File name: Pandora26s1_CambridgeMA_20240617_L2Fit_fout2c7d20230915p1-8.txt File generation date: 20241010T175324.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20240617_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240617 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.1176 305.2583 305.3991 305.5398 305.6805 305.8212 305.9619 306.1026 306.2432 306.3839 306.5245 306.6651 306.8057 306.9464 307.0869 307.2275 307.3681 307.5087 307.6492 307.7897 307.9303 308.0708 308.2113 308.3518 308.4923 308.6327 308.7732 308.9136 309.0541 309.1945 309.3349 309.4753 309.6157 309.7561 309.8964 310.0368 310.1771 310.3175 310.4578 310.5981 310.7384 310.8787 311.0189 311.1592 311.2995 311.4397 311.5799 311.7201 311.8604 312.0005 312.1407 312.2809 312.4211 312.5612 312.7013 312.8415 312.9816 313.1217 313.2618 313.4019 313.5419 313.6820 313.8220 313.9621 314.1021 314.2421 314.3821 314.5221 314.6621 314.8020 314.9420 315.0819 315.2219 315.3618 315.5017 315.6416 315.7815 315.9213 316.0612 316.2010 316.3409 316.4807 316.6205 316.7603 316.9001 317.0399 317.1797 317.3194 317.4592 317.5989 317.7386 317.8783 318.0180 318.1577 318.2974 318.4371 318.5767 318.7164 318.8560 318.9956 319.1352 319.2748 319.4144 319.5540 319.6935 319.8331 319.9726 320.1122 320.2517 320.3912 320.5307 320.6702 320.8096 320.9491 321.0885 321.2280 321.3674 321.5068 321.6462 321.7856 321.9250 322.0643 322.2037 322.3430 322.4823 322.6217 322.7610 322.9003 323.0395 323.1788 323.3181 323.4573 323.5965 323.7358 323.8750 324.0142 324.1534 324.2926 324.4317 324.5709 324.7100 324.8491 324.9883 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240617T110048.0Z 8934.458888 143 1 54.32 2 71.77 74.61 142.47 309.87 0.00 1 0.00 1 0 17 4.501e-02 5.404e-03 3.403e-03 4.803e-04 4.337971e-01 2.547788e-04 5.028574e-03 -6.000000e+00 2.740843e-02 232.94 -2.00 3.54 -2.00 318.48 0.00e+00 6.514183e-04 5.246514e-05 2.334755e-04 -6.000000e+00 1.218983e-03 285.82 -2.00 20.00 -2.00 317.67 0.00e+00 3.155 0.001 302.00 328.00 3 1.3441e+00 7.0037e-04 3.9014e-02 -6.0000e+00 6.8792e-02 4.6793e-03 7.9669e-04 2.2941e-02 -6.0000e+00 7.4374e-02 -2.4978e-02 5.2784e-04 1.1066e-02 -6.0000e+00 4.4212e-02 5.0337e-03 2.6987e-04 3.0708e-03 -6.0000e+00 1.8250e-02 3.6115e-03 7.6830e-05 1.4884e-05 3.6081e-05 -6.0000e+00 1.4087e-03 -7.0836e-03 0.0000e+00 10 0 0 10 0 0 99.68 25.91 0.31 -0.00708 -0.00651 727 76 1 5 0 74.700 35.00 20.01 25.91 24.27 3.3 988.45 -14275 -12225 -11092 -13328 -21640 -23136 -19306 -16050 -10174 -10043 -7524 -7271 -3227 -4960 -2853 -1974 -1089 499 3439 2893 2 -657 1570 -206 -1531 -1442 -2237 -3016 -214 -1229 -616 690 -1177 -1987 -3152 -1280 -1466 -572 200 -826 -792 80 621 -37 449 508 306 252 42 847 1046 1423 1506 1366 798 1051 301 320 433 839 1170 1550 1379 1174 323 -209 302 -33 887 864 -144 85 -4 -53 -450 -503 -396 -762 -524 -552 -1292 -1309 -1887 -1368 -774 -559 -90 167 376 310 399 466 337 327 325 136 310 157 -263 -601 -632 -709 -187 77 -678 -980 -532 -445 27 317 193 91 142 189 230 447 603 326 190 -90 -197 -42 243 210 571 549 292 921 497 65 26 -150 -57 29 70 -50 -121 80 -150 -187 -135 -386 -365 -558 -512 -468 -548 -917 -1008 -885 -802 -528 -551 -426 -459 -232 -432 -285 -219 -130 57 404 356 0 -87 215 -31 -246 -239 -370 -487 -33 -203 -113 140 -263 -457 -720 -297 -352 -162 67 -297 -312 33 264 -16 196 223 135 112 18 373 498 734 779 752 461 625 183 194 258 502 733 988 964 821 228 -142 212 -22 659 677 -123 71 -3 -43 -342 -368 -272 -530 -398 -453 -1146 -1222 -1905 -1393 -838 -613 -102 194 431 341 426 463 337 334 344 155 381 204 -344 -772 -792 -859 -217 92 -835 -1280 -700 -622 39 473 294 141 215 281 333 621 847 481 287 -136 -301 -64 363 313 807 775 405 1318 745 103 43 -245 -97 49 123 -93 -223 149 -278 -346 -240 -682 -639 SS 20240617T110710.0Z 8934.463310 146 1 52.20 2 70.64 75.58 143.34 311.86 0.00 1 0.00 1 0 17 2.040e-01 2.026e-02 4.759e-02 3.469e-03 4.102412e-01 1.838910e-03 4.719092e-03 -6.000000e+00 1.242266e-01 232.94 -2.00 3.54 -2.00 319.11 0.00e+00 -1.568960e-03 4.520783e-04 3.631042e-04 -6.000000e+00 5.526060e-03 285.82 -2.00 20.00 -2.00 318.33 0.00e+00 2.981 0.000 302.00 328.00 3 4.8926e+00 5.1513e-03 3.6956e-02 -6.0000e+00 3.1179e-01 5.4069e-02 5.9725e-03 2.2005e-02 -6.0000e+00 3.3712e-01 -6.2432e-02 4.2088e-03 1.0483e-02 -6.0000e+00 2.0040e-01 2.7411e-02 2.1538e-03 3.0819e-03 -6.0000e+00 8.2700e-02 1.2445e-04 1.1480e-04 1.1058e-04 3.5073e-05 -6.0000e+00 6.3865e-03 -5.6243e-03 0.0000e+00 12 9 9 12 1 1 99.96 25.93 -0.16 -0.00562 -0.00476 15 2 1 5 0 3262.080 35.00 20.00 25.93 24.99 3.2 991.38 11903 56858 117624 49817 -42236 -97330 -67825 -31079 25553 4820 56681 1836 32880 29362 7164 -7757 -7066 6604 93413 34900 -1211 -5047 24063 7453 -6128 -11568 -1303 -17036 3055 -21240 -15184 -3110 5936 -5811 -9573 23900 1763 -768 9716 -3669 -6096 4287 8024 8294 -7338 10398 2678 -2514 -5409 2570 -7327 16876 15970 9997 -111 5089 -6665 6147 -372 -295 -2445 2405 -1793 1535 4461 -3500 -2208 -1970 -1593 6464 -38 383 2145 -1447 -3220 -536 -2028 -781 -2488 -295 -3069 -3212 -2126 -1702 -893 -785 -1604 1953 3165 2727 -825 150 -2132 -1735 -498 1026 2440 -378 684 -1313 -1584 -2140 1776 1863 -1900 -509 -824 -687 -472 2136 -496 79 1222 319 49 -786 1317 105 149 132 