File name: Pandora26s1_CambridgeMA_20240509_L2Fit_fout2c7d20230915p1-8.txt File generation date: 20241010T184844.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20240509_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.1176 305.2583 305.3991 305.5398 305.6805 305.8212 305.9619 306.1026 306.2432 306.3839 306.5245 306.6651 306.8057 306.9464 307.0869 307.2275 307.3681 307.5087 307.6492 307.7897 307.9303 308.0708 308.2113 308.3518 308.4923 308.6327 308.7732 308.9136 309.0541 309.1945 309.3349 309.4753 309.6157 309.7561 309.8964 310.0368 310.1771 310.3175 310.4578 310.5981 310.7384 310.8787 311.0189 311.1592 311.2995 311.4397 311.5799 311.7201 311.8604 312.0005 312.1407 312.2809 312.4211 312.5612 312.7013 312.8415 312.9816 313.1217 313.2618 313.4019 313.5419 313.6820 313.8220 313.9621 314.1021 314.2421 314.3821 314.5221 314.6621 314.8020 314.9420 315.0819 315.2219 315.3618 315.5017 315.6416 315.7815 315.9213 316.0612 316.2010 316.3409 316.4807 316.6205 316.7603 316.9001 317.0399 317.1797 317.3194 317.4592 317.5989 317.7386 317.8783 318.0180 318.1577 318.2974 318.4371 318.5767 318.7164 318.8560 318.9956 319.1352 319.2748 319.4144 319.5540 319.6935 319.8331 319.9726 320.1122 320.2517 320.3912 320.5307 320.6702 320.8096 320.9491 321.0885 321.2280 321.3674 321.5068 321.6462 321.7856 321.9250 322.0643 322.2037 322.3430 322.4823 322.6217 322.7610 322.9003 323.0395 323.1788 323.3181 323.4573 323.5965 323.7358 323.8750 324.0142 324.1534 324.2926 324.4317 324.5709 324.7100 324.8491 324.9883 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240509T102144.0Z 8895.431759 55 1 54.38 2 81.70 73.78 88.67 57.02 0.00 1 0.00 1 0 17 7.615e-01 1.702e-02 1.676e-01 2.084e-03 9.467458e-01 1.196014e-03 1.048809e-02 -6.000000e+00 4.625825e-01 230.57 -2.00 3.54 -2.00 321.63 0.00e+00 7.445049e-03 6.607234e-04 2.818336e-03 -6.000000e+00 2.132804e-02 281.83 -2.00 20.00 -2.00 321.13 0.00e+00 6.505 0.005 302.00 328.00 3 2.1313e-01 4.3494e-03 8.3380e-02 -6.0000e+00 1.1595e+00 5.1688e-01 6.3882e-03 5.3412e-02 -6.0000e+00 1.2593e+00 -6.6500e-01 6.6459e-03 3.0970e-02 -6.0000e+00 7.4483e-01 2.6529e-01 3.0224e-03 1.3630e-02 -6.0000e+00 3.0918e-01 2.4915e-04 -5.4108e-04 5.4173e-05 2.1491e-04 -6.0000e+00 2.4164e-02 -1.2854e-02 0.0000e+00 12 8 8 10 0 0 33.68 25.78 0.31 -0.01285 -0.01692 211 22 1 5 0 257.710 34.75 20.00 25.78 20.92 3.3 970.88 900000 -127570 -133682 900000 -305897 -310728 -289695 -235056 900000 -238845 199537 -162843 -134918 -96525 -132020 38059 -10897 -42507 900000 362514 -63503 -128793 45401 2018 -104584 -44037 -86437 -80011 -74636 -101692 -76346 -27391 -64167 25580 -59837 5517 -34540 -3123 24295 -23708 -27282 33685 27015 22322 -6402 72741 30988 19424 9216 14704 -3089 46060 29214 24639 17099 22827 -2015 5813 7417 13054 997 7474 4394 11349 27480 2673 4171 4528 6326 12326 4635 5127 10003 6282 -1210 1204 1067 2207 -1404 4305 1960 -727 509 -1828 -1373 997 785 2331 2171 468 -579 185 -1129 -2622 -2348 -2313 -879 -667 -238 -1022 -1795 -2196 -1591 -1517 -1701 -1787 -1880 -2041 14 -118 -526 -427 -85 -265 -111 -233 433 182 80 434 943 693 1511 1538 1100 949 355 1007 1070 251 468 345 79 -262 289 -56 -42 217 10 -87 -202 -873 -1234 900000 -447 -518 900000 -5985 -6309 -5026 -2560 900000 -3130 405 -1413 -1195 -784 -1974 139 -75 -449 900000 736 -915 -3583 230 17 -2654 -626 -1878 -1641 -1561 -3324 -2449 -662 -2567 436 -2369 117 -1213 -95 676 -1242 -1651 1190 1070 952 -373 1994 1359 1029 593 1003 -287 2955 2462 2366 1878 2456 -281 735 895 1479 135 1067 749 2042 4497 576 923 1084 1681 3172 1391 1564 2805 1685 -315 308 269 598 -424 1490 824 -361 275 -993 -789 589 483 1434 1318 277 -327 109 -685 -1628 -1700 -1997 -817 -710 -252 -1087 -1929 -2129 -1411 -1342 -1585 -1765 -1995 -2218 16 -164 -773 -673 -137 -421 -171 -354 667 294 127 689 1536 1075 2228 2186 1519 1371 486 1497 1726 470 922 700 173 -587 686 -139 -105 548 25 -205 -463 -1885 -2615 SS 20240509T103753.7Z 8895.442983 60 1 54.29 2 78.81 76.37 86.20 59.52 0.00 1 0.00 1 0 25 4.975e-01 9.709e-03 2.294e-02 7.971e-04 7.533356e-01 4.339477e-04 8.547723e-03 -6.000000e+00 3.006571e-01 230.57 -2.00 3.54 -2.00 320.49 0.00e+00 2.917403e-03 1.730627e-04 2.078757e-03 -6.000000e+00 1.325396e-02 281.83 -2.00 20.00 -2.00 319.89 0.00e+00 4.975 0.002 302.00 328.00 3 1.7999e-01 1.3265e-03 6.4161e-02 -6.0000e+00 7.5121e-01 1.4310e-01 1.7059e-03 4.1042e-02 -6.0000e+00 8.1395e-01 -1.6998e-01 1.6257e-03 2.1711e-02 -6.0000e+00 4.8368e-01 6.3007e-02 8.0180e-04 7.2008e-03 -6.0000e+00 2.0004e-01 1.3835e-03 -9.5814e-05 2.1809e-05 1.0037e-04 -6.0000e+00 1.5558e-02 -1.3557e-02 0.0000e+00 12 8 8 10 0 0 26.60 25.76 0.29 -0.01356 -0.01428 526 55 1 5 0 103.200 34.75 20.01 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-343 -540 340 541 400 116 879 328 494 282 452 339 1360 1155 1051 927 1118 250 468 452 458 469 946 1025 1414 1759 381 728 397 1086 1328 833 806 938 424 -291 -43 -283 -250 -362 -93 -550 -806 -1392 -1520 -1138 -668 -250 -48 273 217 -92 -207 -563 -624 -591 -697 -216 38 -342 -830 -828 -1049 -782 -314 -1015 -1346 -741 -797 153 567 390 343 164 433 248 498 874 438 272 97 72 456 1119 785 728 659 447 1515 863 162 249 -462 -255 -163 185 -201 -262 72 -182 -196 -47 -814 -1013 SS 20240509T104424.7Z 8895.447508 63 1 54.33 2 77.64 77.41 85.19 60.51 0.00 1 0.00 1 0 25 3.717e-01 8.451e-03 1.613e-02 6.543e-04 6.953462e-01 3.520520e-04 7.902026e-03 -6.000000e+00 2.245750e-01 230.57 -2.00 3.54 -2.00 320.16 0.00e+00 2.162029e-03 1.263086e-04 1.356578e-03 -6.000000e+00 9.901546e-03 281.83 -2.00 20.00 -2.00 319.53 0.00e+00 4.538 0.002 302.00 328.00 3 2.8865e-01 1.0444e-03 5.8565e-02 -6.0000e+00 5.6111e-01 1.0069e-01 1.2915e-03 3.7143e-02 -6.0000e+00 6.0800e-01 -1.1167e-01 1.1723e-03 1.8993e-02 -6.0000e+00 3.6130e-01 3.8830e-02 5.9208e-04 6.0192e-03 -6.0000e+00 1.4940e-01 1.9939e-03 -1.4752e-04 1.8383e-05 7.9876e-05 -6.0000e+00 1.1623e-02 -1.2660e-02 0.0000e+00 11 8 0 10 0 0 97.19 25.77 0.30 -0.01266 -0.01377 623 65 1 5 0 87.190 34.75 19.97 25.77 21.40 3.3 972.12 -142686 -104534 -128127 -119167 -143240 -149695 -137602 -124644 -90675 -100125 -80017 -82929 -63922 -55398 -47792 -28052 -25482 -19495 -7509 -14109 -17189 -29848 -17909 -13679 -26073 -19831 -23868 -21466 -22531 -20427 -14200 -6682 -11389 -4432 -12648 -4724 -6627 -2880 -1097 -1902 -2170 1847 1984 2421 648 3531 1402 1089 698 1188 1628 4264 3610 3654 2483 2856 1242 955 1250 1391 1581 2825 2649 2987 2875 1144 1684 1136 2030 2072 670 720 614 550 -454 -807 -554 -794 -1016 -713 -1166 -1479 -1975 -1909 -1100 -573 -273 5 409 183 271 259 -229 -357 -397 -359 14 144 -195 -571 -657 -925 -569 -174 -760 -1157 -627 -483 53 348 311 131 171 218 127 457 583 303 185 -53 -54 123 625 456 527 512 293 919 604 57 84 -167 -108 -107 21 -85 -113 76 -98 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