File name: Pandora141s1_Calakmul_20250802_L2Fit_fwvt1c3d20231011p1-8.txt
File generation date: 20250805T180615.0Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: 
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 141
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora141_OF_v2d20230802.txt
Instrument calibration file used: Pandora141s1_CF_v3d20231011.txt
Level 1 file used: Pandora141s1_Calakmul_20250802_L1_smca1c3d20231011p1-8.txt
Full location name: Calakmul Atmospheric Observatory
Short location name: Calakmul
Country of location: Mexico
Location latitude [deg]: 18.5956
Location longitude [deg]: -89.4137
Location altitude [m]: 275
Local noon date: 20250802
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based on session 2
First and last pixel inside fitting window: 1659 1808
Nominal wavelengths inside fitting window [nm]: 492.0753 492.1962 492.3171 492.4380 492.5588 492.6797 492.8005 492.9213 493.0421 493.1629 493.2837 493.4044 493.5251 493.6458 493.7665 493.8872 494.0079 494.1285 494.2492 494.3698 494.4904 494.6110 494.7315 494.8521 494.9726 495.0931 495.2136 495.3341 495.4546 495.5750 495.6954 495.8158 495.9362 496.0566 496.1770 496.2973 496.4177 496.5380 496.6583 496.7785 496.8988 497.0191 497.1393 497.2595 497.3797 497.4999 497.6200 497.7402 497.8603 497.9804 498.1005 498.2206 498.3407 498.4607 498.5807 498.7007 498.8207 498.9407 499.0607 499.1806 499.3006 499.4205 499.5404 499.6602 499.7801 499.8999 500.0198 500.1396 500.2594 500.3791 500.4989 500.6187 500.7384 500.8581 500.9778 501.0975 501.2171 501.3368 501.4564 501.5760 501.6956 501.8151 501.9347 502.0542 502.1738 502.2933 502.4128 502.5322 502.6517 502.7711 502.8906 503.0100 503.1293 503.2487 503.3681 503.4874 503.6067 503.7260 503.8453 503.9646 504.0838 504.2031 504.3223 504.4415 504.5607 504.6799 504.7990 504.9181 505.0373 505.1564 505.2754 505.3945 505.5136 505.6326 505.7516 505.8706 505.9896 506.1085 506.2275 506.3464 506.4653 506.5842 506.7031 506.8220 506.9408 507.0596 507.1785 507.2972 507.4160 507.5348 507.6535 507.7723 507.8910 508.0097 508.1283 508.2470 508.3656 508.4842 508.6029 508.7214 508.8400 508.9586 509.0771 509.1956 509.3141 509.4326 509.5511 509.6695 509.7880 509.9064
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250802T123040.1Z 9345.521298 68 1 29.28 2 78.37 75.13 175.72 154.07 0.00 1 0.00 1 0 15 4.791e-03 4.673e-03 1.326e-03 1.324e-03 9.493470e+03 9.240865e+01 6.180639e+02 -6.000000e+00 2.766222e+02 293.75 -2.00 20.00 -2.00 505.28 0.00e+00 5.754271e-04 3.755265e-05 5.333754e-05 -6.000000e+00 1.382133e-04 293.75 -2.00 20.00 -2.00 500.48 0.00e+00 3.778531e-01 2.601747e-02 5.586319e-02 -6.000000e+00 9.479703e-02 227.39 -2.00 3.11 -2.00 502.07 0.00e+00 4.800 0.000 489.00 513.00 1 8.0583e+00 1.9989e-03 8.2528e-03 -6.0000e+00 7.2866e-03 -5.0268e-03 5.1384e-04 1.3831e-03 -6.0000e+00 1.9044e-03 3.0408e-04 1.2562e-03 1.2355e-04 6.0824e-05 -6.0000e+00 4.7777e-04 -5.9625e-02 5.5793e-05 12 9 8 11 8 0 99.74 19.85 0.69 -0.05963 -0.05091 12 12 1 4 0 2439.490 26.00 20.00 19.85 32.58 40.7 987.52 -464 -264 80 289 497 611 440 441 345 524 73 160 -172 -141 -162 -120 -197 -136 -64 89 174 -243 189 140 208 655 163 -95 123 -181 -628 -273 -330 -155 240 288 -24 -67 -22 30 85 -17 -7 -174 -44 349 210 -30 