File name: Pandora281s1_CambridgeBay_20240810_L2Fit_fwvt1c2d20240201p1-8.txt File generation date: 20240811T071603.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 281 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora281_OF_v1d20230823.txt Instrument calibration file used: Pandora281s1_CF_v2d20240201.txt Level 1 file used: Pandora281s1_CambridgeBay_20240810_L1_smca1c2d20240201p1-8.txt Full location name: Cambridge Bay, Nunavut: Canadian High Arctic Reseach Station Short location name: CambridgeBay Country of location: Canada Location latitude [deg]: 69.1212 Location longitude [deg]: -105.0398 Location altitude [m]: 10 Local noon date: 20240810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1161 492.2368 492.3574 492.4780 492.5986 492.7192 492.8398 492.9603 493.0808 493.2013 493.3218 493.4423 493.5628 493.6832 493.8036 493.9240 494.0444 494.1648 494.2852 494.4055 494.5258 494.6461 494.7664 494.8867 495.0069 495.1272 495.2474 495.3676 495.4878 495.6080 495.7281 495.8482 495.9684 496.0885 496.2086 496.3286 496.4487 496.5687 496.6887 496.8087 496.9287 497.0487 497.1686 497.2885 497.4085 497.5284 497.6482 497.7681 497.8879 498.0078 498.1276 498.2474 498.3672 498.4869 498.6067 498.7264 498.8461 498.9658 499.0855 499.2051 499.3247 499.4444 499.5640 499.6836 499.8031 499.9227 500.0422 500.1617 500.2812 500.4007 500.5202 500.6396 500.7591 500.8785 500.9979 501.1173 501.2366 501.3560 501.4753 501.5946 501.7139 501.8332 501.9525 502.0717 502.1909 502.3101 502.4293 502.5485 502.6677 502.7868 502.9059 503.0250 503.1441 503.2632 503.3822 503.5013 503.6203 503.7393 503.8583 503.9772 504.0962 504.2151 504.3340 504.4529 504.5718 504.6907 504.8095 504.9284 505.0472 505.1660 505.2847 505.4035 505.5222 505.6410 505.7597 505.8783 505.9970 506.1157 506.2343 506.3529 506.4715 506.5901 506.7087 506.8272 506.9458 507.0643 507.1828 507.3012 507.4197 507.5382 507.6566 507.7750 507.8934 508.0118 508.1301 508.2485 508.3668 508.4851 508.6034 508.7216 508.8399 508.9581 509.0763 509.1945 509.3127 509.4309 509.5490 509.6672 509.7853 509.9034 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20240810T114302.0Z 8988.488217 267 1 19.98 2 82.77 65.50 122.36 9.12 0.00 1 0.00 1 0 22 2.221e-02 2.212e-02 3.765e-03 3.755e-03 5.046479e+02 2.139893e+02 9.881868e+01 -6.000000e+00 1.278755e+03 276.81 -2.00 20.00 -2.00 505.39 0.00e+00 3.948013e-03 1.041436e-04 2.122116e-04 -6.000000e+00 6.285783e-04 276.81 -2.00 20.00 -2.00 501.02 0.00e+00 -4.421418e-01 7.543846e-02 4.398573e-02 -6.000000e+00 4.599303e-01 233.68 -2.00 4.87 -2.00 502.51 0.00e+00 7.312 0.012 489.00 513.00 1 8.3609e+00 5.7827e-03 1.2217e-02 -6.0000e+00 3.5263e-02 -2.0426e-02 1.4627e-03 7.7799e-04 -6.0000e+00 9.0685e-03 1.5927e-04 2.7912e-03 4.5905e-04 1.0391e-04 -6.0000e+00 2.7264e-03 5.7345e-03 -1.1361e-04 12 8 8 10 0 0 4.78 27.33 18.98 0.00573 0.02510 5 5 1 4 0 3995.300 35.25 20.00 27.33 20.91 4.1 935.27 -5372 -4153 -1295 238 1700 2718 4110 3058 2453 1076 341 -831 -2144 -2041 -3324 -2084 -932 440 1324 634 1751 1687 1562 2222 2579 2600 966 307 -2284 -2514 -3180 -3010 -1345 135 503 1311 965 -42 -658 286 216 471 2094 2958 3099 3443 3027 1485 112 -1452 -3380 -4218 -3988 -2955 -874 -9 1058 1896 2245 2626 1906 2663 3457 2354 1814 1244 -430 -254 -431 -2972 -2757 -2703 -903 -706 -156 -986 -2108 -2647 -3022 -3580 -2917 -2603 -3192 -2093 -1743 -836 -1206 -1150 -1186 -140 -197 1193 2505 2692 2325 2008 134 -1465 -2146 -4149 -3992 -3196 -2118 -233 -32 -551 -535 -1591 -1921 -242 640 1687 2641 3865 5200 4093 3925 3796 2928 2294 1671 145 1432 1072 