File name: Pandora26s1_CambridgeMA_20240506_L2Fit_fout2c7d20230915p1-8.txt File generation date: 20241010T173830.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20240506_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240506 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.1176 305.2583 305.3991 305.5398 305.6805 305.8212 305.9619 306.1026 306.2432 306.3839 306.5245 306.6651 306.8057 306.9464 307.0869 307.2275 307.3681 307.5087 307.6492 307.7897 307.9303 308.0708 308.2113 308.3518 308.4923 308.6327 308.7732 308.9136 309.0541 309.1945 309.3349 309.4753 309.6157 309.7561 309.8964 310.0368 310.1771 310.3175 310.4578 310.5981 310.7384 310.8787 311.0189 311.1592 311.2995 311.4397 311.5799 311.7201 311.8604 312.0005 312.1407 312.2809 312.4211 312.5612 312.7013 312.8415 312.9816 313.1217 313.2618 313.4019 313.5419 313.6820 313.8220 313.9621 314.1021 314.2421 314.3821 314.5221 314.6621 314.8020 314.9420 315.0819 315.2219 315.3618 315.5017 315.6416 315.7815 315.9213 316.0612 316.2010 316.3409 316.4807 316.6205 316.7603 316.9001 317.0399 317.1797 317.3194 317.4592 317.5989 317.7386 317.8783 318.0180 318.1577 318.2974 318.4371 318.5767 318.7164 318.8560 318.9956 319.1352 319.2748 319.4144 319.5540 319.6935 319.8331 319.9726 320.1122 320.2517 320.3912 320.5307 320.6702 320.8096 320.9491 321.0885 321.2280 321.3674 321.5068 321.6462 321.7856 321.9250 322.0643 322.2037 322.3430 322.4823 322.6217 322.7610 322.9003 323.0395 323.1788 323.3181 323.4573 323.5965 323.7358 323.8750 324.0142 324.1534 324.2926 324.4317 324.5709 324.7100 324.8491 324.9883 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240506T110631.2Z 8892.462861 94 1 54.31 2 74.18 81.56 63.14 102.66 0.00 1 0.00 1 0 17 1.432e-01 6.174e-03 1.634e-02 9.334e-04 5.481337e-01 4.958252e-04 6.304608e-03 -6.000000e+00 8.643475e-02 230.31 -2.00 3.54 -2.00 319.61 0.00e+00 1.414684e-03 1.467817e-04 5.717779e-04 -6.000000e+00 3.810963e-03 281.50 -2.00 20.00 -2.00 318.94 0.00e+00 3.604 0.001 302.00 328.00 3 1.9548e+00 1.4187e-03 4.6232e-02 -6.0000e+00 2.1584e-01 5.2735e-02 1.6785e-03 2.8913e-02 -6.0000e+00 2.3397e-01 -4.3856e-02 1.3611e-03 1.4380e-02 -6.0000e+00 1.3904e-01 1.0498e-02 7.0394e-04 4.3499e-03 -6.0000e+00 5.7480e-02 1.0750e-03 -2.0530e-04 2.8087e-05 5.3505e-05 -6.0000e+00 4.4792e-03 -1.0056e-02 0.0000e+00 10 0 0 10 0 0 99.99 25.53 0.30 -0.01006 -0.01160 482 51 1 5 0 112.660 34.50 19.99 25.53 19.21 3.4 962.61 -65776 -34311 -44274 -48772 -59951 -62110 -56968 -50439 -21323 -33958 -11665 -32941 -21674 -11503 -15165 -11862 4955 -6264 9502 4015 710 -8414 1672 -1450 -7848 -4763 -12723 -8509 -9217 -8828 -6396 -356 -6459 -3065 -8591 -2208 -4278 -2958 824 -2851 -2876 382 934 950 -423 2687 383 1164 55 946 533 2850 2523 2225 1160 2012 -129 326 768 1165 1142 1890 1561 1428 2217 -367 460 293 764 1325 393 296 800 -89 96 48 -157 -497 -614 -120 -891 -1311 -1951 -1543 -1212 -499 -138 186 521 244 79 413 184 125 176 -61 82 241 -275 -585 -575 -919 -385 -147 -789 -1022 -623 -450 70 401 212 118 161 160 280 341 687 284 35 -140 -86 -27 427 171 422 499 220 985 589 82 -26 -156 -132 -31 33 84 -162 65 -148 -53 -123 -309 -361 -1180 -503 -742 -826 -1086 -1170 -1120 -1051 -369 -717 -213 -861 -619 -366 -603 -526 206 -318 439 205 39 -513 98 -94 -583 -357 -1032 -648 -714 -738 -600 -36 -771 -365 -1071 -268 -596 -486 157 -595 -664 91 230 239 -109 684 101 313 15 284 177 1014 979 851 471 840 -56 140 323 490 505 911 837 764 1198 -199 245 163 466 902 271 210 556 -63 63 28 -88 -288 -396 -83 -710 -1094 -1772 -1487 -1166 -505 -146 199 550 247 80 389 168 119 173 -68 98 303 -365 -767 -704 -1097 -435 -169 -972 -1259 -809 -623 100 590 336 192 259 245 425 501 1017 442 55 -226 -138 -42 673 259 610 694 318 1407 929 135 -45 -279 -237 -58 63 169 -332 128 -304 -105 -241 -579 -670 SS 20240506T111847.9Z 8892.471388 97 1 54.29 2 71.93 83.53 60.96 104.89 0.00 1 0.00 1 0 17 6.265e-02 5.876e-03 2.941e-03 3.824e-04 4.833746e-01 2.014285e-04 5.621948e-03 -6.000000e+00 3.781017e-02 230.31 -2.00 3.54 -2.00 318.55 0.00e+00 1.036455e-03 4.231236e-05 2.543777e-04 -6.000000e+00 1.666878e-03 281.50 -2.00 20.00 -2.00 317.83 0.00e+00 3.181 0.001 302.00 328.00 3 8.3013e-01 5.5006e-04 4.0661e-02 -6.0000e+00 9.4420e-02 3.2951e-02 6.2658e-04 2.5210e-02 -6.0000e+00 1.0235e-01 -3.8146e-02 4.2700e-04 1.2334e-02 -6.0000e+00 6.0818e-02 1.1386e-02 2.2025e-04 3.5878e-03 -6.0000e+00 2.5147e-02 5.3932e-03 -7.5105e-05 1.1595e-05 4.2786e-05 -6.0000e+00 1.9591e-03 -1.0814e-02 0.0000e+00 10 0 0 10 0 0 99.87 25.55 0.27 -0.01081 -0.01138 737 77 1 5 0 73.650 34.75 20.08 25.55 19.30 3.4 963.30 -24543 -19464 -18467 -23426 -26533 -27802 -25379 -18152 -13568 -16311 -11509 -13412 -8834 -6781 -3935 -2402 -219 -163 2438 1740 377 -1343 765 -324 -1793 -1402 -3250 -2998 -2642 -1318 -244 725 -410 -1573 -3179 -1578 -1613 -279 713 -239 -709 198 584 430 508 890 187 448 276 856 870 1494 1555 1471 770 1098 457 193 432 949 1242 1809 1432 1306 615 -41 339 5 958 824 -88 62 -156 -90 -250 -422 -315 -782 -477 -581 -1170 -1392 -1877 -1502 -961 -684 -207 41 213 173 300 502 244 397 339 96 119 190 -321 -589 -576 -724 -165 100 -592 -1019 -531 -461 -13 251 159 111 140 219 251 561 691 356 175 -118 -266 68 372 269 543 614 346 1043 