File name: Pandora26s1_CambridgeMA_20240529_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20241217T225302.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20240529_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240529 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240529T100304.3Z 8915.418799 171 1 54.32 2 82.32 67.51 61.41 181.96 0.00 1 0.00 1 0 25 7.234e-01 2.212e-02 2.249e-01 2.849e-03 1.008249e+00 1.697069e-03 1.105769e-02 -6.000000e+00 4.449886e-01 231.94 -2.00 3.54 -2.00 321.93 0.00e+00 5.283220e-03 1.023777e-03 4.052245e-03 -6.000000e+00 2.246654e-02 283.91 -2.00 20.00 -2.00 321.45 0.00e+00 6.956 0.006 302.00 328.00 3 3.8781e-01 6.6107e-03 9.0321e-02 -6.0000e+00 1.1258e+00 7.9300e-01 9.9077e-03 5.9785e-02 -6.0000e+00 1.2260e+00 -1.0827e+00 9.8006e-03 3.3597e-02 -6.0000e+00 7.2231e-01 4.3970e-01 4.3335e-03 1.1965e-02 -6.0000e+00 2.9846e-01 1.2655e-04 -5.3100e-04 7.4454e-05 2.0676e-04 -6.0000e+00 2.3113e-02 5.2115e-03 5.8925e-06 12 8 8 10 0 0 8.03 25.98 0.30 0.00521 0.00122 164 17 1 5 0 331.150 35.00 19.99 25.98 23.92 3.2 987.32 -191999 900000 900000 900000 -218768 -258907 -248344 -286532 900000 900000 -14958 -218797 -117797 41391 56422 330250 20704 900000 900000 900000 193322 -87819 900000 152824 -86670 -55180 -91125 -76621 -6901 -79550 -46978 -35950 -77349 87280 -46373 900000 -35649 2695 73989 -17989 -28251 34777 102302 38147 -11856 51131 53558 52419 -1100 26515 12 105487 120175 49829 23735 53620 2360 28766 26497 30234 21320 3379 12061 12923 33056 9864 16305 16487 14703 26240 15298 9684 20320 6734 3541 6588 8514 2873 848 6806 4275 408 731 -3466 -2003 3027 769 5440 2710 1427 -1928 -483 -2932 -5463 -3594 -1823 -1962 -925 -890 -1915 -2330 -3474 -1945 -3341 -2378 -2233 -2733 -2779 -813 -58 -504 -1059 239 237 -503 -821 810 -129 -85 108 1595 709 2464 2302 1578 2320 -260 1311 694 478 1216 -92 19 -74 616 -24 -20 185 -17 -172 -341 -1252 -1446 -2323 900000 900000 900000 -3254 -5548 -4946 -8885 900000 900000 -41 -5185 -1336 125 185 916 130 900000 900000 900000 536 -1815 900000 424 -2187 -1025 -2375 -1700 -80 -2250 -1199 -997 -3668 823 -1620 900000 -1246 75 1211 -853 -1637 1138 1759 1259 -651 1531 1634 1730 -68 1382 1 3188 3466 3150 2060 3569 264 2401 2168 2339 1886 401 1515 1820 4070 1576 2555 2807 2883 5174 3623 2468 4468 1554 755 1242 1553 607 217 1999 1393 159 314 -1662 -1005 1519 409 2797 1409 718 -949 -227 -1449 -3074 -2338 -1281 -1640 -881 -915 -1981 -2254 -3048 -1544 -2682 -1989 -1978 -2619 -2948 -893 -73 -726 -1540 353 347 -725 -1175 1166 -197 -134 172 2406 1023 3601 3254 2178 3109 -362 1983 1143 853 2426 -191 44 -169 1485 -61 -51 477 -42 -407 -793 -2733 -3089 SS 20240529T101518.8Z 8915.427300 174 1 54.31 2 80.22 69.44 61.51 185.18 0.00 1 0.00 1 0 17 6.997e-01 1.215e-02 9.497e-02 1.226e-03 8.592686e-01 6.818521e-04 9.866753e-03 -6.000000e+00 4.247500e-01 231.94 -2.00 3.54 -2.00 321.11 0.00e+00 4.975493e-03 3.344482e-04 4.095439e-03 -6.000000e+00 1.879658e-02 283.92 -2.00 20.00 -2.00 320.53 0.00e+00 5.619 0.003 302.00 328.00 3 3.7752e-01 2.2894e-03 7.4467e-02 -6.0000e+00 1.0641e+00 2.3513e-01 3.1985e-03 5.0872e-02 -6.0000e+00 1.1516e+00 -3.0138e-01 3.2455e-03 2.8221e-02 -6.0000e+00 6.8439e-01 1.1634e-01 1.5248e-03 9.6169e-03 -6.0000e+00 2.8258e-01 