File name: Pandora141s1_Calakmul_20250831_L2Fit_fout2c3d20231011p1-8.txt
File generation date: 20250901T060436.2Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c3p1-8
Local principal investigator: 
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 141
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora141_OF_v2d20230802.txt
Instrument calibration file used: Pandora141s1_CF_v3d20231011.txt
Level 1 file used: Pandora141s1_Calakmul_20250831_L1_smca1c3d20231011p1-8.txt
Full location name: Calakmul Atmospheric Observatory
Short location name: Calakmul
Country of location: Mexico
Location latitude [deg]: 18.5956
Location longitude [deg]: -89.4137
Location altitude [m]: 275
Local noon date: 20250831
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based on session 2
First and last pixel inside fitting window: 238 379
Nominal wavelengths inside fitting window [nm]: 305.1074 305.2483 305.3892 305.5302 305.6711 305.8120 305.9528 306.0937 306.2346 306.3754 306.5163 306.6571 306.7979 306.9387 307.0795 307.2203 307.3611 307.5018 307.6426 307.7833 307.9240 308.0647 308.2054 308.3461 308.4868 308.6275 308.7681 308.9088 309.0494 309.1900 309.3306 309.4712 309.6118 309.7524 309.8930 310.0335 310.1741 310.3146 310.4551 310.5956 310.7361 310.8766 311.0171 311.1575 311.2980 311.4384 311.5788 311.7192 311.8596 312.0000 312.1404 312.2808 312.4211 312.5615 312.7018 312.8421 312.9824 313.1227 313.2630 313.4033 313.5435 313.6838 313.8240 313.9643 314.1045 314.2447 314.3849 314.5251 314.6652 314.8054 314.9455 315.0857 315.2258 315.3659 315.5060 315.6461 315.7862 315.9262 316.0663 316.2063 316.3463 316.4864 316.6264 316.7664 316.9063 317.0463 317.1863 317.3262 317.4662 317.6061 317.7460 317.8859 318.0258 318.1657 318.3055 318.4454 318.5852 318.7250 318.8649 319.0047 319.1445 319.2842 319.4240 319.5638 319.7035 319.8433 319.9830 320.1227 320.2624 320.4021 320.5418 320.6814 320.8211 320.9607 321.1003 321.2400 321.3796 321.5192 321.6588 321.7983 321.9379 322.0774 322.2170 322.3565 322.4960 322.6355 322.7750 322.9145 323.0539 323.1934 323.3328 323.4723 323.6117 323.7511 323.8905 324.0299 324.1692 324.3086 324.4479 324.5873 324.7266 324.8659
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250831T125947.3Z 9374.541520 76 1 30.19 2 72.74 86.72 162.83 123.03 0.00 1 0.00 1 0 17 4.166e-02 6.294e-03 3.979e-02 2.939e-03 4.031587e-01 1.594235e-03 4.429477e-03 -6.000000e+00 2.545362e-02 227.23 -2.00 3.11 -2.00 319.41 0.00e+00 7.823284e-04 4.438506e-04 1.252137e-03 -6.000000e+00 1.164946e-03 293.74 -2.00 20.00 -2.00 318.56 0.00e+00 3.320 0.000 302.00 328.00 3 4.0410e+00 4.5205e-03 3.7293e-02 -6.0000e+00 6.2862e-02 -1.6871e-03 5.3455e-03 2.0152e-02 -6.0000e+00 6.7613e-02 1.5124e-02 3.9588e-03 9.4929e-03 -6.0000e+00 4.0592e-02 -1.2609e-02 2.0845e-03 2.6373e-03 -6.0000e+00 1.7663e-02 2.3432e-04 -4.8435e-04 9.5275e-05 3.4181e-05 -6.0000e+00 1.2863e-03 -5.5664e-02 -4.0806e-06 11 1 0 11 8 0 99.96 19.77 0.21 -0.05566 -0.05930 65 65 1 5 0 464.330 26.00 19.97 19.77 32.90 41.0 983.09 4777 10987 -4643 -13166 27477 -14943 2109 4462 -770 -12128 -11260 -4477 -9210 9331 -12662 -902 -6899 -1283 -4828 -3967 -1160 -388 -3714 -3933 1992 -2077 3168 -5146 -935 -3457 4855 2489 -3097 1610 -7036 -1584 -4277 -1060 3 -1813 -670 -1740 75 -1784 1210 -1671 -951 -577 514 825 -131 1757 249 1704 1146 991 1420 141 -240 494 2391 1148 2405 1190 1275 57 413 1118 719 1969 863 1015 -79 583 -53 20 -885 -1534 -1190 -1849 -1303 -2048 -1629 -1408 -589 -24 82 625 353 333 -368 118 -742 -287 88 -159 744 4 -19 -303 -802 -1234 -219 -501 -1305 -1110 -616 55 509 1208 609 891 536 297 80 333 829 367 283 -179 -239 -167 -206 -141 34 114 180 1005 155 54 -293 -648 -499 -37 -303 13 -53 -105 215 -22 81 82 90 220 -113 -339 458 -359 46 106 -21 -401 -385 -155 -381 385 -750 -54 -479 -90 -372 -317 -93 -32 -321 -363 186 -211 309 -528 -90 -347 489 287 -414 215 -1004 -215 -644 -181 1 -427 -173 -484 21 -528 352 -503 -285 -173 154 256 -44 621 96 686 484 433 632 63 -107 219 1078 559 1263 674 736 32 225 606 418 1250 598 731 -58 409 -35 13 -509 -873 -713 -1242 -973 -1689 -1434 -1303 -572 -24 87 680 384 353 -374 113 -676 -260 83 -166 850 5 -25 -398 -1015 -1474 -250 -579 -1593 -1420 -818 76 739 1850 982 1465 872 467 121 482 1194 546 440 -290 -393 -272 -327 -218 51 165 255 1434 235 87 -499 -1144 -904 -69 -592 27 -109 -221 451 -45 162 161
SS 20250831T130500.1Z 9374.545140 80 1 4.51 2 71.50 87.11 161.83 121.49 0.00 1 0.00 1 0 17 2.782e-02 7.193e-03 3.092e-02 4.310e-03 3.794092e-01 2.317574e-03 4.058886e-03 -6.000000e+00 1.700884e-02 227.23 -2.00 3.11 -2.00 318.43 0.00e+00 8.686314e-04 4.822627e-04 3.851623e-04 -6.000000e+00 7.779156e-04 293.74 -2.00 20.00 -2.00 317.54 0.00e+00 3.112 0.000 302.00 328.00 3 3.5217e+00 6.2683e-03 3.4631e-02 -6.0000e+00 4.2007e-02 1.0293e-02 7.1679e-03 1.7603e-02 -6.0000e+00 4.5172e-02 2.4179e-03 4.7851e-03 8.6580e-03 -6.0000e+00 2.7121e-02 -7.6372e-03 2.5195e-03 2.4887e-03 -6.0000e+00 1.1810e-02 4.9118e-04 -5.7057e-05 1.3643e-04 3.1030e-05 -6.0000e+00 8.5903e-04 -5.8458e-02 7.5885e-05 12 9 1 12 1 1 99.85 19.77 0.20 -0.05846 -0.05889 7 53 1 5 0 562.740 26.00 20.00 19.77 33.04 41.3 983.17 117 -1048 942 -7193 -5351 -1723 -3409 5122 -3835 -3913 -22847 -3423 4902 -6798 2366 -1689 -1202 -2744 3807 -1943 -979 1879 649 3135 -1268 2651 -1443 4073 -6122 -1116 -1944 661 -3871 -2539 -1773 -7356 -1256 -956 1845 -283 122 -1811 -799 764 -1557 -18 239 434 -665 -386 536 2003 3776 221 1164 951 -174 246 -435 -317 1589 1656 2751 1227 406 1289 -732 386 1756 43 930 501 609 -419 344 -483 -132 -1199 -1201 -1064 -1560 -1418 -2083 -1874 -781 -463 23 -599 434 441 490 43 -12 796 689 593 127 -250 -952 -155 -569 -777 447 385 -1033 -1153 -136 -366 326 990 625 500 372 141 218 622 662 834 -39 -446 -521 -359 -769 356 296 359 271 450 426 333 -301 -881 188 362 -101 202 -211 217 -190 -471 163 -220 4 -44 41 -331 -226 -68 -145 224 -203 -221 -1592 -212 320 -581 216 -180 -138 -339 467 -262 -135 256 92 458 -205 431 -245 641 -1026 -181 -340 125 -829 -557 -381 -1659 -288 -251 551 -98 46 -733 -332 319 -667 -8 101 183 -286 -170 246 970 1913 121 652 549 -103 145 -256 -186 943 1037 1830 868 293 901 -502 262 1243 33 763 426 519 -350 273 -361 -93 -834 -871 -840 -1348 -1318 -2053 -1922 -830 -512 26 -701 505 502 536 45 -12 789 711 657 152 -320 -1274 -207 -735 -957 530 461 -1297 -1505 -182 -509 469 1486 974 793 584 215 319 882 938 1208 -58 -694 -822 -561 -1186 533 434 511 379 635 626 513 -484 -1459 316 626 -181 371 -397 411 -362 -885 299 -396
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