File name: Pandora26s1_CambridgeMA_20210617_L2Fit_fout2c11d20210107p1-8.txt File generation date: 20241217T191852.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Kelly Chance Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v3d20191031.txt Instrument calibration file used: Pandora26s1_CF_v11d20210107.txt Level 1 file used: Pandora26s1_CambridgeMA_20210617_L1_smca1c11d20210107p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20210617 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 255 397 Nominal wavelengths inside fitting window [nm]: 305.0400 305.1807 305.3214 305.4621 305.6028 305.7434 305.8841 306.0247 306.1654 306.3060 306.4466 306.5872 306.7278 306.8684 307.0090 307.1495 307.2901 307.4306 307.5711 307.7116 307.8521 307.9926 308.1331 308.2736 308.4140 308.5545 308.6949 308.8353 308.9757 309.1161 309.2565 309.3969 309.5372 309.6776 309.8179 309.9583 310.0986 310.2389 310.3792 310.5195 310.6597 310.8000 310.9402 311.0805 311.2207 311.3609 311.5011 311.6413 311.7815 311.9217 312.0618 312.2020 312.3421 312.4822 312.6223 312.7624 312.9025 313.0426 313.1827 313.3227 313.4628 313.6028 313.7428 313.8828 314.0228 314.1628 314.3028 314.4427 314.5827 314.7226 314.8626 315.0025 315.1424 315.2823 315.4221 315.5620 315.7019 315.8417 315.9816 316.1214 316.2612 316.4010 316.5408 316.6806 316.8203 316.9601 317.0998 317.2396 317.3793 317.5190 317.6587 317.7984 317.9380 318.0777 318.2174 318.3570 318.4966 318.6362 318.7758 318.9154 319.0550 319.1946 319.3341 319.4737 319.6132 319.7528 319.8923 320.0318 320.1713 320.3107 320.4502 320.5896 320.7291 320.8685 321.0079 321.1473 321.2867 321.4261 321.5655 321.7049 321.8442 321.9835 322.1229 322.2622 322.4015 322.5408 322.6801 322.8193 322.9586 323.0978 323.2371 323.3763 323.5155 323.6547 323.7939 323.9330 324.0722 324.2114 324.3505 324.4896 324.6287 324.7678 324.9069 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210617T091621.2Z 7838.386356 46 1 50.00 2 89.39 58.15 126.29 340.58 0.00 1 0.00 1 0 102 1.741e+00 6.372e-01 5.999e-01 2.570e-01 -2.899682e-02 1.922864e-01 1.179217e-02 -6.000000e+00 1.443107e+00 232.94 -2.00 3.54 -2.00 312.73 0.00e+00 -2.672412e-02 1.460690e-02 3.913206e-03 -6.000000e+00 7.345119e-02 285.72 -2.00 20.00 -2.00 312.29 0.00e+00 19.392 0.139 302.00 328.00 3 -5.6756e+00 4.9680e-01 2.5111e-01 -6.0000e+00 3.6556e+00 1.6452e+00 5.6576e-01 1.3963e-01 -6.0000e+00 3.9132e+00 2.1903e-01 3.0375e-01 6.6369e-03 -6.0000e+00 2.2877e+00 6.0732e-02 1.0963e-01 4.3876e-02 -6.0000e+00 9.9041e-01 1.0328e-07 1.3166e-01 1.0990e-02 6.1361e-04 -6.0000e+00 7.2658e-02 -1.3600e-02 2.8649e-03 12 12 8 10 0 0 39.37 21.26 46.60 -0.01360 0.97576 20 4 1 5 0 2499.480 25.28 20.00 21.26 21.43 8.8 1012.17 900000 900000 900000 125481 161724 900000 900000 -30931 900000 900000 900000 11602 900000 900000 -22580 900000 61787 900000 303362 236940 900000 219674 900000 900000 900000 900000 900000 900000 170295 86661 900000 19128 900000 -35607 117935 900000 900000 900000 900000 900000 158981 900000 50369 479107 -21644 1054 