File name: Pandora141s1_Calakmul_20250818_L2Fit_fout2c3d20231011p1-8.txt File generation date: 20250819T060420.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 141 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora141_OF_v2d20230802.txt Instrument calibration file used: Pandora141s1_CF_v3d20231011.txt Level 1 file used: Pandora141s1_Calakmul_20250818_L1_smca1c3d20231011p1-8.txt Full location name: Calakmul Atmospheric Observatory Short location name: Calakmul Country of location: Mexico Location latitude [deg]: 18.5956 Location longitude [deg]: -89.4137 Location altitude [m]: 275 Local noon date: 20250818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 2 First and last pixel inside fitting window: 238 379 Nominal wavelengths inside fitting window [nm]: 305.1074 305.2483 305.3892 305.5302 305.6711 305.8120 305.9528 306.0937 306.2346 306.3754 306.5163 306.6571 306.7979 306.9387 307.0795 307.2203 307.3611 307.5018 307.6426 307.7833 307.9240 308.0647 308.2054 308.3461 308.4868 308.6275 308.7681 308.9088 309.0494 309.1900 309.3306 309.4712 309.6118 309.7524 309.8930 310.0335 310.1741 310.3146 310.4551 310.5956 310.7361 310.8766 311.0171 311.1575 311.2980 311.4384 311.5788 311.7192 311.8596 312.0000 312.1404 312.2808 312.4211 312.5615 312.7018 312.8421 312.9824 313.1227 313.2630 313.4033 313.5435 313.6838 313.8240 313.9643 314.1045 314.2447 314.3849 314.5251 314.6652 314.8054 314.9455 315.0857 315.2258 315.3659 315.5060 315.6461 315.7862 315.9262 316.0663 316.2063 316.3463 316.4864 316.6264 316.7664 316.9063 317.0463 317.1863 317.3262 317.4662 317.6061 317.7460 317.8859 318.0258 318.1657 318.3055 318.4454 318.5852 318.7250 318.8649 319.0047 319.1445 319.2842 319.4240 319.5638 319.7035 319.8433 319.9830 320.1227 320.2624 320.4021 320.5418 320.6814 320.8211 320.9607 321.1003 321.2400 321.3796 321.5192 321.6588 321.7983 321.9379 322.0774 322.2170 322.3565 322.4960 322.6355 322.7750 322.9145 323.0539 323.1934 323.3328 323.4723 323.6117 323.7511 323.8905 324.0299 324.1692 324.3086 324.4479 324.5873 324.7266 324.8659 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250818T140517.4Z 9361.587007 107 1 30.64 2 56.88 86.48 10.41 347.82 0.00 1 0.00 1 0 17 1.080e-02 6.233e-03 5.762e-03 2.374e-03 2.235037e-01 1.276297e-03 2.429034e-03 -6.000000e+00 6.591673e-03 227.27 -2.00 3.11 -2.00 316.66 0.00e+00 5.743349e-04 1.627718e-04 1.278677e-04 -6.000000e+00 3.020701e-04 293.76 -2.00 20.00 -2.00 315.79 0.00e+00 1.824 0.000 302.00 328.00 3 5.5725e+00 3.3199e-03 2.0303e-02 -6.0000e+00 1.6280e-02 4.1044e-02 3.7042e-03 1.0279e-02 -6.0000e+00 1.7519e-02 7.5815e-03 2.1641e-03 5.0285e-03 -6.0000e+00 1.0517e-02 -8.1106e-03 1.0394e-03 1.4276e-03 -6.0000e+00 4.5678e-03 2.6412e-04 -3.1737e-04 7.6163e-05 