File name: Pandora26s1_CambridgeMA_20240604_L2Fit_fout2c7d20230915p1-8.txt File generation date: 20241010T180358.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20240604_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.1176 305.2583 305.3991 305.5398 305.6805 305.8212 305.9619 306.1026 306.2432 306.3839 306.5245 306.6651 306.8057 306.9464 307.0869 307.2275 307.3681 307.5087 307.6492 307.7897 307.9303 308.0708 308.2113 308.3518 308.4923 308.6327 308.7732 308.9136 309.0541 309.1945 309.3349 309.4753 309.6157 309.7561 309.8964 310.0368 310.1771 310.3175 310.4578 310.5981 310.7384 310.8787 311.0189 311.1592 311.2995 311.4397 311.5799 311.7201 311.8604 312.0005 312.1407 312.2809 312.4211 312.5612 312.7013 312.8415 312.9816 313.1217 313.2618 313.4019 313.5419 313.6820 313.8220 313.9621 314.1021 314.2421 314.3821 314.5221 314.6621 314.8020 314.9420 315.0819 315.2219 315.3618 315.5017 315.6416 315.7815 315.9213 316.0612 316.2010 316.3409 316.4807 316.6205 316.7603 316.9001 317.0399 317.1797 317.3194 317.4592 317.5989 317.7386 317.8783 318.0180 318.1577 318.2974 318.4371 318.5767 318.7164 318.8560 318.9956 319.1352 319.2748 319.4144 319.5540 319.6935 319.8331 319.9726 320.1122 320.2517 320.3912 320.5307 320.6702 320.8096 320.9491 321.0885 321.2280 321.3674 321.5068 321.6462 321.7856 321.9250 322.0643 322.2037 322.3430 322.4823 322.6217 322.7610 322.9003 323.0395 323.1788 323.3181 323.4573 323.5965 323.7358 323.8750 324.0142 324.1534 324.2926 324.4317 324.5709 324.7100 324.8491 324.9883 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240604T100108.4Z 8921.417458 99 1 54.18 2 82.28 66.47 64.00 87.56 0.00 1 0.00 1 0 17 8.254e-01 4.103e-02 2.654e-01 9.317e-03 9.461786e-01 5.607387e-03 1.029413e-02 -6.000000e+00 5.090936e-01 232.31 -2.00 3.54 -2.00 322.06 0.00e+00 -1.628088e-02 2.855810e-03 2.234091e-03 -6.000000e+00 2.565553e-02 284.52 -2.00 20.00 -2.00 321.52 0.00e+00 6.919 0.006 302.00 328.00 3 2.0068e+00 2.1353e-02 8.9465e-02 -6.0000e+00 1.2841e+00 1.3955e+00 2.7049e-02 6.5074e-02 -6.0000e+00 1.3980e+00 -1.9664e+00 1.8832e-02 2.5439e-02 -6.0000e+00 8.2923e-01 7.8538e-01 8.9750e-03 1.4440e-02 -6.0000e+00 3.4359e-01 2.6901e-05 2.2731e-04 2.6920e-04 1.9930e-04 -6.0000e+00 2.7023e-02 -8.5051e-03 0.0000e+00 12 8 8 10 0 0 -5.66 25.81 0.41 -0.00851 -0.00680 35 4 1 5 0 1547.770 34.75 20.00 25.81 23.85 3.2 986.92 247164 900000 900000 900000 16409 -72828 -26966 -48652 140707 240599 900000 127958 257024 900000 900000 74946 900000 344759 900000 900000 115932 -25735 900000 900000 -16717 -20902 16027 -18995 104660 -22499 -9224 42443 3377 221515 -31791 900000 5465 140588 900000 10046 -41345 85389 421635 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1297 1402 -4908 -4688 3825 1744 8070 4753 2353 -2941 298 -2138 -8212 -2866 -322 768 -648 -744 -4332 -4585 -8601 -310 -471 -5924 -1386 -3733 -6482 366 4754 -5362 -2277 2403 -1403 4444 -7536 4395 -2039 -3991 -3080 6737 6239 2716 3660 3538 9115 1880 -129 -3299 1759 6011 47 -4263 -17 9497 2770 -3624 2247 -4442 2051 -1604 -6259 -2956 SS 20240604T101341.7Z 8921.426177 102 1 54.06 2 80.13 68.45 61.72 89.53 0.00 1 0.00 1 0 17 5.625e-01 1.809e-02 1.973e-01 2.771e-03 8.186821e-01 1.579059e-03 9.539647e-03 -6.000000e+00 3.432196e-01 232.31 -2.00 3.54 -2.00 321.38 0.00e+00 1.883131e-03 8.254693e-04 5.938460e-03 -6.000000e+00 1.596635e-02 284.52 -2.00 20.00 -2.00 320.81 0.00e+00 