900000 900000 900000 900000 900000 35550 900000 900000 900000 900000 91682 231132 72541 138776 197094 900000 900000 309736 130769 96204 900000 82916 900000 900000 900000 900000 900000 900000 900000 98186 900000 125919 900000 296161 900000 230755 -56934 900000 900000 85624 900000 900000 70007 54046 900000 130367 -33339 405832 122845 900000 53702 119190 900000 900000 900000 134018 39512 -9908 103802 577510 900000 -20147 83304 108591 -37492 -2279 900000 900000 104388 68026 72786 176019 900000 41816 182057 15918 900000 488694 900000 900000 900000 900000 8640 91073 70754 81170 12723 900000 -37355 47850 900000 -4740 84737 41725 277443 -22072 -26210 900000 900000 900000 52071 48109 900000 900000 -46596 900000 900000 900000 10085 900000 900000 -28149 900000 39007 900000 74183 57941 900000 53718 900000 900000 900000 900000 900000 900000 41643 31674 900000 17793 900000 -79380 68417 900000 900000 900000 900000 900000 50839 900000 39441 117159 -32999 1352 900000 900000 900000 900000 900000 41911 900000 900000 900000 900000 64549 56520 58285 52832 48197 900000 900000 75742 59595 64041 900000 63306 900000 900000 900000 900000 900000 900000 900000 54225 900000 60168 900000 72422 900000 56428 -189091 900000 900000 59959 900000 900000 48997 45956 900000 61102 -73724 99241 57219 900000 45657 56905 900000 900000 900000 66729 48977 -19759 71315 141223 900000 -36591 51787 49223 -66444 -3045 900000 900000 59459 54715 54916 46312 900000 34742 44520 15663 900000 119504 900000 900000 900000 900000 9673 48488 46282 48382 14356 900000 -63512 35688 900000 -5711 45428 35074 67845 -36221 -44788 SS 20210617T094122.2Z 7838.403729 66 1 51.83 2 85.38 62.26 127.59 347.79 0.00 1 0.00 1 0 70 9.248e-01 1.608e-01 4.170e-01 5.388e-02 1.364175e+00 4.227940e-02 2.828622e-02 -6.000000e+00 6.687638e-01 232.94 -2.00 3.54 -2.00 321.44 0.00e+00 1.168556e-01 1.640656e-02 2.032530e-02 -6.000000e+00 3.645197e-02 285.72 -2.00 20.00 -2.00 321.20 0.00e+00 10.379 0.021 302.00 328.00 3 -1.1582e+00 1.4214e-01 2.7983e-01 -6.0000e+00 1.6737e+00 4.8708e+00 1.5742e-01 3.8093e-01 -6.0000e+00 1.8291e+00 -3.2340e+00 7.3236e-02 3.5089e-02 -6.0000e+00 1.0999e+00 7.5934e-01 4.4310e-02 1.1121e-01 -6.0000e+00 4.7066e-01 1.6302e-06 -2.3439e-03 1.4337e-03 1.3145e-03 -6.0000e+00 3.5740e-02 1.3025e-02 1.8944e-06 12 8 8 10 0 0 -44.55 21.26 1.55 0.01303 -0.00459 21 4 1 5 0 2467.740 25.28 19.99 21.26 22.10 8.7 1015.28 209406 900000 900000 834 242003 166469 900000 136893 900000 900000 -127814 -95908 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -10643 900000 900000 900000 900000 900000 900000 900000 -40438 37367 108919 57936 900000 900000 900000 900000 900000 7753 314649 900000 6301 900000 900000 900000 900000 900000 4395 900000 900000 900000 900000 352898 900000 900000 32316 900000 900000 900000 900000 900000 260798 900000 162409 900000 900000 21560 900000 900000 41509 900000 900000 900000 -16207 198977 79442 900000 -27900 -28894 900000 900000 30083 77219 -11416 14541 11793 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