File name: Pandora26s1_CambridgeMA_20240608_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20241217T225326.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20240608_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240608 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240608T095936.5Z 8925.416395 59 1 54.42 2 82.39 65.82 95.55 44.77 0.00 1 0.00 1 0 17 6.554e-01 2.258e-02 1.657e-01 2.870e-03 1.028205e+00 1.707814e-03 1.140552e-02 -6.000000e+00 4.030128e-01 232.56 -2.00 3.54 -2.00 321.99 0.00e+00 5.868500e-03 1.043372e-03 4.540832e-03 -6.000000e+00 1.946436e-02 284.93 -2.00 20.00 -2.00 321.50 0.00e+00 7.009 0.006 302.00 328.00 3 3.0899e-01 6.7823e-03 9.1753e-02 -6.0000e+00 1.0151e+00 8.7504e-01 1.0040e-02 6.1065e-02 -6.0000e+00 1.1019e+00 -1.2059e+00 9.6538e-03 3.4462e-02 -6.0000e+00 6.5544e-01 4.9086e-01 4.2585e-03 1.2750e-02 -6.0000e+00 2.7127e-01 1.2651e-04 -4.3080e-04 7.4181e-05 2.3272e-04 -6.0000e+00 2.0916e-02 2.6886e-03 5.0656e-05 12 8 8 10 0 0 9.47 25.92 0.34 0.00269 -0.00055 169 18 1 5 0 321.950 34.75 19.99 25.92 23.32 3.3 983.50 -184596 900000 900000 900000 -218784 -285045 -220344 -184294 -89211 -216176 -11173 -166016 275343 900000 36007 -1272 1456 900000 900000 900000 -33540 -83021 900000 900000 -103230 -45246 -83049 -101263 -68510 -65371 -71321 -5921 -61177 27584 -44824 71893 -22132 30988 27080 -9684 -50725 42578 73966 33417 4296 31487 41930 36954 625 34968 1566 175748 100606 62813 38069 54489 10651 29914 29971 11176 15350 24806 14260 20592 40656 18149 16612 28438 18090 19956 15477 14661 21250 11942 3389 211 885 2414 -2978 5997 2645 2181 3482 -1575 -243 2597 1611 6665 1800 1218 -2526 -1321 -3279 -3787 -5094 -1957 -529 -2087 -2122 -2258 -1542 -2968 -2299 -1989 -3293 -2620 -2202 -2282 -2177 176 -1070 -566 -223 -295 -339 -1297 628 234 292 368 2227 359 1680 1828 2219 2584 703 1408 -63 976 1151 213 -280 182 557 21 -234 531 -227 -56 -583 -1214 -1490 -2626 900000 900000 900000 -4001 -9630 -3974 -2434 -476 -4283 -31 -2657 769 900000 165 -10 13 900000 900000 900000 -452 -1793 900000 900000 -3288 -809 -2112 -3028 -1551 -1680 -2431 -127 -2581 493 -1603 804 -693 667 719 -428 -3713 1297 1695 1158 200 1144 1429 1415 38 1661 118 2603 3486 3440 2819 3532 1074 2416 2311 1018 1398 2301 1697 2606 4510 2597 2525 4180 3331 4071 3555 3453 4495 2536 701 41 168 494 -766 1717 849 812 1413 -720 -117 1271 825 3288 917 597 -1215 -608 -1581 -2040 -3279 -1468 -427 -1974 -2175 -2314 -1462 -2560 -1805 -1548 -2729 -2287 -2061 -2368 -2387 219 -1534 -813 -330 -434 -487 -1865 907 355 461 583 3342 520 2473 2595 3043 3454 970 2128 -105 1743 2317 445 -635 417 1360 53 -611 1377 -578 -135 -1374 -2675 -3206 SS 20240608T101204.9Z 8925.425057 62 1 54.30 2 80.27 67.78 93.98 46.90 0.00 1 0.00 1 0 17 7.358e-01 1.304e-02 5.896e-02 1.220e-03 8.738966e-01 6.827657e-04 1.017124e-02 -6.000000e+00 4.479716e-01 232.56 -2.00 3.54 -2.00 321.14 0.00e+00 4.172158e-03 3.392277e-04 5.113324e-03 -6.000000e+00 1.984816e-02 284.93 -2.00 20.00 -2.00 320.55 0.00e+00 5.648 0.003 302.00 328.00 3 3.2927e-01 2.3221e-03 7.6761e-02 -6.0000e+00 1.1237e+00 2.6089e-01 3.2460e-03 5.5394e-02 -6.0000e+00 1.2150e+00 -3.4944e-01 3.2370e-03 2.9262e-02 -6.0000e+00 7.2215e-01 1.3836e-01 1.5123e-03 8.7327e-03 -6.0000e+00 2.9831e-01 