5.576 0.003 302.00 328.00 3 1.7613e+00 5.6095e-03 7.6876e-02 -6.0000e+00 8.6294e-01 3.1577e-01 7.8523e-03 5.9139e-02 -6.0000e+00 9.3631e-01 -4.8856e-01 7.6156e-03 2.8203e-02 -6.0000e+00 5.5537e-01 1.9485e-01 3.5099e-03 6.8544e-03 -6.0000e+00 2.3002e-01 1.5508e-04 2.1446e-04 7.7937e-05 1.5429e-04 -6.0000e+00 1.7698e-02 -8.9201e-03 0.0000e+00 12 8 8 10 0 0 19.88 25.82 0.46 -0.00892 -0.00731 104 11 1 5 0 519.770 34.75 20.00 25.82 24.73 3.2 990.56 -176640 900000 900000 -38857 -250617 -268694 -237929 -231810 78642 -83768 16678 -135538 -65696 -37526 -92915 -92732 -7115 22855 900000 900000 -46107 -62537 155130 19810 -115172 -80934 -61342 -51234 -35615 -59656 -23192 -25144 -53312 32943 -36124 900000 -11747 31097 24227 -16357 -28309 15227 28857 20470 -22703 14830 14148 17405 3462 11136 -6079 53370 43038 24013 12067 17478 1422 14061 18222 10317 8295 7543 3708 5007 19017 1843 8333 8345 4134 12122 4713 5007 10866 2326 911 -2277 614 -758 -1276 -118 -110 -2378 -1299 -4230 -3404 654 323 2434 1207 964 -3391 -484 -1874 -3297 -2930 -595 -503 -645 -651 -1326 -1626 -2190 -684 -893 -1779 -1304 -1286 -795 317 910 -322 -242 350 435 482 -867 1447 314 136 -31 1020 -257 1027 1403 862 1711 365 738 400 267 587 -209 -372 35 430 -29 -380 477 -435 44 -156 -831 -566 -1561 900000 900000 -105 -4860 -6331 -4497 -4609 212 -452 45 -1663 -568 -314 -1681 -1978 -73 191 900000 900000 -859 -1401 419 225 -5380 -2775 -1722 -1286 -798 -1949 -639 -842 -2663 720 -1561 900000 -466 966 975 -1153 -2499 929 1597 1255 -2176 1001 997 1255 309 1019 -745 4049 3997 2931 1763 2520 245 2099 2539 1549 1339 1371 797 1179 4077 474 2066 2226 1297 3603 1629 1766 3505 759 300 -710 182 -243 -435 -47 -52 -1304 -772 -2772 -2164 422 218 1631 807 674 -2330 -310 -1224 -2367 -2210 -515 -507 -681 -732 -1484 -1700 -2261 -651 -863 -1836 -1311 -1383 -929 411 1234 -490 -389 564 683 731 -1307 2175 499 212 -49 1670 -409 1551 2035 1214 2323 505 1100 636 482 1095 -423 -806 77 992 -69 -889 1115 -1065 102 -338 -1816 -1216 SS 20240604T102116.5Z 8921.431441 106 1 54.32 2 78.83 69.63 60.34 90.74 0.00 1 0.00 1 0 17 5.151e-01 1.306e-02 9.734e-02 1.690e-03 7.474733e-01 9.367426e-04 8.602474e-03 -6.000000e+00 3.140256e-01 232.31 -2.00 3.54 -2.00 320.85 0.00e+00 9.608002e-04 4.227657e-04 3.720923e-03 -6.000000e+00 1.406428e-02 284.52 -2.00 20.00 -2.00 320.24 0.00e+00 4.979 0.002 302.00 328.00 3 1.5803e+00 3.0356e-03 6.6084e-02 -6.0000e+00 7.8888e-01 1.2530e-01 4.0579e-03 4.6204e-02 -6.0000e+00 8.5517e-01 -2.2266e-01 3.8910e-03 2.2301e-02 -6.0000e+00 5.0726e-01 8.5403e-02 1.8611e-03 5.7686e-03 -6.0000e+00 2.0849e-01 3.5785e-04 1.3726e-04 4.7732e-05 1.0119e-04 -6.0000e+00 1.6122e-02 -8.8449e-03 0.0000e+00 12 8 8 10 0 0 73.38 25.83 0.37 -0.00884 -0.00781 173 18 1 5 0 313.930 34.75 20.00 25.83 25.19 3.1 993.12 -201632 -37822 -59351 -131393 -208491 -242851 -191215 -211929 -155831 -134560 3644 -158999 -67321 -21389 -28393 -49995 -29811 -22596 900000 900000 -42383 -67027 15240 20056 -76947 -61182 -55205 -47628 -26668 -42850 -38477 -18791 -38481 1275 -24335 25625 -20565 4505 8097 -6635 -17693 733 12910 6775 -7006 8092 4615 6682 3746 2672 -3134 17713 16338 8158 3808 9771 1040 7516 6028 4354 5381 4210 2769 3803 7142 1933 4075 3302 2605 3773 2304 2941 3660 436 -865 -1821 258 -1608 -2248 -352 -1532 -2028 -2007 -2768 -1618 325 -196 1207 533 263 -1047 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