File name: Pandora26s1_CambridgeMA_20220718_L2Fit_fwvt1c11d20210107p1-8.txt File generation date: 20241217T221951.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c11p1-8 Local principal investigator: Kelly Chance Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v4d20191031.txt Instrument calibration file used: Pandora26s1_CF_v11d20210107.txt Level 1 file used: Pandora26s1_CambridgeMA_20220718_L1_smca1c11d20210107p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20220718 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1679 1828 Nominal wavelengths inside fitting window [nm]: 492.1164 492.2371 492.3578 492.4785 492.5991 492.7198 492.8404 492.9610 493.0816 493.2022 493.3228 493.4433 493.5639 493.6844 493.8049 493.9254 494.0458 494.1663 494.2867 494.4071 494.5275 494.6479 494.7682 494.8886 495.0089 495.1292 495.2495 495.3698 495.4901 495.6103 495.7306 495.8508 495.9710 496.0911 496.2113 496.3314 496.4516 496.5717 496.6918 496.8119 496.9319 497.0520 497.1720 497.2920 497.4120 497.5320 497.6519 497.7719 497.8918 498.0117 498.1316 498.2515 498.3713 498.4912 498.6110 498.7308 498.8506 498.9704 499.0901 499.2099 499.3296 499.4493 499.5690 499.6887 499.8083 499.9280 500.0476 500.1672 500.2868 500.4064 500.5259 500.6455 500.7650 500.8845 501.0040 501.1235 501.2429 501.3623 501.4818 501.6012 501.7206 501.8399 501.9593 502.0786 502.1979 502.3172 502.4365 502.5558 502.6750 502.7943 502.9135 503.0327 503.1519 503.2710 503.3902 503.5093 503.6284 503.7475 503.8666 503.9857 504.1047 504.2237 504.3428 504.4618 504.5807 504.6997 504.8186 504.9376 505.0565 505.1754 505.2943 505.4131 505.5320 505.6508 505.7696 505.8884 506.0072 506.1259 506.2447 506.3634 506.4821 506.6008 506.7194 506.8381 506.9567 507.0754 507.1940 507.3125 507.4311 507.5497 507.6682 507.7867 507.9052 508.0237 508.1422 508.2606 508.3791 508.4975 508.6159 508.7342 508.8526 508.9710 509.0893 509.2076 509.3259 509.4442 509.5624 509.6807 509.7989 509.9171 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220718T092631.7Z 8234.393422 174 1 51.51 2 90.36 60.62 47.48 188.35 0.00 1 0.00 1 0 46 2.537e-01 1.947e-01 1.876e-02 1.691e-02 -5.707673e+03 1.008548e+03 3.365101e+02 -6.000000e+00 1.418387e+04 288.42 -2.00 20.00 -2.00 505.36 0.00e+00 5.095880e-03 4.808585e-04 1.648623e-04 -6.000000e+00 7.173620e-03 288.42 -2.00 20.00 -2.00 500.31 0.00e+00 1.084878e+01 3.398659e-01 4.774636e-02 -6.000000e+00 5.034973e+00 232.92 -2.00 3.54 -2.00 501.95 0.00e+00 20.523 0.164 489.00 513.00 1 8.6357e+00 2.6473e-02 3.7838e-02 -6.0000e+00 3.8555e-01 -6.5720e-02 6.5202e-03 2.2463e-03 -6.0000e+00 1.0163e-01 7.5554e-06 2.7705e-02 1.5499e-03 6.9325e-05 -6.0000e+00 2.4456e-02 -1.3625e-01 1.4534e-03 12 9 9 12 40 32 12.90 22.38 7.34 -0.13625 0.05593 16 3 1 4 0 3218.680 -99.00 20.00 22.38 29.60 15.1 1064.15 -36467 10457 70603 8609 2744 66349 21621 34330 2599 -19709 2225 17170 26097 4152 36684 12145 -8059 5603 5969 -8161 -28774 13605 -3322 -2933 5810 2364 -1592 5045 -5120 5153 12605 -15434 11030 14999 238 -30309 -934 4767 19232 -4449 9640 9378 -4454 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-34 -9622 -48739 -16653 729 -1097 22716 -6740 5677 -5995 -680 5925 563 7462 -2716 5066 6352 -941 2644 -7041 9256 -2046 5214 -18070 12430 6371 -8189 4907 470 9332 -2023 1610 3212 8384 2965 8102 11938 32630 205 17096 -18060 -9106 -3607 4365 23911 -29898 -16558 -14558 40302 2289 -13962 -412 380 761 36050 -16582 -2405 -4540 25053 3169 -32092 -551 24738 -4410 5609 30064 37697 36921 -28487 14574 19533 32956 -27559 34356 -19807 -49642 36122 7656 2136 11711 10196 10876 900000 SQ 20220718T093420.5Z 8234.398848 186 1 52.18 2 89.10 61.93 47.68 190.93 0.00 1 0.00 1 0 22 1.945e-02 1.922e-02 1.232e-03 1.227e-03 1.685048e+04 8.616961e+01 1.018957e+03 -6.000000e+00 1.086624e+03 288.42 -2.00 20.00 -2.00 505.43 0.00e+00 4.514175e-03 3.439824e-05 2.577458e-04 -6.000000e+00 5.491922e-04 288.42 -2.00 20.00 -2.00 501.11 0.00e+00 5.524722e-01 2.341058e-02 1.296883e-01 -6.000000e+00 3.844549e-01 232.92 -2.00 3.54 -2.00 502.59 0.00e+00 18.711 0.125 489.00 513.00 1 6.1307e+00 1.7871e-03 3.4369e-02 -6.0000e+00 2.9467e-02 -2.5816e-02 4.5470e-04 3.3683e-03 -6.0000e+00 7.7202e-03 2.6348e-04 1.8618e-03 1.0642e-04 1.3511e-04 -6.0000e+00 1.8741e-03 2.9918e-02 -1.7027e-04 12 9 8 11 32 0 84.87 22.38 13.43 0.02992 0.04283 19 3 1 4 0 2745.900 26.21 20.00 22.38 29.74 15.1 1063.92 -5051 -3608 -1105 -67 1452 2110 3130 2975 2021 1447 276 -743 -1716 -2005 -2386 -1666 -558 814 1913 1397 1306 1447 1332 2061 2041 1258 1915 74 -2278 -3197 -3236 -2770 -1151 496 1541 1352 228 549 -590 -456 175 615 1691 1744 2720 2709 2007 1334 -204 -1493 -3112 -3614 -3350 -1757 -647 1099 1448 2056 1831 2130 1448 2870 1999 2290 1336 711 -493 -927 -1878 -2155 -2301 -1756 -547 -1227 -491 -1255 -1939 -2796 -3277 -3589 -2535 -2062 -2139 -1778 -1414 -926 -1236 -1437 -1272 -255 -372 1286 1848 2123 1344 1200 194 -1439 -3065 -3127 -3334 -3009 -1173 224 1144 336 -559 -1523 -1101 -727 254 716 1915 2599 3665 3578 4211 3724 2358 1318 660 142 944 1781 2259 1631 2062 1217 1196 879 155 -1094 -1469 -2301 -2077 -1173 -718 256 706 793 857 651 1161 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