File name: Pandora26s1_CambridgeMA_20240612_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20241217T230219.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20240612_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240612T101906.9Z 8929.429941 76 1 22.99 2 79.02 68.54 124.03 10.90 0.00 1 0.00 1 0 17 4.003e-01 2.925e-02 1.374e-01 7.877e-03 7.750329e-01 4.582160e-03 1.000594e-02 -6.000000e+00 2.489550e-01 232.80 -2.00 3.54 -2.00 321.26 0.00e+00 1.482624e-02 2.184718e-03 6.668148e-03 -6.000000e+00 1.299289e-02 285.33 -2.00 20.00 -2.00 320.66 0.00e+00 5.057 0.002 302.00 328.00 3 3.1860e+00 1.5657e-02 6.9107e-02 -6.0000e+00 6.3014e-01 7.2283e-01 2.0101e-02 4.7916e-02 -6.0000e+00 6.8639e-01 -9.6968e-01 1.6885e-02 3.1419e-02 -6.0000e+00 4.0811e-01 4.0635e-01 8.0470e-03 1.4997e-02 -6.0000e+00 1.6858e-01 5.3719e-05 3.7284e-04 2.3030e-04 2.8903e-04 -6.0000e+00 1.2873e-02 4.6970e-03 7.5108e-05 12 9 9 12 33 1 99.30 26.02 0.14 0.00470 0.00750 9 3 1 5 0 2298.340 35.00 20.00 26.02 25.84 3.1 994.73 -24419 900000 900000 900000 -90440 -185223 -135323 -49035 -116542 -15197 900000 900000 900000 900000 900000 15706 900000 900000 900000 900000 8280 -58983 900000 -60 57784 -41734 -41650 -50308 8298 -10251 -7172 -33275 20589 31093 -2823 900000 51285 35516 200695 9154 -14692 24208 49737 54032 2007 18005 52289 58545 9754 39591 -9141 29673 176800 78027 15729 35827 -4313 33968 663 13534 433 6502 -1901 13833 3938 5736 6384 11054 7333 23293 10655 7574 19430 -1889 -7221 3453 2122 -1893 -10540 4251 -1947 -5340 -3231 -6693 -2479 -624 -2317 3994 2258 207 -5270 -1410 -4651 -7845 -4352 -1187 1995 -1040 414 -2521 -2626 -2746 251 2320 -3871 -1115 -3053 -2351 -54 2685 -842 -1745 1417 460 249 -2061 1409 -370 239 290 2736 -1315 2089 1722 3673 3120 1106 459 -969 1278 1354 379 -897 371 1545 88 -1649 -91 -439 484 -859 -1145 -1150 -408 900000 900000 900000 -2582 -12511 -5371 -820 -3814 -180 900000 900000 900000 900000 900000 405 900000 900000 900000 900000 271 -3614 900000 -2 1151 -2206 -2138 -2775 267 -455 -374 -2651 1057 1453 -177 900000 2004 1850 2306 799 -1756 2058 3391 3601 229 1793 3805 4171 1196 3882 -1603 3864 5688 7112 2747 5159 -918 4788 126 2270 88 1380 -497 3401 1110 1582 1765 3074 2342 7066 3918 2913 6385 -709 -2578 1008 608 -600 -4214 1742 -899 -2878 -1852 -4218 -1588 -413 -1622 2664 1511 135 -3405 -833 -2821 -5272 -3234 -1004 1907 -1065 446 -2763 -2682 -2771 229 2095 -3930 -1069 -3191 -2658 -66 3635 -1202 -2648 2092 667 347 -3123 2105 -544 367 452 4073 -1955 3125 2487 5008 4148 1500 675 -1513 2200 2562 721 -1834 797 3480 210 -3788 -207 -1050 1088 -1829 -2300 -2265 SS 20240612T104528.0Z 8929.448240 88 1 27.93 2 74.43 72.60 122.95 18.18 0.00 1 0.00 1 0 17 1.618e-01 6.728e-03 1.033e-02 6.849e-04 5.873582e-01 3.655976e-04 6.713613e-03 -6.000000e+00 9.854890e-02 232.80 -2.00 3.54 -2.00 319.36 0.00e+00 1.485011e-03 1.000016e-04 5.690168e-04 -6.000000e+00 4.374127e-03 285.34 -2.00 20.00 -2.00 318.60 0.00e+00 3.657 0.001 302.00 328.00 3 8.6815e-01 1.0367e-03 4.8184e-02 -6.0000e+00 2.4731e-01 5.3685e-02 1.2167e-03 3.1096e-02 -6.0000e+00 2.6740e-01 -6.3222e-02 9.3850e-04 1.5275e-02 -6.0000e+00 1.5894e-01 1.9498e-02 4.8595e-04 4.5721e-03 -6.0000e+00 6.5592e-02 2.8994e-03 -9.5230e-05 1.9998e-05 5.3982e-05 -6.0000e+00 5.0648e-03 5.0595e-03 -5.0837e-05 12 9 1 12 1 1 98.21 26.05 0.31 0.00506 0.00434 310 64 1 5 0 89.780 35.00 20.00 26.05 26.39 3.1 997.52 -63361 -56355 -36276 -56731 -65217 -70795 -61819 -53046 -43983 -44370 -33394 -31800 -22779 -19757 -11915 -13381 -8186 -4000 1438 708 -4676 -8687 -1717 -5387 -6309 -6616 -8811 -10149 -5810 -5911 -2593 -3547 -4491 -3676 -5021 -3267 -4034 -1526 36 -1021 -623 3 869 1179 463 1750 1176 1295 1235 1642 1357 2810 2899 2517 1594 1638 764 673 778 1197 1198 2125 1690 1735 975 351 543 -80 732 998 78 155 46 -109 -215 -544 -711 -1092 -1016 -941 -1303 -1362 -1870 -1604 -858 -582 -11 188 487 509 282 395 8 222 -36 -111 99 193 -260 -743 -676 -762 -288 112 -605 -1104 -562 -509 92 308 247 241 220 203 157 396 695 340 166 17 -193 102 414 247 345 550 185 933 489 200 92 -247 -82 -58 69 -100 -121 164 -99 -235 -88 -360 -437 -1164 -1088 -596 -1110 -1333 -1560 -1371 -1222 -1031 -1129 -830 -905 -732 -767 -519 -686 -446 -229 83 43 -311 -619 -121 -427 -542 -595 -812 -931 -518 -577 -284 -414 -588 -495 -679 -451 -633 -280 8 -240 -162 1 248 342 138 523 360 408 377 536 491 1106 1155 1082 729 777 373 327 371 571 560 1085 965 1007 583 207 318 -50 468 715 58 118 35 -77 -147 -340 -451 -716 -701 -712 -1077 -1199 -1709 -1559 -844 -605 -11 198 504 526 286 376 8 215 -37 -125 116 244 -348 -982 -867 -934 -333 132 -731 -1419 -731 -683 129 459 384 386 347 307 233 588 1043 517 258 28 -307 156 632 363 502 797 265 1351 759 321 155 -428 -149 -108 132 -194 -242 330 -197 -461 -168 -660 -791 SS 20240612T105751.7Z 8929.456848 91 1 45.11 2 72.23 74.49 122.24 21.52 0.00 1 0.00 1 0 17 8.717e-02 6.068e-03 3.435e-03 3.655e-04 5.198327e-01 1.940961e-04 5.998077e-03 -6.000000e+00 5.307626e-02 232.81 -2.00 3.54 -2.00 318.81 0.00e+00 1.158654e-03 4.454042e-05 3.842643e-04 -6.000000e+00 2.355925e-03 285.34 -2.00 20.00 -2.00 318.03 0.00e+00 3.231 0.001 302.00 328.00 3 5.9793e-01 5.3782e-04 4.2593e-02 -6.0000e+00 1.3319e-01 3.9281e-02 6.1629e-04 2.7445e-02 -6.0000e+00 1.4402e-01 -4.6974e-02 4.3072e-04 1.3329e-02 -6.0000e+00 8.5600e-02 1.4270e-02 2.2293e-04 3.8274e-03 -6.0000e+00 3.5326e-02 6.1627e-03 -1.0142e-04 1.0930e-05 4.5601e-05 -6.0000e+00 2.7279e-03 4.8875e-03 -6.4374e-05 12 1 1 12 1 1 99.70 26.07 0.27 0.00489 0.00413 863 109 1 5 0 52.200 35.00 20.00 26.07 27.13 3.1 1002.48 -35515 -30182 -24447 -26843 -34099 -38346 -34896 -28613 -23945 -22396 -18854 -16860 -11505 -10389 -5855 -5447 -2603 -1423 1439 164 -1278 -2050 12 -1969 -2662 -2034 -3679 -3909 -3010 -1992 -776 -433 -752 -2232 -3123 -2588 -2022 -790 293 -157 -385 392 1017 852 1115 1178 630 1043 572 1159 1392 1665 1655 1567 1003 1034 599 351 460 822 1207 1752 1696 1548 564 -159 289 82 965 704 -22 129 -21 -6 -285 -541 -520 -1045 -742 -791 -1130 -1433 -1976 -1451 -893 -633 -204 41 262 222 389 515 168 212 153 -18 80 185 -294 -640 -653 -659 -341 67 -616 -984 -524 -373 1 380 340 163 230 200 215 441 642 343 187 -15 -134 74 383 228 427 545 206 954 567 123 50 -190 -97 -46 39 -42 -101 117 -81 -231 -133 -419 -462 -1053 -946 -746 -809 -1053 -1252 -1205 -1048 -928 -916 -799 -799 -626 -683 -439 -465 -239 -127 133 16 -130 -215 1 -235 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