File name: Pandora281s1_CambridgeBay_20240910_L2Fit_fout2c2d20240201p1-8.txt File generation date: 20240911T070024.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 281 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora281_OF_v1d20230823.txt Instrument calibration file used: Pandora281s1_CF_v2d20240201.txt Level 1 file used: Pandora281s1_CambridgeBay_20240910_L1_smca1c2d20240201p1-8.txt Full location name: Cambridge Bay, Nunavut: Canadian High Arctic Reseach Station Short location name: CambridgeBay Country of location: Canada Location latitude [deg]: 69.1212 Location longitude [deg]: -105.0398 Location altitude [m]: 10 Local noon date: 20240910 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1335 305.2741 305.4146 305.5551 305.6956 305.8361 305.9766 306.1171 306.2575 306.3980 306.5384 306.6788 306.8193 306.9597 307.1001 307.2405 307.3808 307.5212 307.6615 307.8019 307.9422 308.0825 308.2228 308.3631 308.5034 308.6437 308.7840 308.9242 309.0645 309.2047 309.3449 309.4851 309.6253 309.7655 309.9057 310.0458 310.1860 310.3261 310.4663 310.6064 310.7465 310.8866 311.0267 311.1668 311.3068 311.4469 311.5869 311.7269 311.8670 312.0070 312.1470 312.2870 312.4269 312.5669 312.7068 312.8468 312.9867 313.1266 313.2665 313.4064 313.5463 313.6862 313.8261 313.9659 314.1058 314.2456 314.3854 314.5252 314.6650 314.8048 314.9446 315.0843 315.2241 315.3638 315.5035 315.6433 315.7830 315.9227 316.0623 316.2020 316.3417 316.4813 316.6210 316.7606 316.9002 317.0398 317.1794 317.3190 317.4585 317.5981 317.7377 317.8772 318.0167 318.1562 318.2957 318.4352 318.5747 318.7142 318.8536 318.9931 319.1325 319.2719 319.4113 319.5507 319.6901 319.8295 319.9689 320.1082 320.2476 320.3869 320.5262 320.6655 320.8048 320.9441 321.0834 321.2227 321.3619 321.5011 321.6404 321.7796 321.9188 322.0580 322.1972 322.3363 322.4755 322.6147 322.7538 322.8929 323.0320 323.1711 323.3102 323.4493 323.5884 323.7274 323.8665 324.0055 324.1445 324.2835 324.4225 324.5615 324.7005 324.8395 324.9784 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20240910T155913.4Z 9019.666127 4017 1 31.93 2 70.84 132.38 127.77 67.20 0.00 1 0.00 1 0 25 1.130e-01 2.121e-02 1.197e-01 1.523e-02 3.509639e-01 7.901103e-03 6.029357e-03 -6.000000e+00 6.666122e-02 228.26 -2.00 4.87 -2.00 319.23 0.00e+00 -1.921026e-03 1.852255e-03 2.053017e-03 -6.000000e+00 2.875311e-03 272.49 -2.00 20.00 -2.00 318.67 0.00e+00 3.012 0.001 302.00 328.00 3 6.4375e+00 2.1844e-02 4.0640e-02 -6.0000e+00 1.6620e-01 8.3532e-02 2.5121e-02 2.9007e-02 -6.0000e+00 1.8067e-01 -3.4271e-02 1.8245e-02 1.2901e-02 -6.0000e+00 1.0702e-01 1.7742e-02 9.4802e-03 4.0489e-03 -6.0000e+00 4.4658e-02 2.7663e-05 -1.1506e-03 4.8751e-04 4.5172e-05 -6.0000e+00 3.3897e-03 -2.1460e-02 -8.6626e-05 12 9 8 11 8 0 99.91 26.21 0.80 -0.02146 -0.03011 8 8 1 5 0 3990.670 34.25 20.01 26.21 12.84 3.9 868.55 10004 -27536 900000 -73415 -52998 12497 -32235 12497 8358 6922 -41257 -17322 -24189 14681 -7224 -10321 14401 346 -8913 9343 -12851 13385 23170 4251 11362 11268 12254 -8527 -12287 -11312 835 8592 13021 -3979 -3589 1356 -8609 -2108 8187 -6607 -9072 -6072 357 9837 -1654 6214 -3607 5918 12844 7003 -7875 4038 7838 6087 3247 5096 9052 -137 -4119 -3385 1507 -1638 5913 3026 1707 2426 -6787 -1264 1681 -1812 -309 1976 3908 4898 -1629 353 -1318 1900 -2455 -6674 -1312 -4099 296 -1757 934 -468 390 2017 389 -922 2243 -266 -7100 143 -1894 1210 -2255 1746 254 -333 83 -4249 -3609 -2677 -2142 -525 -1367 -1658 585 2130 4077 1378 -403 -105 -1984 639 -192 1082 -21 2890 1023 -312 385 1364 598 82 -210 2113 -1912 628 -623 1474 -110 1043 -1354 96 -485 -388 -1596 