252 -155 -471 -614 -649 -445 1221 -1260 -236 187 280 34 410 140 344 1353 -995 -225 -276 -464 -521 -81 -216 -164 123 -55 198 -176 -136 -441 -253 -348 -384 -424 -471 -96 -57 23 -490 -133 -269 -199 45 -249 193 134 13 318 86 -113 -149 -275 -751 -375 -282 -291 -378 -282 -11 -8 93 145 85 -316 167 -204 192 1012 209 532 565 555 278 253 290 98 -16 123 -95 329 60 67 490 299 -122 29 3036 -2231 -403 -150 162 54 283 140 161 432 -112 192 -293 -176 -376 -481 -438 -251 77 285 498 620 452 456 356 538 75 162 -173 -141 -160 -119 -196 -137 -66 92 181 -254 197 146 217 683 170 -99 125 -181 -623 -270 -331 -158 249 301 -25 -70 -23 31 87 -18 -7 -181 -46 365 220 -31 258 -157 -468 -601 -628 -431 1186 -1266 -239 191 287 35 418 143 352 1375 -1021 -229 -278 -463 -516 -80 -212 -161 121 -55 197 -176 -134 -431 -245 -336 -371 -411 -459 -94 -56 23 -486 -132 -265 -195 44 -247 192 134 13 310 83 -107 -139 -254 -691 -347 -266 -283 -375 -283 -11 -8 92 144 85 -318 168 -206 194 1023 214 545 578 566 281 252 287 97 -16 122 -94 325 59 65 479 290 -117 27 2826 -2161 -390 -147 160 54 285 142 164 441 -115 196 -298 -176 -373 -475
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SQ 20250802T125710.4Z 9345.539703 81 1 3.16 2 72.28 76.85 171.27 118.00 0.00 1 0.00 1 0 15 2.857e-03 2.845e-03 1.168e-03 1.166e-03 6.452962e+03 7.767409e+01 4.253167e+02 -6.000000e+00 1.649509e+02 293.75 -2.00 20.00 -2.00 505.26 0.00e+00 5.085230e-04 3.305237e-05 4.217211e-05 -6.000000e+00 8.240425e-05 293.75 -2.00 20.00 -2.00 500.48 0.00e+00 1.885877e-01 2.289098e-02 4.013832e-02 -6.000000e+00 5.650137e-02 227.39 -2.00 3.11 -2.00 502.06 0.00e+00 3.240 0.000 489.00 513.00 1 5.8347e+00 1.7593e-03 5.7076e-03 -6.0000e+00 4.3435e-03 -9.8770e-05 4.5461e-04 9.7193e-04 -6.0000e+00 1.1344e-03 3.5554e-03 6.3115e-04 1.1096e-04 4.3763e-05 -6.0000e+00 2.8494e-04 -6.2248e-02 1.1522e-04 12 1 1 12 1 1 97.38 19.85 0.73 -0.06225 -0.05787 5 57 1 4 0 526.180 26.00 20.01 19.85 33.72 40.3 987.43 -813 -100 -20 263 332 373 579 376 166 379 16 260 -57 -140 -246 -52 -114 -174 -72 -71 -161 234 379 215 420 331 116 -57 -51 -345 -709 -481 25 60 272 392 142 33 95 67 -213 -76 -70 -20 238 286 92 17 -172 -70 -257 -381 -541 -531 114 -278 137 39 72 286 312 335 298 450 -110 45 -141 -281 -297 -10 -304 -94 73 -48 -256 -199 -286 -284 -439 -288 -536 -417 -29 -130 -66 -135 -359 -48 -436 -359 -207 41 -50 262 222 124 241 -170 -114 -159 -453 -409 -332 -545 -306 -223 -44 162 124 -206 44 78 178 277 376 402 630 386 556 272 462 498 376 28 76 222 23 -17 183 -71 250 170 21 91 561 -557 -195 -267 74 70 73 34 248 261 -73 -215 -65 -157 -106 -500 -793 -95 -20 259 337 377 596 392 174 391 17 261 -58 -141 -246 -52 -116 -176 -74 -73 -166 241 390 222 435 344 120 -59 -52 -345 -713 -482 24 61 279 407 147 34 98 69 -219 -79 -71 -20 247 298 96 17 -174 -71 -253 -375 -525 -517 113 -278 140 40 73 288 314 338 303 457 -112 45 -143 -280 -292 -10 -301 -92 73 -47 -255 -198 -280 -280 -428 -279 -521 -407 -28 -129 -65 -133 -357 -47 -433 -357 -207 40 -50 261 219 122 232 -164 -108 -151 -429 -392 -320 -534 -302 -223 -43 162 123 -206 43 78 179 280 383 411 647 390 560 278 463 490 377 28 75 219 23 -17 180 -70 244 163 20 87 535 -530 -189 -264 72 69 73 34 250 264 -74 -218 -64 -157 -104 -487
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