1.9268e-05 -6.0000e+00 3.3374e-04 -4.3173e-02 5.6152e-05 11 1 0 11 8 0 97.76 20.50 0.31 -0.04317 -0.04556 17 17 1 5 0 1801.670 26.62 20.00 20.50 30.57 43.8 983.17 -2268 1729 -3095 -2635 -1796 -3499 -2556 988 40 -1276 -1651 -2724 -152 -2 839 592 -1126 1637 -254 826 934 2283 -370 1487 954 705 864 -1206 646 485 2957 186 2523 -2297 -2373 -1713 -1597 -1102 -56 -657 -1368 -283 -444 -636 -416 -921 -53 -559 -195 -665 194 371 1478 899 1249 1170 212 -590 22 588 979 1567 1660 798 321 -30 -179 -413 879 881 500 751 528 694 -127 139 -400 -819 -969 -1099 -1656 -2080 -1677 -1636 -1218 -470 111 55 235 481 -17 -240 -155 862 124 505 582 592 -83 -229 -511 -994 38 -320 -517 -643 -732 33 523 849 594 457 343 51 -230 210 273 272 -52 -80 -35 39 255 169 143 -125 140 190 188 99 -255 -103 -174 145 60 -172 420 88 196 -329 -163 -602 -348 276 -524 -422 -263 -498 -376 155 7 -232 -304 -521 -31 -1 211 161 -326 477 -78 257 296 717 -121 497 334 254 308 -419 211 156 960 66 924 -887 -891 -636 -633 -495 -29 -378 -850 -182 -292 -422 -275 -609 -34 -356 -122 -420 126 252 1041 658 933 890 164 -459 17 450 767 1283 1437 718 288 -26 -146 -332 732 792 478 740 522 667 -117 119 -321 -638 -777 -952 -1559 -2099 -1772 -1797 -1396 -560 137 69 295 589 -20 -264 -161 873 130 564 695 751 -109 -300 -645 -1199 45 -384 -649 -841 -989 46 747 1256 902 697 511 73 -312 275 356 364 -73 -117 -52 58 370 239 195 -166 181 246 251 138 -368 -152 -259 222 95 -280 695 148 331 -549 -267 -969 SS 20250818T141026.5Z 9361.590584 110 1 21.40 2 55.67 86.84 10.72 342.05 0.00 1 0.00 1 0 17 1.467e-02 8.151e-03 9.442e-03 4.123e-03 2.212513e-01 2.217305e-03 2.406153e-03 -6.000000e+00 8.960031e-03 227.27 -2.00 3.11 -2.00 316.49 0.00e+00 5.372878e-04 2.721082e-04 1.935175e-04 -6.000000e+00 4.101557e-04 293.76 -2.00 20.00 -2.00 315.63 0.00e+00 1.767 0.000 302.00 328.00 3 6.1647e+00 5.7528e-03 1.9767e-02 -6.0000e+00 2.2130e-02 6.8627e-02 6.4107e-03 1.0124e-02 -6.0000e+00 2.3805e-02 -2.1400e-04 3.7316e-03 4.9503e-03 -6.0000e+00 1.4291e-02 -4.9468e-03 1.7808e-03 1.3915e-03 -6.0000e+00 6.2150e-03 1.5316e-04 -3.7560e-05 1.3173e-04 1.9092e-05 -6.0000e+00 4.5290e-04 -5.0167e-02 1.0864e-04 12 9 1 12 9 1 99.89 20.29 0.41 -0.05017 -0.05045 5 8 1 5 0 3564.500 26.41 19.99 20.29 31.86 42.7 983.17 144 -4091 1343 -4439 1098 -3828 -2975 -734 5535 -5774 -854 -1485 -2252 2682 -1814 -1102 -758 2535 -566 3392 1294 2665 2022 1968 757 2286 -555 322 2064 578 682 512 -66 -834 -2528 -1068 -1311 -1650 -335 -317 -1220 -1281 -1205 -878 -1584 -1001 -1351 -1918 -1425 461 -90 576 2389 249 1707 1378 1457 570 501 211 1500 1319 2314 1359 457 -44 -10 424 864 1168 292 1057 1240 -423 -635 -765 -463 -223 -1250 -1157 -1520 -1890 -2960 -1526 -841 -917 611 690 193 -105 274 -90 -913 -464 189 141 566 314 