 -79 203 42 -99 151 -189 -437 264 -129 -276 -32 -468 226 -8 60 -13 -78 21 -224 95 189 38 -289 67 -24 288 -86 389 33 -149 155 210 460 148 119 476 674 888 716 404 -296 -431 -618 -464 57 -56 -486 -1176 -810 -740 -686 -638 -564 -776 -518 -244 -424 -56 181 684 80 335 542 469 224 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