File name: Pandora281s1_CambridgeBay_20250531_L2Fit_fwvt1c2d20240201p1-8.txt File generation date: 20250601T071048.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Kimberly Strong Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 281 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora281_OF_v3d20230823.txt Instrument calibration file used: Pandora281s1_CF_v2d20240201.txt Level 1 file used: Pandora281s1_CambridgeBay_20250531_L1_smca1c2d20240201p1-8.txt Full location name: Cambridge Bay, Nunavut: Canadian High Arctic Reseach Station Short location name: CambridgeBay Country of location: Canada Location latitude [deg]: 69.1212 Location longitude [deg]: -105.0398 Location altitude [m]: 10 Local noon date: 20250531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1161 492.2368 492.3574 492.4780 492.5986 492.7192 492.8398 492.9603 493.0808 493.2013 493.3218 493.4423 493.5628 493.6832 493.8036 493.9240 494.0444 494.1648 494.2852 494.4055 494.5258 494.6461 494.7664 494.8867 495.0069 495.1272 495.2474 495.3676 495.4878 495.6080 495.7281 495.8482 495.9684 496.0885 496.2086 496.3286 496.4487 496.5687 496.6887 496.8087 496.9287 497.0487 497.1686 497.2885 497.4085 497.5284 497.6482 497.7681 497.8879 498.0078 498.1276 498.2474 498.3672 498.4869 498.6067 498.7264 498.8461 498.9658 499.0855 499.2051 499.3247 499.4444 499.5640 499.6836 499.8031 499.9227 500.0422 500.1617 500.2812 500.4007 500.5202 500.6396 500.7591 500.8785 500.9979 501.1173 501.2366 501.3560 501.4753 501.5946 501.7139 501.8332 501.9525 502.0717 502.1909 502.3101 502.4293 502.5485 502.6677 502.7868 502.9059 503.0250 503.1441 503.2632 503.3822 503.5013 503.6203 503.7393 503.8583 503.9772 504.0962 504.2151 504.3340 504.4529 504.5718 504.6907 504.8095 504.9284 505.0472 505.1660 505.2847 505.4035 505.5222 505.6410 505.7597 505.8783 505.9970 506.1157 506.2343 506.3529 506.4715 506.5901 506.7087 506.8272 506.9458 507.0643 507.1828 507.3012 507.4197 507.5382 507.6566 507.7750 507.8934 508.0118 508.1301 508.2485 508.3668 508.4851 508.6034 508.7216 508.8399 508.9581 509.0763 509.1945 509.3127 509.4309 509.5490 509.6672 509.7853 509.9034 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250531T065919.2Z 9282.291194 2 1 31.71 2 88.92 0.33 79.75 304.79 0.00 1 0.00 1 0 29 6.575e-03 6.508e-03 4.013e-04 4.003e-04 1.496003e+04 2.881990e+01 1.015832e+03 -6.000000e+00 3.697806e+02 270.83 -2.00 20.00 -2.00 505.40 0.00e+00 2.448868e-03 1.112110e-05 1.515851e-04 -6.000000e+00 1.833404e-04 270.83 -2.00 20.00 -2.00 500.94 0.00e+00 1.622978e+00 8.133485e-03 1.162565e-01 -6.000000e+00 1.366684e-01 233.90 -2.00 4.87 -2.00 502.46 0.00e+00 18.472 0.190 489.00 513.00 1 3.3858e+00 6.2080e-04 3.9277e-02 -6.0000e+00 1.0457e-02 -3.1444e-02 1.5447e-04 3.5098e-03 -6.0000e+00 2.6926e-03 4.0151e-03 -8.1442e-04 4.3183e-05 1.2917e-04 -6.0000e+00 8.0644e-04 -9.3616e-05 -4.4832e-05 12 9 9 12 1 1 99.05 26.52 4.62 -0.00009 -0.00574 64 12 1 4 0 487.790 34.50 20.00 26.52 7.68 4.2 1100.00 -955 -544 47 372 692 1204 1407 1299 974 732 379 29 -297 -461 -493 -432 -128 198 338 205 240 350 483 767 796 579 406 -40 -645 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7.25 4.3 