5.5735e-04 1.4486e-04 3.1904e-05 1.6619e-04 -6.0000e+00 2.3022e-02 2.2123e-03 5.0402e-05 12 8 8 10 0 0 -1.39 25.94 0.33 0.00221 0.00330 370 39 1 5 0 146.750 34.75 19.99 25.94 23.65 3.3 984.16 -288672 -218784 -160452 -210562 -269398 -292200 -269095 -223034 -189435 -224013 -149387 -181153 -149627 -99340 -99587 -104501 -63722 -4544 82548 1372 -61986 -88856 -27292 -35939 -78745 -65217 -58664 -76160 -68456 -45237 -47258 -29060 -54180 -9636 -32215 -13725 -20439 -8736 -6046 -15221 -16202 1824 3479 3455 -4702 -8 2808 3678 984 4017 2010 16352 13487 11990 8014 9071 3278 5053 2814 2254 2994 5152 4708 6627 9012 3925 4644 4621 3808 4905 4015 3312 3711 1416 630 -869 -558 -1429 -2215 97 -348 -447 -625 -1460 -1089 17 407 1012 321 382 -493 -399 -1102 -1439 -1574 -914 -597 -260 -734 -1099 -1168 -1616 -1049 -717 -1817 -1627 -960 -985 -243 355 -165 80 321 211 -38 41 829 500 384 235 481 387 924 731 842 990 344 1052 591 328 297 -101 -99 -148 -47 -94 -174 190 -90 -173 -197 -499 -567 -3839 -1680 -729 -1548 -3437 -4771 -3812 -2467 -1667 -3064 -1102 -2284 -1833 -981 -1267 -1703 -803 -36 295 12 -1010 -1945 -344 -539 -1948 -1474 -1256 -1957 -1734 -1065 -1416 -888 -2449 -295 -1234 -454 -817 -374 -307 -999 -1208 123 242 248 -376 -1 227 316 95 419 244 1947 1840 1817 1350 1582 618 925 514 413 575 1089 1045 1623 2289 1070 1303 1402 1317 1902 1704 1333 1576 571 232 -298 -186 -518 -946 45 -190 -280 -398 -1004 -796 13 322 809 255 291 -356 -276 -776 -1106 -1300 -886 -631 -293 -890 -1327 -1315 -1760 -1054 -720 -1948 -1842 -1084 -1216 -315 493 -256 125 509 328 -61 63 1306 782 627 390 773 626 1427 1089 1210 1462 513 1598 979 589 565 -208 -210 -320 -108 -217 -410 449 -209 -396 -439 -1051 -1172 SS 20240608T102030.6Z 8925.430909 66 1 54.31 2 78.83 69.10 92.88 48.32 0.00 1 0.00 1 0 17 5.739e-01 1.045e-02 2.681e-02 8.075e-04 7.901094e-01 4.454620e-04 9.000049e-03 -6.000000e+00 3.493512e-01 232.56 -2.00 3.54 -2.00 320.68 0.00e+00 2.572935e-03 1.907058e-04 2.748728e-03 -6.000000e+00 1.547971e-02 284.93 -2.00 20.00 -2.00 320.05 0.00e+00 4.979 0.002 302.00 328.00 3 3.1081e-01 1.4123e-03 6.6306e-02 -6.0000e+00 8.7631e-01 1.4649e-01 1.8498e-03 4.4660e-02 -6.0000e+00 9.4752e-01 -1.8887e-01 1.7641e-03 2.3055e-02 -6.0000e+00 5.6318e-01 7.0951e-02 8.5673e-04 6.9732e-03 -6.0000e+00 2.3263e-01 1.1676e-03 1.4389e-04 2.1843e-05 1.1140e-04 -6.0000e+00 1.7955e-02 2.1949e-03 3.7831e-05 12 8 8 10 0 0 2.38 25.93 0.31 0.00219 0.00328 545 57 1 5 0 99.630 34.75 20.00 25.93 23.82 3.3 985.41 -229518 -173928 -165225 -137331 -213884 -229222 -209892 -191841 -148651 -172975 -117726 -143211 -104683 -90610 -78215 -62184 -50457 -16649 -17789 -20534 -44935 -56077 -24580 -31134 -50869 -34079 -48997 -42265 -37039 -40216 -29843 -13307 -24577 -12223 -16972 -10340 -12966 -4993 -3409 -5900 -5352 3582 3964 2835 1026 1750 1703 2130 1283 2756 2783 7744 6452 6507 4968 5017 1888 2061 1750 1519 2193 3384 3400 3974 4077 2005 2305 2185 2707 2545 1829 1533 2207 1875 503 -1021 -489 -1084 -906 -174 -654 -1183 -1705 -1825 -1406 -546 -138 214 178 50 -152 10 -768 -1015 -907 -616 -148 -94 -569 -778 -770 -1036 -642 -374 -792 -1174 -860 -457 29 408 225 108 254 214 137 314 586 349 111 -43 189 306 630 506 641 738 229 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