File name: Pandora26s1_CambridgeMA_20210713_L2Fit_fwvt1c11d20210107p1-8.txt File generation date: 20241217T193730.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c11p1-8 Local principal investigator: Kelly Chance Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v3d20191031.txt Instrument calibration file used: Pandora26s1_CF_v11d20210107.txt Level 1 file used: Pandora26s1_CambridgeMA_20210713_L1_smca1c11d20210107p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20210713 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1679 1828 Nominal wavelengths inside fitting window [nm]: 492.1164 492.2371 492.3578 492.4785 492.5991 492.7198 492.8404 492.9610 493.0816 493.2022 493.3228 493.4433 493.5639 493.6844 493.8049 493.9254 494.0458 494.1663 494.2867 494.4071 494.5275 494.6479 494.7682 494.8886 495.0089 495.1292 495.2495 495.3698 495.4901 495.6103 495.7306 495.8508 495.9710 496.0911 496.2113 496.3314 496.4516 496.5717 496.6918 496.8119 496.9319 497.0520 497.1720 497.2920 497.4120 497.5320 497.6519 497.7719 497.8918 498.0117 498.1316 498.2515 498.3713 498.4912 498.6110 498.7308 498.8506 498.9704 499.0901 499.2099 499.3296 499.4493 499.5690 499.6887 499.8083 499.9280 500.0476 500.1672 500.2868 500.4064 500.5259 500.6455 500.7650 500.8845 501.0040 501.1235 501.2429 501.3623 501.4818 501.6012 501.7206 501.8399 501.9593 502.0786 502.1979 502.3172 502.4365 502.5558 502.6750 502.7943 502.9135 503.0327 503.1519 503.2710 503.3902 503.5093 503.6284 503.7475 503.8666 503.9857 504.1047 504.2237 504.3428 504.4618 504.5807 504.6997 504.8186 504.9376 505.0565 505.1754 505.2943 505.4131 505.5320 505.6508 505.7696 505.8884 506.0072 506.1259 506.2447 506.3634 506.4821 506.6008 506.7194 506.8381 506.9567 507.0754 507.1940 507.3125 507.4311 507.5497 507.6682 507.7867 507.9052 508.0237 508.1422 508.2606 508.3791 508.4975 508.6159 508.7342 508.8526 508.9710 509.0893 509.2076 509.3259 509.4442 509.5624 509.6807 509.7989 509.9171 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210713T093601.8Z 7864.400020 57 1 51.12 2 88.20 61.75 116.31 31.99 0.00 1 0.00 1 0 46 1.570e-01 1.326e-01 3.357e-02 3.179e-02 2.555384e+04 2.610648e+03 1.787809e+03 -6.000000e+00 8.762594e+03 288.12 -2.00 20.00 -2.00 505.31 0.00e+00 -1.798065e-03 8.938752e-04 3.837903e-05 -6.000000e+00 4.428941e-03 288.12 -2.00 20.00 -2.00 500.14 0.00e+00 1.496202e-01 6.400786e-01 5.011854e-02 -6.000000e+00 3.100927e+00 233.00 -2.00 3.54 -2.00 501.75 0.00e+00 16.459 0.085 489.00 513.00 1 1.0758e+01 4.8802e-02 2.6911e-02 -6.0000e+00 2.3770e-01 1.0759e-01 1.2671e-02 2.6613e-03 -6.0000e+00 6.2184e-02 3.8228e-06 -1.0989e-02 2.4946e-03 1.6378e-04 -6.0000e+00 1.5117e-02 -4.1537e-02 3.4897e-04 12 9 8 11 32 0 46.23 21.85 22.03 -0.04154 -0.11776 15 3 1 4 0 3407.000 25.68 20.00 21.85 25.61 9.3 1033.54 8153 33373 -4067 -10085 188 -7380 1637 11686 17447 8529 -5345 11165 -10840 8920 -22199 -601 18854 -9560 13461 3759 1592 25171 14251 -7432 23648 -6281 14967 -20981 18448 5999 2723 -13188 -264 30044 -13875 27431 4042 6113 4573 458 -8022 -12399 -148 -7964 -15665 -4471 -2692 -11166 -9240 -9106 -5910 -8612 -641 32026 -17732 4853 -2162 13565 13787 -8253 -9981 23839 18032 -12902 5466 21929 365 11399 -4510 26501 17116 7836 -26511 11984 8271 -2318 26044 18457 11438 -1037 19336 15982 11944 11151 -6516 3012 -26977 5768 31212 3516 11692 13074 -12341 -10077 -5988 -3370 13582 -81 -1978 21698 -1276 -16280 -1095 13489 6113 8117 15776 -6809 21604 -18424 -4123 -9054 8564 -1749 -10702 -10037 10662 -18719 -2507 -12237 -15266 23518 3300 21107 14731 3793 -7906 4418 5941 -7586 17141 -18925 9304 4827 15660 33520 4479 -9887 -88 -6420 94603 2984 -385 9786 -2163 -7527 -618 236 2995 9461 7312 23768 -4237 -11457 199 -8575 1773 11734 16537 8745 -6147 10896 -12803 8610 -28434 -633 16760 -11277 13121 4105 1787 22634 14115 -9040 21678 -7589 14740 -28596 17114 6019 2776 -15452 -279 24768 -17727 24070 4398 6434 4825 492 -9346 -15159 -164 -9486 -20093 -5202 -3060 -13651 -10890 -10442 -6351 -9248 -635 23494 -21107 4809 -2329 12803 13007 -9552 -11727 20543 16350 -15567 5514 18728 376 10488 -4744 20619 14320 7224 -33613 10826 7732 -2405 20517 15182 9909 -992 15224 13116 10186 9682 -6781 2895 -34321 5439 22860 3340 10258 11394 -13601 -10833 -5960 -3154 10346 -67 -1622 14178 -1027 -15456 -950 10777 5512 7441 13572 -7212 17403 -21333 -4223 -9803 7842 -1746 -11637 -10853 9609 -22610 -2635 -13913 -17509 18222 3020 16201 12086 3447 -8116 4021 5304 -7720 13684 -20814 7692 4167 12315 22603 4043 -10405 -85 -6745 39021 2937 -395 9097 -2261 -8143 -623 232 2825 8326 SQ 20210713T095549.5Z 7864.413767 69 1 52.01 2 84.93 64.99 114.39 36.58 0.00 1 0.00 1 0 15 9.693e-02 9.240e-02 2.267e-02 2.208e-02 2.392569e+04 1.781261e+03 1.756458e+03 -6.000000e+00 5.407142e+03 288.13 -2.00 20.00 -2.00 505.24 0.00e+00 -1.880902e-03 6.065645e-04 6.582904e-05 -6.000000e+00 2.737168e-03 288.13 -2.00 20.00 -2.00 500.00 0.00e+00 -1.464386e+00 4.467717e-01 7.190715e-02 -6.000000e+00 1.924238e+00 233.00 -2.00 3.54 -2.00 501.62 0.00e+00 9.694 0.017 489.00 513.00 1 1.1430e+01 3.3880e-02 1.5731e-02 -6.0000e+00 1.4732e-01 1.0601e-01 8.9187e-03 2.6167e-03 -6.0000e+00 3.8828e-02 5.8577e-06 -4.5793e-03 1.7481e-03 1.4949e-04 -6.0000e+00 9.3393e-03 4.8773e-02 -6.1889e-04 12 9 8 11 32 0 99.25 21.85 -0.62 0.04877 0.01701 20 4 1 4 0 2599.400 25.68 20.00 21.85 25.51 9.2 1031.37 8467 18287 -8194 -9120 2973 -1279 5330 3923 10659 9161 -5873 1423 -3832 2622 -11552 -2886 8445 -20 8806 2941 2239 1412 1946 21748 7391 -9044 8500 -1089 -4295 74 69 -3883 -2218 12123 -10943 13896 2159 6222 2204 724 271 -4277 -9661 -5875 -13939 1613 -4280 -1582 -12617 -8046 1541 -2139 921 13573 -12822 -4437 -3339 16337 2976 -12157 288 13451 8820 -8614 9691 -8010 -5688 -2539 -9050 -706 8431 4973 5874 -1335 9439 -1676 19506 9699 6348 -112 2452 14078 -963 25182 -5464 7044 -17355 5137 15826 -20079 1390 21864 -6355 -4001 -852 2930 7021 769 -4028 15777 -7256 -8931 942 2572 -1639 -11239 10134 -2996 7765 -26775 -4107 526 8510 -3839 17201 -11860 6614 3510 5878 17999 -4131 8767 -10197 12844 14502 -473 10835 4045 5437 -9717 -3456 -18882 4587 -3830 4037 10185 4325 -6712 -1006 -7933 38949 5646 -1743 4246 17642 -5026 9093 -4658 641 -2102 7711 15213 -8917 -10403 3130 -1415 5627 4251 10929 9428 -6849 1525 -4250 2679 -13357 -3116 8351 -21 8992 3237 2495 1569 2148 20185 7844 -11040 8884 -1224 -4856 78 72 -4155 -2364 11671 -13405 13640 2367 6468 2353 775 290 -4752 -11416 -6749 -17297 1761 -4871 -1732 -15165 -9007 1535 -2149 884 11644 -14272 -4682 -3576 14947 3082 -14237 301 12514 8639 -9808 9358 -9001 -6145 -2620 -9837 -695 7598 4656 5507 -1343 8721 -1709 16269 8638 5741 -105 2239 11676 -927 19308 -5573 6524 -20137 4850 13468 -23477 1346 17590 -6652 -4050 -819 2594 5765 644 -3396 11005 -6214 -7957 796 2272 -1583 -12258 9273 -3072 7052 -33364 -4160 518 7728 -3878 14360 -12915 6122 3418 5657 15435 -4227 7765 -10516 10645 11835 -444 9120 3651 4819 -9845 -3267 -20232 3913 -3494 3448 8257 3756 -6572 -956 -8105 26218 5234 -1732 4032 14795 -5124 8040 -4588 596 -1968 SQ 20210713T103728.4Z 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