1206 699 808 973 820 643 -31 -1596 -1450 -2379 -2999 -2674 -497 -507 480 819 1721 1461 1258 1330 1408 773 -1313 -2406 -3313 -3193 -5079 -3961 -1237 231 1663 2516 3797 2863 2297 1009 317 -772 -1995 -1883 -3106 -1940 -872 414 1256 611 1676 1622 1509 2143 2487 2502 938 295 -2206 -2388 -3021 -2884 -1296 132 497 1291 950 -41 -650 280 213 467 2072 2938 3099 3436 3016 1483 111 -1436 -3337 -4143 -3907 -2908 -863 -9 1071 1922 2279 2665 1956 2724 3516 2415 1857 1266 -439 -256 -431 -3023 -2792 -2747 -909 -716 -158 -1000 -2138 -2672 -3045 -3627 -2947 -2641 -3091 -2022 -1692 -809 -1175 -1123 -1162 -136 -195 1179 2473 2666 2301 1971 131 -1434 -2077 -4046 -3883 -3125 -2095 -231 -32 -556 -536 -1601 -1939 -243 646 1714 2703 3961 5309 4253 4096 3957 3056 2382 1726 151 1470 1107 1249 730 844 1015 856 670 -32 -1667 -1494 -2454 -3116 -2798 -517 -536 509 874 1832 1566 1357 1437 1516 830 -1417 -2578 -3536 -3394 SO 20240810T131300.3Z 8988.550697 313 1 19.12 2 75.05 86.17 119.86 33.88 0.00 1 0.00 1 0 57 1.712e-02 1.701e-02 3.229e-03 3.225e-03 6.336592e+02 1.868589e+02 4.056885e+01 -6.000000e+00 9.858612e+02 276.81 -2.00 20.00 -2.00 505.36 0.00e+00 2.926678e-03 8.975056e-05 1.539039e-04 -6.000000e+00 4.843737e-04 276.81 -2.00 20.00 -2.00 500.86 0.00e+00 -2.621225e-01 6.505881e-02 3.212136e-02 -6.000000e+00 3.539239e-01 233.67 -2.00 4.87 -2.00 502.39 0.00e+00 3.799 0.002 489.00 513.00 1 8.6352e+00 4.9882e-03 7.0351e-03 -6.0000e+00 2.7146e-02 -3.9103e-02 1.2636e-03 5.0397e-04 -6.0000e+00 6.9622e-03 1.9932e-04 -1.7997e-03 3.9289e-04 7.2459e-05 -6.0000e+00 2.1015e-03 7.2120e-03 3.4823e-05 12 8 8 10 0 0 -201.10 27.28 15.62 0.00721 -0.00527 5 5 1 4 0 3823.160 35.00 20.00 27.28 20.88 4.1 935.52 -4257 -3349 -1741 30 1783 2841 1901 2220 1498 843 -61 -124 -1261 -1964 -2058 -1314 -855 313 507 1277 870 1395 1530 1808 2002 1627 953 -88 -2145 -1887 -2362 -2049 -1568 66 1324 1287 546 -162 -379 310 310 234 1012 2110 2027 2584 2848 829 -651 -1120 -2750 -2808 -3044 -2394 -1493 -25 1108 1891 1426 2571 1975 1613 2167 1597 1645 754 -486 -220 -955 -1773 -2013 -987 -679 -615 65 -1339 -1891 -1857 -3236 -2075 -2657 -2349 -1476 -1050 -1240 -1176 -20 -805 -653 -548 414 1905 2099 2665 2194 1388 -323 -974 -1759 -3053 -3284 -2170 -1792 -321 -422 -494 -697 -1641 -1209 -958 120 999 2079 2756 3767 3305 3273 2733 2999 2346 1039 -95 424 840 791 228 686 653 490 662 475 -291 -2028 -1861 -1776 -1544 -1321 -348 -680 840 995 887 785 893 911 449 -285 -1620 -2106 -2391 -4003 -3182 -1675 29 1750 2813 1924 2249 1521 851 -61 -123 -1250 -1944 -2038 -1303 -858 298 490 1237 850 1360 1495 1768 1961 1596 934 -86 -2090 -1797 -2244 -1958 -1524 64 1305 1276 543 -162 -375 304 306 233 1013 2113 2047 2598 2839 832 -651 -1101 -2690 -2708 -2936 -2325 -1471 -24 1111 1901 1447 2585 2005 1650 2208 1633 1669 763 -491 -219 -949 -1761 -1998 -973 -673 -616 65 -1346 -1890 -1836 -3225 -2042 -2641 -2344 -1473 -1053 -1256 -1198 -20 -822 -669 -533 403 1850 2058 2609 2149 1353 -315 -937 -1674 -2906 -3130 -2073 -1745 -316 -420 -493 -694 -1637 -1200 -955 120 1007 2107 2810 3837 3403 3380 2832 3077 2395 1062 -97 431 853 807 235 703 669 503 675 482 -294 -2060 -1872 -1786 -1565 -1356 -359 -716 879 1047 939 836 952 969 475 -299 -1695 -2184 -2478 SO 20240810T132329.3Z 8988.557978 317 1 19.42 2 74.12 88.61 119.38 36.68 0.00 1 0.00 1 0 29 1.648e-02 1.635e-02 2.415e-03 2.410e-03 8.279844e+02 1.376164e+02 2.916551e+01 -6.000000e+00 9.486420e+02 276.81 -2.00 20.00 -2.00 505.34 0.00e+00 2.780649e-03 6.723520e-05 1.454199e-04 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