1027 -1428 575 -309 1649 1882 -633 840 -797 471 487 -95 -1519 -532 1125 485 -869 -167 41 256 -420 -463 -68 310 1020 1154 910 -1829 -7410 -4223 -1514 778 191 1400 86 1313 1421 497 -690 -669 579 3603 2503 -127 -562 2109 830 -831 -1707 -171 -2496 357 -3277 -2420 -486 912 -1017 -1704 3146 326 -173 2354 -1167 -1973 1315 2677 2781 -2618 3413 943 -848 -1907 964 -2973 6401 5959 4198 -54 2414 -3608 2906 -185 -147 -1302 1322 -1118 976 2740 -2223 -1345 -1228 -1084 4528 -28 290 1572 -1042 -2368 -348 -1254 -479 -1690 -223 -2464 -2853 -2006 -1701 -946 -815 -1757 2104 3330 2977 -868 145 -2010 -1658 -511 1161 2818 -492 919 -1759 -1993 -2509 1932 2098 -2369 -661 -1130 -997 -680 3230 -812 131 1936 480 69 -1165 1930 151 228 211 1625 -2267 866 -450 2421 2640 -889 1206 -1168 735 807 -164 -2587 -944 2073 939 -1750 -338 82 495 -783 -832 -120 SS 20240617T111130.5Z 8934.466325 149 1 3.74 2 69.86 76.24 143.92 313.26 0.00 1 0.00 1 0 17 2.604e-02 5.849e-03 1.236e-02 2.499e-03 3.954386e-01 1.325602e-03 4.628808e-03 -6.000000e+00 1.585925e-02 232.94 -2.00 3.54 -2.00 317.99 0.00e+00 3.830012e-04 2.354593e-04 3.061063e-04 -6.000000e+00 7.052347e-04 285.82 -2.00 20.00 -2.00 317.18 0.00e+00 2.873 0.000 302.00 328.00 3 2.2270e+00 3.5867e-03 3.5532e-02 -6.0000e+00 3.9805e-02 2.9735e-03 4.0473e-03 2.0874e-02 -6.0000e+00 4.3033e-02 -2.0271e-02 2.5222e-03 1.0032e-02 -6.0000e+00 2.5581e-02 5.2344e-03 1.2599e-03 2.7037e-03 -6.0000e+00 1.0561e-02 2.0500e-03 2.6460e-04 7.8005e-05 3.3615e-05 -6.0000e+00 8.1498e-04 -8.0875e-03 0.0000e+00 12 1 1 12 1 1 18.62 25.94 0.31 -0.00809 -0.00610 13 21 1 5 0 266.580 35.00 20.00 25.94 25.30 3.2 992.29 -11657 -2139 -11905 1976 -7941 -11907 -12601 -6219 3338 -780 -5190 -5859 2306 -2496 -4757 1387 -1039 1916 2368 2113 109 1790 3503 54 -929 -140 -3106 -3411 682 -1076 -848 -593 -1720 -1817 -3148 -1596 -1311 -796 -780 -1030 -1467 77 261 247 -425 106 593 -286 -44 234 1139 1628 1729 1016 867 2073 161 946 210 1461 1286 987 1443 1213 579 -348 191 -318 1064 862 185 -68 -227 -130 -792 -255 -414 -306 -502 -403 -1111 -1353 -1628 -1310 -905 -329 95 15 128 234 -32 214 27 67 456 92 216 -209 -277 -669 -538 -879 -143 -23 -725 -966 -694 -393 229 707 268 461 222 387 340 358 528 351 91 62 -240 -104 126 375 907 250 344 897 479 323 12 -533 -107 -74 85 -207 -20 199 -261 -174 -3 -389 -440 -727 -132 -818 112 -470 -740 -860 -447 239 -61 -448 -563 238 -290 -654 199 -165 314 407 378 20 334 673 11 -194 -30 -672 -713 146 -245 -195 -151 -476 -511 -880 -453 -385 -276 -299 -454 -662 36 126 121 -210 52 290 -141 -22 122 595 916 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