1100.00 -994 -480 79 393 739 1195 1444 1332 1043 722 366 -11 -375 -538 -515 -445 -193 200 284 195 327 466 512 728 770 603 453 22 -631 -928 -889 -765 -286 288 205 -89 -206 -188 -311 -278 -116 66 255 584 698 646 509 297 -189 -698 -1152 -1381 -1360 -1068 -531 -94 40 217 227 467 685 828 768 711 444 192 -51 -276 -471 -706 -762 -636 -559 -258 -177 -603 -895 -995 -994 -986 -879 -887 -863 -737 -424 -439 -590 -485 -259 21 331 703 999 875 691 442 63 -325 -872 -1361 -1621 -1434 -948 -369 -330 -520 -675 -783 -585 -134 136 221 467 798 1008 1287 1560 1495 1004 653 364 214 404 768 797 703 714 523 530 514 218 -201 -364 -552 -628 -321 -42 -158 46 329 345 351 439 408 439 231 -135 -524 -888 -819 -889 -436 72 369 697 1146 1377 1280 1003 691 348 -11 -357 -510 -490 -419 -184 194 277 192 324 455 503 717 761 597 447 22 -621 -899 -855 -741 -277 285 203 -90 -206 -187 -308 -276 -115 67 258 586 706 656 515 298 -191 -693 -1125 -1355 -1330 -1056 -524 -93 41 222 232 471 692 838 780 722 449 192 -52 -276 -468 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1.3023e-04 -6.0000e+00 9.1588e-04 -2.7254e-03 -5.2849e-05 12 8 8 10 0 0 98.79 26.52 5.58 -0.00273 -0.00369 253 27 1 4 0 213.760 34.75 20.00 26.52 7.06 4.4 1100.00 -1117 -620 -23 465 857 1328 1564 1476 1188 819 512 37 -378 -569 -580 -530 -226 194 354 241 327 487 628 763 819 638 474 -9 -663 -1054 -1021 -855 -369 233 217 -114 -158 -158 -305 -303 -135 61 293 578 753 707 523 297 -189 -737 -1180 -1440 -1502 -1118 -523 -99 77 252 342 568 758 880 840 774 520 211 -86 -278 -544 -794 -864 -760 -639 -318 -222 -661 -1011 -1107 -1108 -1135 -1007 -984 -886 -693 -508 -515 -642 -543 -291 -40 282 773 1004 926 746 469 75 -410 -929 -1458 -1802 -1530 -934 -347 -331 -569 -722 -834 -554 -173 130 248 572 937 1159 1442 1684 1609 1070 708 407 283 452 797 779 741 746 615 508 587 254 -191 -347 -587 -713 -349 -86 -160 68 330 437 381 516 482 457 246 -135 -595 -980 -959 -995 -561 -21 434 805 1269 1486 1414 1139 781 485 36 -360 -539 -550 -497 -215 189 343 237 318 475 615 751 810 632 467 -9 -641 -1021 -982 -829 -358 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0.00 1 0.00 1 0 15 2.463e-03 2.458e-03 6.306e-05 6.301e-05 2.180150e+03 3.787875e+00 1.566731e+02 -6.000000e+00 1.386579e+02 271.02 -2.00 20.00 -2.00 505.28 0.00e+00 6.949881e-04 1.725947e-06 3.898947e-05 -6.000000e+00 6.874734e-05 271.02 -2.00 20.00 -2.00 500.55 0.00e+00 5.713963e-01 1.296374e-03 2.109235e-02 -6.000000e+00 5.125570e-02 233.99 -2.00 4.87 -2.00 502.13 0.00e+00 5.285 0.004 489.00 513.00 1 6.1940e-02 9.9125e-05 7.8321e-03 -6.0000e+00 3.9215e-03 -1.7814e-03 2.5365e-05 6.3022e-04 -6.0000e+00 1.0110e-03 8.2304e-01 3.4823e-04 7.5217e-06 2.5028e-05 -6.0000e+00 3.0235e-04 -1.5308e-02 -3.7341e-05 10 0 0 10 0 0 -0.00 26.50 1.78 -0.01531 -0.01289 1875 201 1 4 0 3.160 34.50 20.01 26.50 12.30 4.2 1100.00 -332 -170 -43 -96 -50 267 447 376 292 248 197 28 -177 -204 -204 -255 -159 82 69 -157 -48 141 224 384 421 282 261 99 -186 -252 -59 -158 30 337 91 -280 -167 24 -67 -78 23 70 72 180 272 237 177 161 -27 -257 -421 -452 -512 -402 -151 -113 -171 -210 -119 63 296 355 275 225 212 112 42 26 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