File name: Pandora281s1_CambridgeBay_20240822_L2Fit_fout2c2d20240201p1-8.txt File generation date: 20240826T185004.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 281 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora281_OF_v1d20230823.txt Instrument calibration file used: Pandora281s1_CF_v2d20240201.txt Level 1 file used: Pandora281s1_CambridgeBay_20240822_L1_smca1c2d20240201p1-8.txt Full location name: Cambridge Bay, Nunavut: Canadian High Arctic Reseach Station Short location name: CambridgeBay Country of location: Canada Location latitude [deg]: 69.1212 Location longitude [deg]: -105.0398 Location altitude [m]: 10 Local noon date: 20240822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1335 305.2741 305.4146 305.5551 305.6956 305.8361 305.9766 306.1171 306.2575 306.3980 306.5384 306.6788 306.8193 306.9597 307.1001 307.2405 307.3808 307.5212 307.6615 307.8019 307.9422 308.0825 308.2228 308.3631 308.5034 308.6437 308.7840 308.9242 309.0645 309.2047 309.3449 309.4851 309.6253 309.7655 309.9057 310.0458 310.1860 310.3261 310.4663 310.6064 310.7465 310.8866 311.0267 311.1668 311.3068 311.4469 311.5869 311.7269 311.8670 312.0070 312.1470 312.2870 312.4269 312.5669 312.7068 312.8468 312.9867 313.1266 313.2665 313.4064 313.5463 313.6862 313.8261 313.9659 314.1058 314.2456 314.3854 314.5252 314.6650 314.8048 314.9446 315.0843 315.2241 315.3638 315.5035 315.6433 315.7830 315.9227 316.0623 316.2020 316.3417 316.4813 316.6210 316.7606 316.9002 317.0398 317.1794 317.3190 317.4585 317.5981 317.7377 317.8772 318.0167 318.1562 318.2957 318.4352 318.5747 318.7142 318.8536 318.9931 319.1325 319.2719 319.4113 319.5507 319.6901 319.8295 319.9689 320.1082 320.2476 320.3869 320.5262 320.6655 320.8048 320.9441 321.0834 321.2227 321.3619 321.5011 321.6404 321.7796 321.9188 322.0580 322.1972 322.3363 322.4755 322.6147 322.7538 322.8929 323.0320 323.1711 323.3102 323.4493 323.5884 323.7274 323.8665 324.0055 324.1445 324.2835 324.4225 324.5615 324.7005 324.8395 324.9784 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240822T162131.2Z 9000.681611 40 1 29.76 2 63.15 134.67 91.08 282.92 0.00 1 0.00 1 0 17 4.833e-02 7.286e-03 2.252e-02 3.599e-03 3.267076e-01 1.874087e-03 5.317747e-03 -6.000000e+00 2.889706e-02 231.84 -2.00 4.87 -2.00 318.46 0.00e+00 8.628971e-04 3.578600e-04 2.677292e-04 -6.000000e+00 1.225485e-03 275.45 -2.00 20.00 -2.00 317.85 0.00e+00 2.202 0.000 302.00 328.00 3 5.4329e+00 5.0914e-03 3.2869e-02 -6.0000e+00 7.2610e-02 2.2415e-02 5.7585e-03 2.3770e-02 -6.0000e+00 7.8662e-02 6.4508e-03 3.8378e-03 1.1632e-02 -6.0000e+00 4.6514e-02 -9.1854e-03 1.9700e-03 3.2894e-03 -6.0000e+00 1.9254e-02 1.6890e-04 -1.2640e-04 1.1252e-04 3.8664e-05 -6.0000e+00 1.4439e-03 -2.1905e-02 5.5523e-05 11 8 0 10 0 0 95.84 25.32 0.43 -0.02190 -0.02285 12 12 1 5 0 2479.210 34.00 20.00 25.32 7.97 4.3 834.57 997 18425 46436 -4909 -6018 -13764 4905 -6525 336 -2395 -8852 -3654 -3761 7882 1562 -259 99 -835 462 559 -15 -303 -2811 -715 66 793 -2123 -85 258 3643 630 662 -743 -2536 -4778 -4734 -3257 -2798 1389 553 -1021 -3198 738 -181 831 -764 9 577 -1491 -2421 1397 1208 911 1315 1938 1242 329 273 960 -6 58 1268 1332 1655 1128 276 -764 -512 258 923 1255 1129 842 387 -677 -1011 -1343 -2068 -1687 -294 -649 -1586 -1477 -1693 -711 216 781 694 859 1082 -220 41 -508 -814 -119 431 788 553 888 -482 -1212 -748 -1572 -667 -760 -812 -879 -177 -49 550 839 469 500 415 -77 -914 -276 -578 370 283 -274 413 19 922 521 -124 -43 144 694 193 455 -117 -300 -322 -85 -220 479 201 78 -167 -58 -218 -653 50 841 1613 -265 -304 -754 241 -401 21 -161 -649 -276 -327 711 172 -32 13 -116 66 83 -2 -46 -460 -121 12 143 -390 -14 42 592 114 131 -161 -566 -1046 -1058 -799 -802 455 210 -429 -1439 329 -82 375 -350 4 254 -671 -1133 672 625 457 693 1050 693 188 155 533 -3 34 793 905 1183 801 186 -495 -332 179 713 1047 977 724 319 -521 -705 -866 -1315 -1142 -221 -551 -1499 -1491 -1810 -739 237 893 815 1004 1206 -230 43 -499 -796 -124 493 919 713 1196 -646 -1538 -874 -1769 -767 -938 -1058 -1204 -253 -74 817 1309 744 766 648 -111 -1272 -382 -838 566 456 -416 665 30 1377 742 -170 -57 192 986 295 734 -181 -480 -538 -149 -406 904 388 152 -315 -104 -382 -1128 SS 20240822T162631.6Z 9000.685088 43 1 29.86 2 62.84 136.00 91.48 284.06 0.00 1 0.00 1 0 25 1.443e-02 6.163e-03 3.111e-03 8.721e-04 3.214168e-01 4.557369e-04 5.273106e-03 -6.000000e+00 8.627327e-03 231.84 -2.00 4.87 -2.00 317.42 0.00e+00 5.320149e-04 6.634603e-05 1.747678e-04 -6.000000e+00 3.659656e-04 275.45 -2.00 20.00 -2.00 316.81 0.00e+00 2.179 0.000 302.00 328.00 3 3.2359e+00 1.2135e-03 3.2351e-02 -6.0000e+00 2.1678e-02 3.5530e-03 1.3585e-03 2.3267e-02 -6.0000e+00 2.3486e-02 1.8510e-03 8.2665e-04 1.1345e-02 -6.0000e+00 1.3888e-02 -3.8224e-03 4.0552e-04 3.1257e-03 -6.0000e+00 5.7475e-03 1.5856e-03 -4.3208e-04 2.6581e-05 3.7528e-05 -6.0000e+00 4.3120e-04 -2.1296e-02 1.9977e-05 10 0 0 10 0 0 99.00 25.37 0.31 -0.02130 -0.02454 90 90 1 5 0 331.680 34.00 20.00 25.37 8.08 4.3 835.37 -2803 -1640 -1473 -5142 -6292 -5432 -4746 -1802 -3313 -3296 -4849 -4056 -1612 -1351 -74 -762 336 -369 650 250 930 535 517 587 390 -101 -562 -1264 -1246 -26 1020 1252 635 -944 -2995 -2932 -2272 -1236 -27 -42 -431 -50 246 -86 201 50 -106 -370 -314 447 937 885 1204 1630 1026 825 761 617 308 552 957 1799 1871 1384 692 -376 -588 -619 -73 546 553 405 384 311 -264 -676 -1197 -1446 -1277 -768 -994 -1453 -1491 -1620 -981 -515 -101 438 577 491 210 -75 -393 -266 -164 135 