520 319 -1011 -1036 -733 303 -312 -932 -405 -418 939 536 1056 959 -30 539 194 -233 -132 -258 193 173 -62 523 49 204 482 104 -30 -44 698 -406 -273 -683 -88 -6 -129 -386 326 217 265 309 -165 -859 23 -746 237 -786 170 -591 -472 -126 977 -1178 -168 -300 -497 635 -497 -323 -232 776 -183 1090 431 880 680 688 279 853 -210 116 699 194 235 188 -26 -331 -990 -409 -535 -767 -177 -187 -780 -854 -821 -602 -1092 -683 -910 -1271 -926 296 -60 399 1708 187 1298 1068 1140 449 391 165 1190 1099 2022 1238 417 -38 -8 343 727 1056 283 1050 1233 -416 -595 -669 -376 -174 -1010 -1006 -1435 -1913 -3169 -1682 -966 -1102 753 869 244 -130 322 -100 -958 -476 198 158 675 399 682 417 -1282 -1251 -862 361 -390 -1217 -545 -579 1333 790 1593 1453 -44 764 262 -304 -172 -344 268 249 -91 763 71 286 653 137 -38 -57 920 -562 -389 -993 -130 -9 -201 -622 534 360 441 508 -266 -1367 SS 20250818T141535.8Z 9361.594165 113 1 30.06 2 54.45 87.21 11.14 336.67 0.00 1 0.00 1 0 17 7.838e-03 5.715e-03 1.143e-03 5.824e-04 2.113911e-01 3.150201e-04 2.313314e-03 -6.000000e+00 4.790502e-03 227.27 -2.00 3.11 -2.00 316.02 0.00e+00 1.460053e-04 3.471055e-05 9.959883e-05 -6.000000e+00 2.191754e-04 293.76 -2.00 20.00 -2.00 315.19 0.00e+00 1.715 0.000 302.00 328.00 3 3.1025e+00 8.1171e-04 1.9120e-02 -6.0000e+00 1.1832e-02 1.5499e-02 9.0092e-04 9.7170e-03 -6.0000e+00 1.2725e-02 3.7388e-03 5.2106e-04 4.7569e-03 -6.0000e+00 7.6396e-03 -4.9229e-03 2.4375e-04 1.3378e-03 -6.0000e+00 3.3245e-03 3.5849e-03 -1.1421e-04 1.8591e-05 1.9474e-05 -6.0000e+00 2.4202e-04 -5.4905e-02 6.6035e-05 11 1 0 11 8 0 99.94 20.13 0.15 -0.05491 -0.05576 228 228 1 5 0 131.820 26.32 20.02 20.13 33.00 41.9 983.23 -63 -894 -1342 -1976 -2369 -1187 -166 856 653 -998 -1514 -429 -216 372 44 -283 -156 334 228 678 770 593 907 1250 1013 798 -54 -187 591 1132 1490 2080 1080 -711 -1936 -1649 -1636 -561 -208 -828 -1119 -916 -751 -741 -448 -561 -790 -843 -533 -90 187 697 828 736 590 592 558 213 336 678 1038 1487 1657 1053 388 -136 -258 359 1012 1030 495 255 279 246 113 -92 -394 -398 -450 -659 -1112 -1690 -1883 -1648 -1045 -622 -261 182 32 145 187 188 194 645 509 537 439 308 -118 -278 -551 -746 -29 -30 -609 -750 -751 -317 171 561 465 207 96 40 287 417 493 600 327 -94 -182 -173 -85 79 236 209 499 630 492 309 -187 -256 -130 119 -57 -130 111 -50 -49 -216 -194 -404 -13 -184 -281 -430 -471 -221 -32 179 151 -245 -374 -107 -54 103 14 -96 -55 121 86 260 301 232 359 514 439 329 -22 -79 234 432 583 862 479 -326 -868 -726 -772 -279 -122 -521 -773 -664 -558 -555 -334 -415 -574 -596 -366 -62 132 520 607 564 466 478 457 174 271 545 856 1298 1451 970 357 -126 -222 298 879 927 486 262 288 246 106 -84 -328 -336 -365 -588 -1040 -1741 -1956 -1804 -1211 -724 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