1276 639 -307 -950 311 -1338 900000 -5252 -2861 354 -1566 439 338 299 -2951 -1052 -1796 852 -595 -961 1108 32 -950 858 -1492 1210 2002 476 1258 1293 1373 -1105 -1576 -1466 104 1079 1687 -618 -586 215 -1687 -457 1921 -2080 -3192 -2173 123 3096 -582 2011 -1269 1871 3795 2267 -3169 1553 3096 2594 1480 2346 4072 -67 -2061 -1678 738 -892 3249 1811 1027 1365 -4010 -711 994 -1243 -227 1470 2826 3346 -1096 210 -736 1007 -1454 -4658 -978 -3475 257 -1651 915 -495 429 2240 438 -1005 2194 -246 -6599 123 -1777 1224 -2642 2170 337 -436 102 -5035 -4046 -3056 -2608 -664 -1833 -2351 862 3311 6574 2320 -670 -164 -2931 874 -264 1534 -32 4501 1644 -502 596 2007 843 111 -275 2746 -2768 953 -1015 2443 -191 1865 -2621 192 -1003 -817 -3398 2564 1241 -579 -1767 SU 20240910T173944.1Z 9019.735927 6513 1 30.76 2 65.84 158.84 119.56 91.01 0.00 1 0.00 1 0 25 1.745e-01 3.383e-02 8.137e-02 1.462e-02 2.880421e-01 7.497332e-03 4.945893e-03 -6.000000e+00 1.028734e-01 228.25 -2.00 4.87 -2.00 318.54 0.00e+00 1.278497e-02 1.423637e-03 2.873484e-04 -6.000000e+00 4.371974e-03 272.48 -2.00 20.00 -2.00 318.01 0.00e+00 2.426 0.000 302.00 328.00 3 6.9249e+00 2.0375e-02 3.3071e-02 -6.0000e+00 2.5649e-01 1.6189e-01 2.2945e-02 2.6251e-02 -6.0000e+00 2.7884e-01 -1.6536e-01 1.4346e-02 1.1651e-02 -6.0000e+00 1.6508e-01 9.0744e-02 7.1772e-03 1.0489e-02 -6.0000e+00 6.8616e-02 3.0749e-05 -2.6849e-03 4.6132e-04 1.0448e-04 -6.0000e+00 5.2094e-03 -2.1834e-02 -1.8545e-04 12 8 8 10 0 0 99.83 26.17 1.69 -0.02183 -0.04201 8 8 1 5 0 3843.560 34.25 20.00 26.17 12.19 4.0 865.63 77000 33646 -97621 40944 75197 24850 -23488 20028 20206 5003 32799 -7204 29804 20932 27115 38842 45965 58096 26853 32532 21130 13153 14215 11748 13047 14535 19140 10392 -4264 8547 4654 11818 10323 10650 4930 10268 10762 -721 816 -3008 5979 -326 1183 6946 2464 5122 11585 5746 5576 4780 8516 4374 874 1635 -1804 -1144 -35 -4447 -9221 -911 142 3518 4756 2897 1017 4269 5004 1962 -246 -2946 1 1076 -1322 -3859 -1091 -2400 -2092 -3430 -6536 -5320 -4182 -2285 -860 -3978 -441 -1509 -3194 -659 -1144 860 1524 -3418 -3138 -3324 -194 1995 -135 -369 3393 1690 236 213 -1576 -2091 -2821 -204 -185 1187 -807 22 2609 974 741 -2262 602 -278 -2861 -1503 449 2692 1386 726 2662 3535 -446 2430 314 2165 2161 1951 -428 490 1081 -1261 -1557 353 -181 1382 49 -1305 -613 -2649 -1160 3393 2486 -26952 2600 3022 1546 -2344 1324 1362 389 1913 -682 2318 2143 3058 4330 5064 5949 3898 4554 3287 2148 2248 1873 2029 2223 2754 1576 -741 1374 857 2221 2114 2181 1111 2181 2455 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2.0525e-02 -6.0000e+00 5.8223e-02 1.0775e-02 5.1337e-03 1.0151e-02 -6.0000e+00 3.4470e-02 -1.0931e-02 2.6180e-03 2.9724e-03 -6.0000e+00 1.4342e-02 1.0710e-04 -2.9056e-04 1.6006e-04 3.6624e-05 -6.0000e+00 1.0866e-03 -2.4254e-02 3.2679e-05 12 8 8 10 0 0 99.94 26.16 0.35 -0.02425 -0.02644 9 9 1 5 0 3332.520 34.25 19.99 26.16 12.28 4.0 866.25 1548 -5990 21414 -3461 -12586 -11597 -8686 11238 -6285 -15252 -4217 -4010 -5851 -4547 -1668 -4548 1936 4001 -6830 8158 4400 -3643 3006 -2534 4197 2463 -3216 2079 563 -3014 -916 3246 -2022 -312 -3274 -2024 1516 -3350 3677 130 1670 1189 -3245 8 139 -1759 420 -1399 -17 -1096 219 692 2551 1637 -629 947 1612 1452 -461 -1108 556 953 3185 2510 1151 -289 -780 -1706 256 861 -218 1180 308 1152 133 -1083 -1557 -2328 -2464 -1047 -2223 -439 -1564 -2324 -932 153 -91 1174 1400 895 -16 -153 -376 -1484 -337 -176 1070 685 933 582 -563 -1318 -2529 -709 -1719 -831 126 83 -190 1277 1449 517 372 -522 181 -1281 -578 -552 508 294 -27 35 523 468 186 436 -572 373 785 211 -401 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