File name: Pandora26s1_CambridgeMA_20240513_L2Fit_fout2c7d20230915p1-8.txt File generation date: 20241010T184456.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20240513_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240513 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.1176 305.2583 305.3991 305.5398 305.6805 305.8212 305.9619 306.1026 306.2432 306.3839 306.5245 306.6651 306.8057 306.9464 307.0869 307.2275 307.3681 307.5087 307.6492 307.7897 307.9303 308.0708 308.2113 308.3518 308.4923 308.6327 308.7732 308.9136 309.0541 309.1945 309.3349 309.4753 309.6157 309.7561 309.8964 310.0368 310.1771 310.3175 310.4578 310.5981 310.7384 310.8787 311.0189 311.1592 311.2995 311.4397 311.5799 311.7201 311.8604 312.0005 312.1407 312.2809 312.4211 312.5612 312.7013 312.8415 312.9816 313.1217 313.2618 313.4019 313.5419 313.6820 313.8220 313.9621 314.1021 314.2421 314.3821 314.5221 314.6621 314.8020 314.9420 315.0819 315.2219 315.3618 315.5017 315.6416 315.7815 315.9213 316.0612 316.2010 316.3409 316.4807 316.6205 316.7603 316.9001 317.0399 317.1797 317.3194 317.4592 317.5989 317.7386 317.8783 318.0180 318.1577 318.2974 318.4371 318.5767 318.7164 318.8560 318.9956 319.1352 319.2748 319.4144 319.5540 319.6935 319.8331 319.9726 320.1122 320.2517 320.3912 320.5307 320.6702 320.8096 320.9491 321.0885 321.2280 321.3674 321.5068 321.6462 321.7856 321.9250 322.0643 322.2037 322.3430 322.4823 322.6217 322.7610 322.9003 323.0395 323.1788 323.3181 323.4573 323.5965 323.7358 323.8750 324.0142 324.1534 324.2926 324.4317 324.5709 324.7100 324.8491 324.9883 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240513T101546.5Z 8899.427622 68 1 54.24 2 82.06 72.08 112.59 11.04 0.00 1 0.00 1 0 17 6.196e-01 2.340e-02 2.349e-01 3.199e-03 1.123300e+00 1.927428e-03 1.204642e-02 -6.000000e+00 3.836999e-01 230.92 -2.00 3.54 -2.00 322.13 0.00e+00 1.219828e-02 1.208800e-03 3.319752e-03 -6.000000e+00 1.876299e-02 282.28 -2.00 20.00 -2.00 321.68 0.00e+00 6.760 0.006 302.00 328.00 3 3.8514e-01 7.7582e-03 9.9279e-02 -6.0000e+00 9.6619e-01 1.1506e+00 1.1468e-02 8.6279e-02 -6.0000e+00 1.0516e+00 -1.4953e+00 1.1499e-02 3.4084e-02 -6.0000e+00 6.2281e-01 5.9386e-01 5.1056e-03 1.9297e-02 -6.0000e+00 2.5690e-01 1.2063e-04 -7.6845e-04 7.9808e-05 2.7747e-04 -6.0000e+00 1.9680e-02 -1.1623e-02 0.0000e+00 12 8 8 10 0 0 21.26 25.41 0.35 -0.01162 -0.01740 147 15 1 5 0 368.910 34.50 19.90 25.41 18.09 3.5 958.68 -37022 900000 131256 900000 -155407 -258304 -235990 -188113 900000 900000 23647 -85413 -28635 80909 36225 900000 900000 33603 900000 900000 59473 -153301 900000 900000 -85121 -4557 -61890 -34165 -50071 -114525 -43118 3356 -77545 225141 -50072 51514 30601 -3520 164243 -14280 -37972 96438 123563 106307 -6571 900000 74737 100616 21886 41768 -10458 127028 114042 73525 33818 74083 12226 34355 30039 42877 17247 9076 15904 26821 90003 11911 17173 12436 11702 32873 17195 19591 34977 13955 -2242 7444 10367 11190 -318 15541 7603 2405 3885 -1245 -421 4280 3090 3781 5681 2008 -3112 689 -1950 -6778 -3417 -3007 -1231 -2269 982 -1755 -1508 -3362 -2975 -2853 -2186 -2123 -3777 -3347 -1184 -938 -1398 -1006 -1017 -748 -384 -1051 531 -193 -855 954 1441 1089 2677 2657 1647 2383 1237 1341 1020 771 1225 210 -258 -8 878 85 -40 86 -188 242 -276 -1315 -1948 -157 900000 409 900000 -1847 -7895 -5610 -2768 900000 900000 74 -629 -162 252 185 900000 900000 257 900000 900000 337 -6942 900000 900000 -1927 -50 -1156 -479 -889 -4706 -1114 67 -3911 701 -1871 690 543 -101 1023 -600 -2199 1531 1539 1589 -307 900000 1675 1879 988 1729 -827 2847 3195 3319 2369 3529 1070 2310 2001 2456 1337 862 1644 2839 5464 1639 2363 1959 2095 5342 3490 3909 5673 2524 -422 1156 1556 1853 -71 3663 2324 813 1428 -514 -182 1843 1388 1700 2457 859 -1325 275 -828 -3401 -1981 -2112 -935 -2021 919 -1686 -1342 -2705 -2357 -2223 -1769 -1666 -3251 -3199 -1282 -1098 -1888 -1479 -1554 -1139 -572 -1566 