File name: Pandora281s1_CambridgeBay_20240921_L2Fit_fout2c2d20240201p1-8.txt File generation date: 20240922T065708.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 281 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora281_OF_v1d20230823.txt Instrument calibration file used: Pandora281s1_CF_v2d20240201.txt Level 1 file used: Pandora281s1_CambridgeBay_20240921_L1_smca1c2d20240201p1-8.txt Full location name: Cambridge Bay, Nunavut: Canadian High Arctic Reseach Station Short location name: CambridgeBay Country of location: Canada Location latitude [deg]: 69.1212 Location longitude [deg]: -105.0398 Location altitude [m]: 10 Local noon date: 20240921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1335 305.2741 305.4146 305.5551 305.6956 305.8361 305.9766 306.1171 306.2575 306.3980 306.5384 306.6788 306.8193 306.9597 307.1001 307.2405 307.3808 307.5212 307.6615 307.8019 307.9422 308.0825 308.2228 308.3631 308.5034 308.6437 308.7840 308.9242 309.0645 309.2047 309.3449 309.4851 309.6253 309.7655 309.9057 310.0458 310.1860 310.3261 310.4663 310.6064 310.7465 310.8866 311.0267 311.1668 311.3068 311.4469 311.5869 311.7269 311.8670 312.0070 312.1470 312.2870 312.4269 312.5669 312.7068 312.8468 312.9867 313.1266 313.2665 313.4064 313.5463 313.6862 313.8261 313.9659 314.1058 314.2456 314.3854 314.5252 314.6650 314.8048 314.9446 315.0843 315.2241 315.3638 315.5035 315.6433 315.7830 315.9227 316.0623 316.2020 316.3417 316.4813 316.6210 316.7606 316.9002 317.0398 317.1794 317.3190 317.4585 317.5981 317.7377 317.8772 318.0167 318.1562 318.2957 318.4352 318.5747 318.7142 318.8536 318.9931 319.1325 319.2719 319.4113 319.5507 319.6901 319.8295 319.9689 320.1082 320.2476 320.3869 320.5262 320.6655 320.8048 320.9441 321.0834 321.2227 321.3619 321.5011 321.6404 321.7796 321.9188 322.0580 322.1972 322.3363 322.4755 322.6147 322.7538 322.8929 323.0320 323.1711 323.3102 323.4493 323.5884 323.7274 323.8665 324.0055 324.1445 324.2835 324.4225 324.5615 324.7005 324.8395 324.9784 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240921T160943.1Z 9030.673415 384 1 29.72 2 74.04 137.16 72.49 280.34 0.00 1 0.00 1 0 25 2.251e-01 1.630e-02 2.184e-01 1.374e-02 4.250677e-01 7.160922e-03 6.967962e-03 -6.000000e+00 1.316073e-01 226.01 -2.00 4.87 -2.00 319.77 0.00e+00 2.125152e-03 1.968934e-03 6.998480e-04 -6.000000e+00 5.677322e-03 270.29 -2.00 20.00 -2.00 319.27 0.00e+00 3.574 0.001 302.00 328.00 3 5.6324e+00 2.0074e-02 4.7058e-02 -6.0000e+00 3.2664e-01 1.9021e-01 2.3474e-02 3.0610e-02 -6.0000e+00 3.5585e-01 -6.0914e-02 1.9213e-02 1.5581e-02 -6.0000e+00 2.1090e-01 9.9294e-03 1.0106e-02 4.7479e-03 -6.0000e+00 8.8214e-02 3.0845e-05 -2.0209e-03 4.3730e-04 6.2415e-05 -6.0000e+00 6.7517e-03 -1.8933e-02 -1.4420e-04 12 8 8 10 0 0 99.79 26.42 0.52 -0.01893 -0.03412 8 8 1 5 0 3714.440 34.50 20.00 26.42 7.91 4.1 832.59 134506 74568 900000 -40014 109305 -55347 117041 -33385 -48996 2868 1584 -52108 4571 19093 -7608 -20468 -14584 -21366 -11436 -7911 -14664 15843 33154 -17950 51191 1424 -11707 7050 4879 5342 19538 -15085 -10061 3187 -636 -846 -6099 9977 -4169 -10076 -3299 -7231 163 12211 5801 815 -1307 1909 -2970 5167 -842 4994 7745 7927 -2668 2477 -3962 7643 -1139 -3381 2107 3200 5076 487 1038 1605 669 -4077 -944 -2468 6464 603 2825 221 -1562 -678 1856 -469 -2166 -582 -3555 442 -1751 980 529 -2006 140 616 841 1684 543 -1782 -2405 -681 1245 127 -1538 560 852 -1086 -1517 -2156 -932 -2183 -2220 -135 -1765 -771 798 1739 1534 2308 1488 -694 388 -2336 -523 -3252 -1418 710 908 1138 852 1307 -277 692 -50 -836 1102 571 -753 -55 948 -678 883 -301 1922 -151 660 -216 -1110 -478 -1445 1802 999 900000 -1170 1464 -1753 1568 -1017 -1909 70 41 -2539 150 651 -398 -1371 -995 -1665 -850 -588 -1179 945 1736 -1661 2494 118 -1098 576 399 458 1623 -1980 -1375 389 -77 -105 -891 1457 -838 -2484 -831 -1995 43 2912 1484 221 -361 511 -848 1419 -265 1606 2594 2814 -1094 989 -1709 2908 -464 -1409 867 1415 2421 260 553 811 330 -2136 -520 -1547 4018 411 1858 141 -936 -363 900 -231 -1178 -355 -2539 337 -1466 844 489 -2021 145 648 877 1667 504 -1566 -2010 -562 1089 126 -1752 695 1110 -1420 -1871 -2461 -992 -2398 -2605 -163 -2289 -1049 1142 2668 2516 3847 2443 -1102 569 -3351 -737 -4905 -2227 1142 1466 1798 1309 1917 -392 931 -66 -1132 1581 895 -1277 -96 1711 -1301 1765 -638 4092 -335 1445 -462 -2290 -939 -2802 SS 20240921T184211.4Z 9030.779298 473 1 15.94 2 68.86 177.11 83.52 313.58 0.00 1 0.00 1 0 17 2.914e-02 7.572e-03 1.927e-02 3.625e-03 3.350712e-01 1.860095e-03 5.493746e-03 -6.000000e+00 1.704435e-02 225.99 -2.00 4.87 -2.00 318.30 0.00e+00 2.581631e-04 3.418535e-04 2.522456e-04 -6.000000e+00 7.344358e-04 270.27 -2.00 20.00 -2.00 317.78 0.00e+00 2.746 0.001 302.00 328.00 3 4.5345e+00 4.9832e-03 3.6371e-02 -6.0000e+00 4.2303e-02 2.2753e-02 5.6360e-03 2.3702e-02 -6.0000e+00 4.6072e-02 -1.4426e-03 3.7629e-03 1.1833e-02 -6.0000e+00 2.7305e-02 -3.6296e-03 1.9475e-03 3.3987e-03 -6.0000e+00 1.1432e-02 2.4934e-04 -3.7152e-04 1.1338e-04 4.0622e-05 -6.0000e+00 8.7279e-04 -2.1628e-02 1.7826e-05 12 9 1 12 1 1 97.14 26.25 0.37 -0.02163 -0.02442 8 17 1 5 0 1770.230 34.50 20.00 26.25 9.13 4.1 843.91 -16923 -3760 900000 -7769 -9747 -12465 -6763 -13126 1112 -9503 -2900 -2687 -756 -4052 -2438 -1449 1877 -1546 354 2603 -853 3747 750 1102 83 1868 -2559 -1034 2256 411 812 -1150 693 -3662 -3078 -2261 -2108 -2564 -556 1297 -1995 -1271 -2459 -200 1140 1821 237 -239 483 -1121 1659 1318 1703 1888 834 1490 726 