617 153 7 -180 -71 -21 37 -58 -150 66 -133 -163 -104 -444 -498 -892 -744 -716 -916 -1016 -1091 -1062 -796 -627 -827 -593 -797 -602 -548 -366 -227 -22 -18 275 206 46 -171 101 -46 -277 -223 -525 -469 -411 -215 -44 148 -85 -339 -685 -345 -397 -74 225 -82 -269 79 240 180 215 379 81 182 116 379 419 731 822 829 431 632 269 113 249 547 749 1119 978 906 433 -28 227 3 724 662 -73 54 -132 -72 -193 -313 -220 -557 -354 -472 -1038 -1317 -1845 -1564 -1021 -740 -233 47 241 187 314 509 238 398 357 110 143 245 -420 -786 -720 -864 -194 120 -737 -1299 -712 -635 -18 377 247 173 218 323 360 799 993 520 263 -183 -415 102 560 389 773 867 480 1497 909 240 12 -299 -120 -37 65 -107 -277 124 -249 -301 -188 -770 -878 SS 20240506T112517.4Z 8892.475896 101 1 3.03 2 70.74 84.59 59.81 106.11 0.00 1 0.00 1 0 17 5.102e-02 5.978e-03 1.233e-02 1.989e-03 4.567224e-01 1.048587e-03 5.332071e-03 -6.000000e+00 3.079415e-02 230.31 -2.00 3.54 -2.00 318.31 0.00e+00 8.722062e-04 2.024067e-04 2.396650e-04 -6.000000e+00 1.357463e-03 281.50 -2.00 20.00 -2.00 317.58 0.00e+00 2.996 0.000 302.00 328.00 3 1.4066e+00 2.8385e-03 3.8319e-02 -6.0000e+00 7.6900e-02 3.3094e-02 3.2187e-03 2.3757e-02 -6.0000e+00 8.3352e-02 -3.6061e-02 2.1056e-03 1.1609e-02 -6.0000e+00 4.9532e-02 1.1895e-02 1.0751e-03 3.3246e-03 -6.0000e+00 2.0482e-02 3.7297e-03 -1.9618e-05 6.0604e-05 3.9621e-05 -6.0000e+00 1.5954e-03 -1.1317e-02 0.0000e+00 12 1 1 12 1 1 95.74 25.56 0.29 -0.01132 -0.01146 22 43 1 5 0 131.380 34.50 19.98 25.56 20.08 3.4 967.74 -20764 -7837 -18984 -22382 -23177 -20331 -18366 -12164 -3236 -16261 -11282 -9997 -7608 -3033 -7515 -1428 -421 939 3759 2252 -859 -699 3572 1868 -177 -2807 -2485 -2434 -1263 -1469 -552 1832 -94 -1202 -1547 -1735 -1586 993 1309 -351 -812 -668 173 440 261 1561 133 372 207 702 593 1132 1692 1141 621 1579 996 590 673 607 1282 1802 1412 730 537 -342 675 89 838 979 -98 -406 -20 -27 -449 -417 -876 -958 -500 -387 -1042 -1197 -2145 -1494 -1051 -415 -74 12 496 64 34 202 60 337 305 -81 88 36 -423 -539 -588 -555 -164 185 -284 -1023 -386 -533 -61 242 345 238 198 309 340 316 722 211 212 36 -337 243 355 161 640 562 409 736 594 208 52 -33 -51 -87 -1 -194 -175 154 -170 -358 -15 -430 -426 -975 -356 -983 -1146 -1133 -974 -941 -658 -176 -1073 -751 -737 -651 -298 -824 -166 -53 125 514 325 -131 -108 557 318 -33 -549 -481 -456 -232 -286 -109 398 -23 -300 -380 -441 -416 301 440 -138 -330 -287 76 196 118 699 61 171 97 325 298 616 929 670 361 939 605 357 401 364 800 1155 997 525 390 -241 484 62 643 797 -83 -356 -17 -23 -354 -314 -655 -687 -391 -329 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