562 584 509 19 -521 -1099 -1058 -649 -531 -777 -644 -368 135 513 790 585 432 -104 -231 -309 17 77 262 208 175 255 382 516 364 330 274 517 625 458 209 81 -375 -149 -102 -63 176 61 118 -100 -247 -392 -872 -251 -157 -141 -476 -545 -468 -439 -181 -370 -384 -584 -524 -233 -226 -13 -145 67 -78 142 57 212 124 125 150 105 -28 -155 -333 -315 -7 280 374 206 -313 -972 -971 -763 -483 -13 -20 -230 -28 141 -50 116 29 -61 -209 -178 258 533 541 780 1110 727 600 524 423 223 401 673 1355 1529 1124 559 -308 -460 -485 -61 479 525 376 354 291 -229 -569 -933 -1105 -1040 -658 -958 -1461 -1515 -1741 -1123 -593 -122 537 704 575 241 -80 -413 -277 -171 155 685 744 681 25 -651 -1346 -1236 -779 -683 -1004 -874 -498 192 745 1205 905 647 -154 -317 -425 23 105 379 303 259 371 568 734 517 448 358 686 882 661 305 123 -586 -232 -168 -104 298 106 205 -169 -420 -645 -1415 SS 20240822T163705.5Z 9000.692425 46 1 30.68 2 62.21 138.83 92.31 286.46 0.00 1 0.00 1 0 25 6.708e-02 8.510e-03 3.465e-02 5.464e-03 3.192315e-01 2.843514e-03 5.243343e-03 -6.000000e+00 4.008857e-02 231.84 -2.00 4.87 -2.00 318.47 0.00e+00 6.080349e-04 5.469308e-04 3.141910e-04 -6.000000e+00 1.701092e-03 275.45 -2.00 20.00 -2.00 317.84 0.00e+00 2.133 0.000 302.00 328.00 3 6.0546e+00 7.7406e-03 3.2094e-02 -6.0000e+00 1.0073e-01 4.5807e-02 8.7663e-03 2.3373e-02 -6.0000e+00 1.0914e-01 3.8273e-03 5.7959e-03 1.1440e-02 -6.0000e+00 6.4538e-02 -8.1084e-03 2.9504e-03 3.1652e-03 -6.0000e+00 2.6701e-02 9.6881e-05 -8.0010e-04 1.7192e-04 3.9835e-05 -6.0000e+00 2.0045e-03 -2.0625e-02 -4.6226e-05 11 8 0 10 0 0 99.22 25.43 0.66 -0.02062 -0.02664 9 9 1 5 0 3408.300 34.00 19.99 25.43 8.47 4.2 838.07 -11507 -24960 68644 -1344 12790 -5013 2838 -7567 -980 -3135 -3590 -4469 -2944 -6371 4000 2162 -6130 3650 1425 1811 -204 600 2266 -4366 2261 713 -1214 -543 -519 913 -1951 729 -851 2182 -5105 -1312 -4751 -3826 80 -1659 148 4704 -1416 -285 -1278 1928 757 -980 -279 159 1086 -845 1132 2179 2490 -147 161 1514 -527 -1193 -221 432 1123 1652 705 623 -178 -1597 -1044 1454 663 1359 1883 -1056 297 -1926 -319 -2155 -1603 -470 -795 -1410 -1447 -2475 -628 509 109 823 1333 706 -17 -402 -1034 -616 -199 -122 1049 942 1089 -164 -572 -1582 -1303 -1601 -808 -654 -370 -386 529 856 1356 781 -70 32 -381 -945 -215 -879 162 -91 358 72 698 654 481 -449 55 322 221 -191 138 -193 -527 -289 223 -202 819 330 248 -170 9 -188 -811 -619 -1656 1975 -72 552 -259 147 -484 -64 -219 -256 -348 -259 -672 435 263 -856 486 203 265 -31 91 351 -765 389 128 -220 -92 -85 150 -358 142 -181 453 -1093 -276 -1152 -1079 26 -627 59 1895 -624 -125 -568 828 324 -422 -119 69 500 -425 593 1191 1402 -87 96 886 -309 -708 -135 284 793 1224 520 432 -118 -1078 -755 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