992 529 1151 405 1872 1668 1354 431 -821 -934 -1056 39 1143 777 519 1155 762 611 -1720 -2342 -1984 -1622 -576 -572 -2121 -1346 -2013 -949 -306 152 1046 550 796 -111 -468 -376 -249 -665 -293 139 1033 1307 -465 -654 -695 -1334 -269 -774 -975 -512 -571 440 377 597 1021 -162 -190 260 -490 -135 -66 300 438 78 350 333 302 617 -165 197 654 337 942 368 -20 -802 -718 285 -91 132 202 189 -91 89 -629 -685 -1041 -219 900000 -442 -524 -692 -385 -891 72 -715 -209 -210 -67 -431 -293 -190 253 -227 53 397 -137 579 125 194 16 356 -504 -190 385 74 157 -249 159 -886 -712 -530 -550 -790 -182 482 -834 -554 -1116 -90 505 801 105 -105 211 -514 792 679 930 1089 504 917 457 618 326 707 261 1179 1146 987 314 -571 -622 -707 28 907 671 466 1021 645 478 -1246 -1575 -1306 -1139 -453 -506 -1942 -1309 -2086 -1042 -355 171 1199 631 939 -122 -478 -359 -236 -678 -330 163 1320 1748 -621 -824 -810 -1609 -307 -953 -1269 -698 -820 620 570 951 1643 -256 -281 357 -690 -190 -97 435 668 121 534 495 430 894 -230 265 888 493 1371 570 -32 -1344 -1177 490 -165 244 383 357 -168 157 -1083 -1158 SS 20240921T184700.1Z 9030.782640 476 1 29.96 2 68.84 178.40 83.80 314.62 0.00 1 0.00 1 0 25 2.984e-02 6.025e-03 5.326e-03 1.085e-03 3.353605e-01 5.546752e-04 5.538502e-03 -6.000000e+00 1.745434e-02 225.98 -2.00 4.87 -2.00 317.99 0.00e+00 7.690283e-04 9.419945e-05 1.794491e-04 -6.000000e+00 7.409208e-04 270.26 -2.00 20.00 -2.00 317.48 0.00e+00 2.745 0.001 302.00 328.00 3 3.0711e+00 1.4766e-03 3.6395e-02 -6.0000e+00 4.3322e-02 1.4815e-03 1.6639e-03 2.3753e-02 -6.0000e+00 4.7181e-02 4.8176e-03 1.0717e-03 1.1815e-02 -6.0000e+00 2.7947e-02 -6.2444e-03 5.4846e-04 3.4118e-03 -6.0000e+00 1.1656e-02 1.0879e-03 -4.5814e-04 3.3443e-05 4.1280e-05 -6.0000e+00 8.8993e-04 -2.1465e-02 3.3377e-05 10 0 0 10 0 0 99.83 26.25 0.39 -0.02147 -0.02491 100 100 1 5 0 299.510 34.50 20.00 26.25 9.31 4.1 845.48 -3197 -1623 25862 -10779 -8671 -5393 -6887 -2430 -6679 -8281 -5075 -3677 -3774 -1744 -678 -119 -486 -264 -533 153 -130 -449 327 -208 -693 43 -1082 -1348 -1666 -179 693 1525 336 -1304 -3127 -2764 -1758 -1888 565 184 -399 -33 -260 15 347 192 -672 -335 -331 521 517 1165 1148 1208 869 904 862 908 68 576 722 1680 2066 1600 769 -274 -748 -553 -73 943 417 749 407 352 14 -673 -1374 -1548 -1286 -731 -991 -1447 -1322 -1635 -844 -237 108 327 738 707 295 42 -286 -416 -227 -71 539 644 544 93 -512 -1006 -1230 -775 -379 -735 -627 -356 -53 319 575 472 262 -108 -247 -323 -192 157 248 309 216 205 307 495 433 321 270 389 729 449 82 66 -129 -46 -122 -47 191 152 30 -152 -275 -466 -635 -200 -108 1324 -743 -541 -327 -459 -173 -545 -718 -437 -339 -403 -213 -95 -18 -80 -46 -97 29 -25 -86 65 -44 -141 9 -227 -295 -353 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