799 -305 -1311 1435 2218 1580 3643 3491 2122 2989 1599 1930 1617 1438 2418 462 -581 -19 2257 216 -103 220 -469 598 -627 -2967 -4290 SS 20240513T103408.2Z 8899.440372 73 1 54.32 2 78.81 75.01 111.89 15.29 0.00 1 0.00 1 0 17 7.144e-01 1.207e-02 3.613e-02 9.603e-04 8.807822e-01 5.319787e-04 9.984844e-03 -6.000000e+00 4.321771e-01 230.92 -2.00 3.54 -2.00 320.96 0.00e+00 4.097146e-03 2.477997e-04 3.369463e-03 -6.000000e+00 1.906805e-02 282.28 -2.00 20.00 -2.00 320.40 0.00e+00 4.972 0.002 302.00 328.00 3 3.6724e-01 1.7252e-03 6.9749e-02 -6.0000e+00 1.0806e+00 2.3250e-01 2.3568e-03 4.9846e-02 -6.0000e+00 1.1705e+00 -3.0067e-01 2.3955e-03 2.7255e-02 -6.0000e+00 6.9555e-01 1.1598e-01 1.1411e-03 9.3249e-03 -6.0000e+00 2.8750e-01 9.8145e-04 -1.3071e-04 2.4777e-05 1.4760e-04 -6.0000e+00 2.2344e-02 -1.1803e-02 0.0000e+00 12 8 8 10 0 0 15.62 25.46 0.32 -0.01180 -0.01278 454 48 1 5 0 119.630 34.50 20.00 25.46 20.05 3.4 967.60 -238493 -199754 -226547 -211283 -259036 -269075 -267359 -231320 -187798 -195367 -173754 -181572 -141580 -127207 -95837 -77281 -41721 -65776 8351 -16555 -58470 -93000 -33771 -46561 -66493 -50253 -66578 -55395 -54646 -61528 -40261 -19176 -35904 -5673 -29501 -15517 -17756 -9997 551 -9159 -8688 7381 5139 5567 -2709 10004 2107 7030 2970 5143 3241 10626 10093 8128 6511 6248 2386 4166 2217 3030 3007 2762 4948 5435 7817 2216 2450 1533 3259 4495 2329 2197 2727 661 -171 17 -216 -518 -707 250 -211 -1258 -1420 -1282 -983 -449 -312 243 542 339 -387 24 -859 -1378 -1026 -674 -445 -374 -352 -833 -1062 -1192 -829 -480 -1025 -1492 -1108 -973 -197 299 268 25 93 115 132 314 822 373 73 131 286 491 880 796 714 657 267 1028 642 172 196 -114 -129 -96 -33 -80 -140 148 -142 -124 -75 -464 -557 -2010 -1326 -2083 -1801 -3445 -4057 -4357 -2968 -1741 -2159 -1774 -2517 -1763 -1835 -1301 -1064 -469 -1059 70 -186 -1024 -2369 -509 -872 -1638 -1101 -1740 -1307 -1371 -1953 -1293 -611 -1553 -191 -1263 -602 -798 -502 30 -655 -696 544 408 453 -246 831 199 679 327 620 454 1566 1665 1360 1182 1189 481 815 431 582 612 634 1278 1571 2342 717 821 561 1215 1873 1073 1039 1242 285 -67 6 -83 -198 -316 133 -123 -848 -977 -943 -767 -368 -247 194 426 273 -295 17 -639 -1123 -899 -652 -474 -452 -430 -1013 -1274 -1288 -878 -508 -1149 -1671 -1322 -1197 -257 441 419 39 149 181 211 490 1298 587 121 217 460 786 1346 1173 1068 955 391 1542 1055 308 373 -225 -263 -208 -73 -186 -319 336 -330 -273 -160 -968 -1140 SS 20240513T104037.8Z 8899.444881 76 1 54.32 2 77.65 76.04 111.58 16.77 0.00 1 0.00 1 0 17 5.765e-01 1.033e-02 2.293e-02 7.308e-04 8.123269e-01 4.013755e-04 9.204394e-03 -6.000000e+00 3.487595e-01 230.92 -2.00 3.54 -2.00 320.60 0.00e+00 3.064513e-03 1.660190e-04 2.286416e-03 -6.000000e+00 1.538656e-02 282.28 -2.00 20.00 -2.00 320.00 0.00e+00 4.539 0.002 302.00 328.00 3 3.5077e-01 1.2421e-03 6.3381e-02 -6.0000e+00 8.7201e-01 1.5895e-01 1.6186e-03 4.4527e-02 -6.0000e+00 9.4457e-01 -1.9886e-01 1.5708e-03 2.3693e-02 -6.0000e+00 5.6129e-01 7.4040e-02 7.6936e-04 7.8802e-03 -6.0000e+00 2.3202e-01 1.6173e-03 -1.0075e-04 1.9466e-05 1.1456e-04 -6.0000e+00 1.8030e-02 -1.2221e-02 0.0000e+00 12 8 8 10 0 0 -8.19 25.51 0.28 -0.01222 -0.01298 604 63 1 5 0 89.920 34.50 19.96 25.51 20.22 3.4 968.07 -208204 -190278 -172275 -161734 -208425 -226677 -208529 -195697 -151227 -142654 -147706 -131975 -105465 -106685 -79699 -57793 -43220 -51076 -6539 -28557 -45273 -60200 -23471 -37865 -44463 -30921 -41483 -42832 -36679 -41871 -29871 -15115 -22147 -7486 -17773 -12755 -12182 -6322 -644 -5610 -4700 2109 3205 2218 323 7023 2116 3137 1707 3057 3747 6543 5866 4992 3979 4576 1545 2251 1850 2752 2329 2944 3059 3988 4743 2032 1832 1210 2112 2744 1447 1693 1549 412 -124 -9 -333 -735 -483 140 -682 -1256 -1738 -1879 -1435 -945 -73 147 222 122 -204 -116 -628 -854 -784 -579 -241 -44 -385 -632 -691 -973 -558 -412 -994 -1195 -751 -653 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