5.5304e-04 -3.7297e-05 3.2132e-05 1.6153e-04 -6.0000e+00 2.1887e-02 5.0147e-03 -1.0269e-05 12 8 8 10 0 0 22.87 26.00 0.36 0.00501 0.00473 364 38 1 5 0 149.180 35.00 20.00 26.00 24.51 3.2 989.27 -266470 -197478 -167400 -198497 -284714 -269191 -243712 -270559 -60461 -125139 -102018 -200360 -180973 -117298 -91954 -53200 -73490 -24753 159149 12270 -58393 -79610 13481 -43808 -70938 -47738 -73136 -63045 -49720 -50739 -40842 -29076 -54940 -13601 -37635 12155 -25100 -6470 -4838 -17499 -13996 1138 8679 2986 -5779 3993 4877 3421 -2344 3105 1292 12337 16309 9327 5304 6781 732 3487 2173 3402 2816 2084 3618 4589 7410 2637 4181 3761 3692 4908 3269 3065 4045 1724 658 -471 276 -673 -1124 -271 -215 -686 -1070 -1868 -992 118 75 1045 974 483 -422 79 -625 -1454 -1361 -993 -515 -51 -412 -857 -1167 -1707 -1093 -945 -1497 -1381 -1128 -1013 21 259 86 -26 388 131 58 40 812 351 175 60 401 574 970 643 566 845 -41 1173 574 228 307 -19 -182 20 85 -95 -332 47 -121 -79 -50 -459 -539 -2780 -1202 -800 -1273 -4177 -3452 -2649 -4322 -145 -628 -463 -3042 -3029 -1388 -1088 -521 -1028 -240 266 94 -928 -1608 114 -717 -1637 -913 -1827 -1439 -1064 -1292 -1177 -911 -2561 -442 -1557 318 -1080 -278 -249 -1205 -1046 79 589 222 -482 314 400 305 -242 339 163 1581 2234 1497 945 1244 132 667 411 637 562 429 843 1189 1978 752 1217 1188 1319 1962 1318 1271 1612 712 249 -165 94 -250 -490 -129 -121 -408 -701 -1322 -741 92 56 794 730 375 -311 55 -447 -1142 -1146 -918 -555 -58 -505 -1046 -1330 -1882 -1114 -968 -1627 -1587 -1296 -1272 28 364 135 -41 619 205 92 63 1285 552 288 101 648 932 1507 964 820 1257 -59 1791 955 411 586 -38 -384 44 197 -219 -781 110 -280 -180 -106 -967 -1116 SS 20240529T102318.4Z 8915.432851 178 1 54.31 2 78.83 70.70 61.63 187.28 0.00 1 0.00 1 0 17 5.444e-01 1.003e-02 2.771e-02 8.178e-04 7.789281e-01 4.489496e-04 8.859442e-03 -6.000000e+00 3.305143e-01 231.94 -2.00 3.54 -2.00 320.65 0.00e+00 2.866337e-03 1.899616e-04 2.561723e-03 -6.000000e+00 1.462544e-02 283.92 -2.00 20.00 -2.00 320.02 0.00e+00 4.981 0.002 302.00 328.00 3 3.4802e-01 1.4090e-03 6.5626e-02 -6.0000e+00 8.2804e-01 1.3848e-01 1.8451e-03 4.3503e-02 -6.0000e+00 8.9607e-01 -1.7441e-01 1.7743e-03 2.2836e-02 -6.0000e+00 5.3254e-01 6.4373e-02 8.6440e-04 7.2412e-03 -6.0000e+00 2.1990e-01 1.1374e-03 7.9941e-05 2.2110e-05 1.0884e-04 -6.0000e+00 1.7030e-02 4.7663e-03 -3.6727e-06 12 8 8 10 0 0 7.40 26.00 0.29 0.00477 0.00537 533 56 1 5 0 101.880 35.00 20.00 26.00 24.80 3.1 990.84 -205137 -168115 -137956 -158380 -204754 -214046 -201121 -205621 -134599 -124852 -119216 -150735 -116579 -84951 -65491 -50409 -36615 -37307 6397 -8982 -34086 -49883 -17869 -31183 -46681 -33777 -43583 -41273 -32484 -33589 -25890 -14561 -27882 -10829 -20975 -4313 -16357 -5716 -275 -4665 -6936 2169 4431 3782 -1188 2199 2393 1618 -15 2222 1201 6591 7705 5387 3661 4840 902 2196 2459 2347 2208 2389 3197 3871 4027 1669 2041 1910 2561 3117 1324 1665 2181 701 115 288 -91 -1135 -970 -131 -595 -1410 -1742 -1878 -1278 -601 -149 282 574 235 -230 -70 -523 -881 -738 -677 -302 114 -319 -741 -746 -977 -767 -422 -939 -1189 -923 -577 108 389 284 83 155 172 209 316 662 312 133 -51 212 413 698 456 457 567 124 1023 458 209 231 -162 -141 -53 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